Elbaite R050260

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Record 4 of 13  

Name: Elbaite
RRUFF ID: R050260
Ideal Chemistry: Na(Al1.5Li1.5)Al6(Si6O18)(BO3)3(OH)3(OH)
Locality: Minas Gerais, Brazil
Source: Marcus Origlieri
Owner: RRUFF
Description: Greenish-gray prismatic single crystal
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ tourmaline (49) ]
Quick search: [ All Elbaite samples (13) ]
CHEMISTRY 
RRUFF ID: R050260.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Na0.760.17Ca0.07)Σ=1(Al1.67Li0.97Mn0.36)Σ=3Al6.00(B1.00O3)3Si6.00O18((OH)3.40F0.60)Σ=4; B assumed by stoichiometry; OH estimated by charge balance
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Sample is oriented and mounted on a pin
Pin ID: L01964
Orientation: Laser parallel to  a*  (1 0 0).     Fiducial mark perpendicular to laser is parallel to  -c   [0 0 -1].
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Raman Mode Analysis
Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050260
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050260.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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RRUFF ID: R050260.1
Sample Description: Powder
Instrument settings: PIKE GladiATR - Far-IR on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050260.1
Sample Description: Powder
Cell Refinement Output: a: 15.8685(4)Å    b: 15.8685(4)Å    c: 7.1112(2)Å
alpha: 90°    beta: 90°    gamma: 120°   Volume: 1550.76(8)Å3    Crystal System: hexagonal
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Elbaite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Vernadsky W (1913) Über die chemische Formel der Turmaline, Zeitschrift für Krystallographie und Mineralogie, 53, 273-288   [view file]

Donnay G, Barton R (1972) Refinement of the crystal structure of elbaite and the mechanism of tourmaline solid solution, Tschermaks Mineralogische und Petrographische Mitteilungen, 18, 273-286

Alvarez M A, Coy-Yll R (1978) Raman spectra of tourmaline, Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, 34, 899-908

Schmetzer K, Nuber B, Abraham K (1979) Zur Kristallchemie Magnesium-reicher Turmaline, Neues Jahrbuch für Mineralogie, Abhandlungen, 136, 93-112

Peng M, Mao H, Chen L, Chao E C T (1989) The polarized Raman spectra of tourmaline, Annual Report of the Director Geophysical Laboratory, 1989, 99-105   [view file]

Burns P C, MacDonald D J, Hawthorne F C (1994) The crystal chemistry of manganese-bearing elbaite, The Canadian Mineralogist, 32, 31-41   [view file]

Gashrova B, Mihailova B, Konstantinov L (1997) Raman spectra of various types of tourmaline, European Journal of Mineralogy, 9, 935-940

Dyar M D, Taylor M E, Lutz T M, Francis C A, Guidotti C V, Wise M (1998) Inclusive chemical characterization of tourmaline: Mössbauer study of Fe valence and site occupancy, American Mineralogist, 83, 848-864   [view file]

Hawthorne F C, Henry D J (1999) Classification of the minerals of the tourmaline group, European Journal of Mineralogy, 11, 201-215   [view file]

Jambor J L, Roberts A C (2001) New mineral names, American Mineralogist, 86, 767-770   [view file]

Bosi F, Andreozzi G B, Federico M, Graziani G, Lucchesi S (2005) Crystal chemistry of the elbaite-schorl series, American Mineralogist, 90, 1784-1792   [view file]

Ertl A, Hughes J M, Prowatke S, Ludwig T, Prasad P S R, Brandstätter F, Körner W, Schuster R, Pertlik F, Marschall H (2006) Tetrahedrally coordinated boron in tourmalines from the liddicoatite-elbaite series from Madagascar: Structure, chemistry, and infrared spectroscopic studies, American Mineralogist, 91, 1847-1856   [view file]

Shtukenberg A, Rozhdestvenskaya I, Frank-Kamenetskaya O, Bronzova J, Euler H, Kirfel A, Bannova I, Zolotarev A (2007) Symmetry and crystal structure of biaxial elbaite-liddicoatite tourmaline from the Transbaikalia region, Russia, American Mineralogist, 92, 675-686   [view file]

Henry D J, Novák M, Hawthorne F C, Ertl A, Dutrow B L, Uher P, Pezzotta F (2011) Nomenclature of the tourmaline-supergroup minerals, American Mineralogist, 96, 895-913   [view file]

Diego Gatta G, Danisi R M, Adamo I, Meven M, Diella V (2012) A single-crystal neutron and X-ray diffraction study of elbaite, Physics and Chemistry of Minerals, 39, 577-588

Vereshchagin O S, Rozhdestvenskaya I V, Frank-Kamenetskaya O V, Zolotarev A A, Mashkovtsev R I (2013) Crystal chemistry of Cu-bearing tourmalines, American Mineralogist, 98, 1610-1616

Watenphul A, Burgdorf M, Schlüter J, Horn I, Malcherek T, Mihailova B (2016) Exploring the potential of Raman spectroscopy for crystallochemical analyses of complex hydrous silicates: II. Tourmalines, American Mineralogist, 101, 970-985

Bosi F (2018) Tourmaline crystal chemistry, American Mineralogist, 103, 298-306   [view file]

Hovis G L, Tribaudino M, Altomare C, Bosi F (2023) Thermal expansion of minerals in the tourmaline supergroup, American Mineralogist, 108, 1053-1063