Bustamite R040014


Name: Bustamite
RRUFF ID: R040014
Ideal Chemistry: CaMn2+Si2O6
Locality: Broken Hill, New South Wales, Australia
Source: University of Arizona Mineral Museum 13651 [view label]
Owner: RRUFF
Description: Orange fragment
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Wollastonite (6) ]
CHEMISTRY 
RRUFF ID: R040014.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Ca0.90Mn0.10)Σ=1(Mn2+0.78Fe2+0.19Fe3+0.02Mg0.01)Σ=1(Si1.98Fe3+0.02)Σ=2O6
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Sample is oriented, mounted onto a pin and polished
Pin ID: L00268
Orientation: Laser parallel to  -a*  (-1 0 0).     Fiducial mark perpendicular to laser is parallel to  b   [0 1 0].
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Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R040014
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R040014.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R040014.1
Sample Description: Powder
Cell Refinement Output: a: 9.844(1)Å    b: 10.755(1)Å    c: 7.128(2)Å
alpha: 99.58(2)°    beta: 99.76(2)°    gamma: 83.878(9)°   Volume: 731.0(2)Å3    Crystal System: triclinic
  File Type Information Close
Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Bustamite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Brongniart A (1826) Sur la bustamite, bisilicate de manganèse et de chaux du Mexique, Anneles des Sciences Naturelles, 8, 411-418   [view file]

Larsen E S, Shannon E V (1922) Bustamite from Franklin Furnace, New Jersey, American Mineralogist, 7, 95-100   [view file]

Hutton C O (1956) Manganpyrosmalite, bustamite, ferroan johannsenite from Broken Hill, New South Wales, Australia, American Mineralogist, 41, 581-591   [view file]

Peacor D R, Buerger M J (1962) Determination and refinement of the crystal structure of bustamite, CaMnSi2O6, Zeitschrift für Kristallographie, 117, 331-343   [view file]

Manning P G (1968) Absorption spectra of the manganese-bearing chain silicates pyroxmangite, rhodonite, bustamite and serandite, The Canadian Mineralogist, 9, 348-357   [view file]

Welin E (1968) Notes on the mineralogy of Sweden 6. X-ray powder data for minerals from Långban and the related mineral deposits of Central Sweden, Arkiv för Mineralogi och Geologi, 4, 499-541

Rapoport P A, Burnham C W (1973) Ferrobustamite: The crystal structures of two Ca,Fe bustamite-type pyroxenoids, Zeitschrift für Kristallographie, 138, 419-438   [view file]

Ohashi Y, Finger L W (1978) The role of octahedral cations in pyroxenoid crystal chemistry. I. Bustamite, wollastonite, and the pectolite–schizolite–serandite series, American Mineralogist, 63, 274-288   [view file]

Viswanathan K, Harneit O (1986) Lattice expansion and ionic substitution in common pyroxenoids, Contributions to Mineralogy and Petrology, 94, 238-244

Hybler J, Petrícek V, Jurek K, Skála R, Císarová I (1997) Structure determination of vistepite SnMn4B2Si4O16(OH)2: isotypism with bustamite, revised crystallographic data and composition, The Canadian Mineralogist, 35, 1283-1292   [view file]

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970   [view file]

Makreski P, Jovanovski G, Gajović A, Biljan T, Angelovski D, Jaćimović R (2006) Minerals from Macedonia. XVI. Vibrational spectra of some common appearing pyroxenes and pyroxenoids, Journal of Molecular Structure, 788, 102-114

Aksenov S M, Shipalkina N V, Rastsvetaeva R K, Rusakov R V, Pekov I V, Chukanov N V, Yapaskurt V O (2015) Iron-rich bustamite from Broken Hill, Australia: the crystal structure and cation-ordering features, Crystallography Reports, 60, 340-345