Hibonite R061069



Name: Hibonite
RRUFF ID: R061069
Ideal Chemistry: (Ca,Ce)(Al,Ti,Mg)12O19
Locality: Madagascar
Source: Michael Scott S101443 [view label]
Owner: RRUFF
Description: Black platy hexagonal prism
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Plumboferrite (4) ]
CHEMISTRY 
RRUFF ID: R061069.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Ca0.82Ce0.10La0.07Nd0.01)Σ=1(Al10.40Ti0.64Fe0.59Mg0.30Si0.07)Σ=12O19
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R061069
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
POWDER DIFFRACTION 
RRUFF ID: R061069.1
Sample Description: Powder
Cell Refinement Output: a: 5.6082(2)Å    b: 5.6082(2)Å    c: 22.226(2)Å
alpha: 90°    beta: 90°    gamma: 120°   Volume: 605.40(5)Å3    Crystal System: hexagonal
  File Type Information Close
Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Hibonite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Curien H, Guillemin C, Orcel J, Sternberg M (1956) La hibonite, nouvelle espèce minérale, Comptes Rendus Hebdomadaires des Séances de l'Académie des Sciences, 242, 2845-2847   [view file]

Fleischer M (1957) New mineral names, American Mineralogist, 42, 117-124   [view file]

Beckett J R, Live D, Tsay F D, Grossman L, Stolper E (1988) Ti3+ in meteoritic and synthetic hibonite, Geochimica et Cosmochimica Acta, 52, 1479-1495

Utsunomiya A, Tanaka K, Morikawa H, Marumo F, Kojima H (1988) Structure refinement of CaO·6Al2O3, Journal of Solid State Chemistry, 75, 197-200   [view file]

Bermanec V, Holtstam D, Sturman D, Criddle A J, Back M E, Scavnicar S (1996) Nezilovite, a new member of the magnetoplumbite group, and the crystal chemistry of magnetoplumbite and hibonite, The Canadian Mineralogist, 34, 1287-1297   [view file]

Doyle P M, Schofield P F, Berry A J, Walker A M, Knight K S (2014) Substitution of Ti3+ and Ti4+ in hibonite (CaAl12O19), American Mineralogist, 99, 1369-1382

Giannini M, Ballaran T B, Langenhorst F (2014) Crystal chemistry of synthetic Ti-Mg-bearing hibonites: a single-crystal X-ray study, American Mineralogist, 99, 2060-2067