Berthierite R070177

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Record 432 of 4043  


Name: Berthierite
RRUFF ID: R070177
Ideal Chemistry: FeSb2S4
Locality: Baia Sprie mine (Felsöbánya mine), Baia Sprie (Felsöbánya), Maramures County, Romania
Source: Michael Scott S101663 [view label]
Owner: RRUFF
Description: A mass of parallel silver gray metallic prismatic striated crystals
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Berthierite (1) ]
CHEMISTRY 
RRUFF ID: R070177.2
Sample Description: Microprobe Fragment
Measured Chemistry: darker phase: (Fe0.97Mn0.03)Σ=1(Sb1.99As0.01)Σ=2S4.00 ; lighter phase (bottom): Sb2.00S3.00 (stibnite)
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R070177
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 40% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R070177.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
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POWDER DIFFRACTION 
RRUFF ID: R070177.1
Sample Description: Powder
Cell Refinement Output: a: 11.4130(6)Å    b: 14.1648(5)Å    c: 3.7632(2)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 608.37(3)Å3    Crystal System: orthorhombic
  File Type Information Close
Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Berthierite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Haidinger W (1827) On berthierite, a new mineral species, The Edinburgh Journal of Science, 7, 353-354   [view file]

Buerger M J, Hahn T (1955) The crystal structure of berthierite, Fe Sb2S4, American Mineralogist, 40, 226-238   [view file]

Tatsuka K, Morimoto N (1977) Tetrahedrite stability relations in the Cu-Fe-Sb-S system, American Mineralogist, 62, 1101-1109   [view file]

Makovicky E (1985) The building principles and classification of sulphosalts based on the SnS archetype, Fortschritte der Mineralogie, 63, 45-89

Bente K, Edenharter A (1989) Röntgenographische Strukturanalyse von MnSb2S4 und Strukturverfeinerung von Berthierit, FeSb2S4, Zeitschrift für Kristallographie, 185, 31-33

Lemoine P, Carré D, Robert F (1991) Structure du sulfure de fer et d'antimoine, FeSb2S4(Berthiérite), Acta Crystallographica, C47, 938-940

Lukaszewicz K, Pietrasko A, Stepien-Damm J, Kajokas A, Grigas J, Drulis H (2001) Crystal structure, Mossbauer spectra, thermal expansion, and phase transition of berthierite FeSb2S4, Journal of Solid State Chemistry, 162, 79-83

Periotto B, Balić-Žunić T, Nestola F (2012) The role of the Sb3+ lone-electron pairs and Fe2+ coordination in the high-pressure behavior of berthierite, The Canadian Mineralogist, 50, 201-218   [view file]

Kharbish S, Andráš P (2014) Investigations of the Fe sulfosalts berthierite, garavellite, arsenopyrite, and gudmundite by Raman spectroscopy, Mineralogical Magazine, 78, issue 5 1287-1299