* R130024 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Carrollite R130024

Name: Carrollite
RRUFF ID: R130024
Ideal Chemistry: CuCo₂S₄
Locality: Kisanfu, Katanga, Democratic Republic of the Congo
Source: Isabel Fay
Owner: RRUFF
Description: Silver metallic, massive, associated with chalcocite, bornite, digenite and magnesite
Status: The identification of this mineral has been confirmed only by single crystal X-ray diffraction.

Mineral Group: [ Spinel (66) ]

Quick search: [ All Carrollite samples (3) ]

CHEMISTRY

RRUFF ID:	R130024.2
Sample Description:	Microprobe Fragment

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented Raman on the primary sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R130024

Wavelength:

Sample Description:

Unoriented Raman on the primary sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R130024.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 9.467(2)Å b: 9.467(2)Å c: 9.467(2)Å
alpha: 90° beta: 90° gamma: 90° Volume: 848.33(7)Å³ Crystal System: cubic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Carrollite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Faber W L (1852) On carrollite, a new cobalt mineral, American Journal of Science and Arts, 13, 418-419 [view file]
Foshag W F (1928) New mineral names, American Mineralogist, 13, 32-34 [view file]
Riedel E, Horvath E (1973) Kationen-anionen-abstände in kupfer- und chrom-thiospinellen, Materials Research Bulletin, 8, 973-982
Williamson D P, Grimes N W (1974) An X-ray diffraction investigation of sulphide spinels, Journal of Physics D: Applied Physics, 7, 1-6
Wagner T, Cook N J (1999) Carrollite and related minerals of the linnaeite group: Solid solutions and nomenclature in the light of new data from the Siegerland District, Germany, The Canadian Mineralogist, 37, 545-558 [view file]
Pattrick R A D, Coker V S, Pearce C I, Telling N D, van der Laan G (2008) The oxidation state of copper and cobalt in carrollite, CuCo₂S₄, The Canadian Mineralogist, 46, 1317-1322 [view file]
Buckley A N, Skinner W M, Harmer S L, Pring A, Fan L J (2009) Electronic environments in carrollite, CuCo₂S₄, determined by soft X-ray photoelectron absorption spectroscopy, Geochimica et Cosmochimica Acta, 73, 4452-4467
Hazen R M, Hystad G, Golden J J, Hummer D R, Liu C, Downs R T, Morrison S M, Ralph J, Grew E S (2017) Cobalt mineral ecology, American Mineralogist, 102, 108-116 [view file]
Bosi F, Biagioni C, Pasero M (2019) Nomenclature and classification of the spinel supergroup, European Journal of Mineralogy, 31, 183-192 [view file]

REFERENCES for Carrollite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Faber W L (1852) On carrollite, a new cobalt mineral, American Journal of Science and Arts, 13, 418-419 [view file]

Foshag W F (1928) New mineral names, American Mineralogist, 13, 32-34 [view file]

Riedel E, Horvath E (1973) Kationen-anionen-abstände in kupfer- und chrom-thiospinellen, Materials Research Bulletin, 8, 973-982

Williamson D P, Grimes N W (1974) An X-ray diffraction investigation of sulphide spinels, Journal of Physics D: Applied Physics, 7, 1-6

Wagner T, Cook N J (1999) Carrollite and related minerals of the linnaeite group: Solid solutions and nomenclature in the light of new data from the Siegerland District, Germany, The Canadian Mineralogist, 37, 545-558 [view file]

Pattrick R A D, Coker V S, Pearce C I, Telling N D, van der Laan G (2008) The oxidation state of copper and cobalt in carrollite, CuCo₂S₄, The Canadian Mineralogist, 46, 1317-1322 [view file]

Buckley A N, Skinner W M, Harmer S L, Pring A, Fan L J (2009) Electronic environments in carrollite, CuCo₂S₄, determined by soft X-ray photoelectron absorption spectroscopy, Geochimica et Cosmochimica Acta, 73, 4452-4467

Hazen R M, Hystad G, Golden J J, Hummer D R, Liu C, Downs R T, Morrison S M, Ralph J, Grew E S (2017) Cobalt mineral ecology, American Mineralogist, 102, 108-116 [view file]

Bosi F, Biagioni C, Pasero M (2019) Nomenclature and classification of the spinel supergroup, European Journal of Mineralogy, 31, 183-192 [view file]