Fluorphosphohedyphane R110037

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		Name: Fluorphosphohedyphane RRUFF ID: R110037 Ideal Chemistry: Ca₂Pb₃(PO₄)₃F Locality: Blue Bell claims, Baker, San Bernardino Co., California, USA Source: Brent Thorne [view label] Owner: RRUFF Description: Colorless hexagonal prisms with long pyramidal terminations, cell parameters suggest phosphohedyphane Status: The identification of this mineral has been confirmed only by single crystal X-ray diffraction.

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented Raman on the primary sample; 780 nm spectrum overwhelmed by fluorescence.

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BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R110037

Wavelength:

Sample Description:

Unoriented Raman on the primary sample; 780 nm spectrum overwhelmed by fluorescence.

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

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	Raman Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R110037.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 9.863(8)Å b: 9.863(8)Å c: 7.208(4)Å
alpha: 90° beta: 90° gamma: 120° Volume: 607.3(1) Crystal System: hexagonal

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REFERENCES for Fluorphosphohedyphane
American Mineralogist Crystal Structure Database Record: [view record]
Miyake M, Ishigaki K, Suzuki T (1986) Structure refinement of Pb²⁺ ion-exchanged apatites by X-ray powder pattern-fitting, Journal of Solid State Chemistry, 61, 230-235
Williams P A, Hatert F, Pasero M (2009) New minerals approved in 2009, in International Mineralogical Association 1-34 [view file]
Pasero M, Kampf A R, Ferraris C, Pekov I V, Rakovan J R, White T J (2010) Nomenclature of the apatite supergroup minerals, European Journal of Mineralogy, 22, 163-179
Kampf A R, Housley R M (2011) Fluorphosphohedyphane, Ca₂Pb₃(PO₄)₃F, the first apatite supergroup mineral with essential Pb and F, American Mineralogist, 96, 423-429