Arsenolite R050383

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Record 275 of 4037  


Name: Arsenolite
RRUFF ID: R050383
Ideal Chemistry: As2O3
Locality: Eureka, Nevada, USA
Source: University of Arizona Mineral Museum 3603 [view label]
Owner: RRUFF
Description: Colorless hoppered octahedra
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Arsenolite (4) ]
Quick search: [ All Arsenolite samples (2) ]
CHEMISTRY 
RRUFF ID: R050383.2
Sample Description: Microprobe Fragment
Measured Chemistry: As2.00O3
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
DOWNLOADS:

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Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050383
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050383.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050383.1
Sample Description: Powder
Cell Refinement Output: a: 11.0749(3)Å    b: 11.0749(3)Å    c: 11.0749(3)Å
alpha: 90.°    beta: 90.°    gamma: 90.°   Volume: 1358.4(1)Å3    Crystal System: cubic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Arsenolite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Dana J D (1854) II. Oxyds of elements of the arsenic group. I. Oxyds of arsenic, antimony, etc. Arsenolite, in A System of Mineralogy, Comprising the Most Recent Discoveries, Fourth Edition, Volume II George P. Putnam & Co. New York and London 139-140   [view file]

Bozorth R M (1923) The crystal structures of the cubic forms of arsenious and antimonous oxides, Journal of the American Chemical Society, 45, 1621-1627   [view file]

Beattie I R, Livingston K M S, Ozin G A, Reynolds D J (1970) Single-crystal Raman spectra of arsenolite (As4O6) and senarmonite (Sb4O6). The gas-phase Raman spectra pf P4O6, P4O10, and As4O6, Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1970, 449-451

Flynn E J, Solin S A, Papatheodorou G N (1976) Vibrational excitations of As2O3. II. Crystalline phases, Physical Review B, 13, 1752-1758

Mrose M E, Larson R R, Estep P A (1976) Forbesite — a mixture of cobaltoan annabergite and arsenolite, The Canadian Mineralogist, 14, 414-421   [view file]

Pertlik F (1978) Strukturverfeinerung von kubischem As2O3 (arsenolith) mit einkristalldaten, Czechoslovak Journal of Physics, 28, 170-176

Treacy D J, Taylor P C (1981) Nuclear quadrupole resonance in two crystalline forms of As2O3, arsenolite and claudetite I, Solid State Communications, 40, 135-138

Grzechnik A (1999) Compressibility and vibrational modes in solid As4O6, Journal of Solid State Chemistry, 144, 416-422

Ballirano P, Maras A (2002) Refinement of the crystal structure of arsenolite, As2O3, Zeitschrift für Kristallographie, 217, 177-178

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970   [view file]

Gilliam S J, Merrow C N, Kirkby S J, Jensen J O, Zeroka D, Banerjee A (2003) Raman spectroscopy of arsenolite: crystalline cubic As4O6, Journal of Solid State Chemistry, 173, 54-58

Ballirano P, Maras A (2006) In-situ X-ray transmission powder diffraction study of the kinetics of the light induced alteration of realgar (α-As4S4), European Journal of Mineralogy, 18, 589-599

Soignard E, Amin S A, Mei Q, Benmore C J, Yarger J L (2008) High-pressure behavior of As2O3: Amorphous-amorphous and crystalline-amorphous transitions, Physical Review B, 77, 144113-8

Gibbs G V, Wallace A F, Cox D F, Dove P M, Downs R T, Ross N L, Rosso K M (2009) Role of directed van der Waals bonded interactions in the determination of the structures of molecular arsenate solids, Journal of Physical Chemistry A, 113, 736-749   [view file]

Ballirano P (2012) Thermal behavior of realgar As4S4, and of arsenolite As2O3 and non-stoichiometric As8S8+x crystals produced from As4S4 melt recrystallization, American Mineralogist, 97, 1320-1329   [view file]