Ilmenorutile R050031 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Rutile R050031

Name: Rutile
RRUFF ID: R050031
Ideal Chemistry: TiO₂
Locality: Chester City, Pennsylvannia, USA
Source: University of Arizona Mineral Museum 3776 [view label]
Owner: RRUFF
Description: Reddish brown single crystal fragment
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Quick search: [ All Rutile samples (5) ]

CHEMISTRY

RRUFF ID:	R050031.2
Sample Description:	Microprobe fragment
Measured Chemistry:	TiO₂

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Sample is oriented, mounted onto a pin and polished

Pin ID:

M00132

Orientation:

Laser parallel to -a* (-1 0 0). Fiducial mark perpendicular to laser is parallel to -c [0 0 -1].

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

Raman Mode Analysis

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R050031

Wavelength:

Sample Description:

Unorientated Raman on the primary sample

Instrument settings:

Thermo Almega XR 785nm @ 100% of 500mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R050031.1

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R050031.1

Sample Description:

Powder

Cell Refinement Output:

a: 4.5945(1)Å b: 4.5945(1)Å c: 2.9594(1)Å
alpha: 90.° beta: 90.° gamma: 90.° Volume: 62.472(3) Crystal System: tetragonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Rutile
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Schoβberger, F. (1942) Über die umwandlungen des titandioxyds, Journal of Solid State Chemistry, 104, 358-374
Baur W H (1956) Über die verfeinerung der kristallstrukturbestimmung einiger vertreter des rutiltyps: TiO₂, SnO₂, GeO₂ und MgF₂, Acta Crystallographica, 9, 515-520 [link]
Papezik V S, De Witt M J (1973) Shorter communications: Coarse-grained rutile from northern Newfoundland, The Canadian Mineralogist, 12, 224-225 [view file]
Corlett M I, McIlreath I A (1974) An authigenic quartz-calcite-rutile assemblage in ordovician limestones, The Canadian Mineralogist, 12, 411-416 [view file]
Meagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO₂ polymorphs: refinement of the crystal structures of rutile and brookite at high temperature, The Canadian Mineralogist, 17, 77-85 [view file]
Cerný P, Paul B J, Hawthorne F C, Chapman R (1981) A niobian rutile – disordered columbite intergrowth from the Huron Claim pegmatite, southeastern Manitoba, The Canadian Mineralogist, 19, 541-548 [view file]
Kudoh Y, Takeda H (1986) Single crystal X-ray diffraction study on the bond compressibility of fayalite, Fe₂SiO₄ and rutile, TiO₂ under high pressure, Physica B, 139, 333-336
Tollo R P, Haggerty S E (1987) Nb–Cr-rutile in the Orapa kimberlite, Botswana, The Canadian Mineralogist, 25, 251-264 [view file]
Sugiyama K, Takéuchi Y (1991) The crystal structure of rutile as a function of temperature up to 1600°C, Zeitschrift für Kristallographie, 194, 305-313 [view file]
Bursill (1996) Boron incorporation into rutile. phase equilibria and structure considerations, Journal of Solid State Chemistry, 127, 240-247
Gesenhues U, Rentschler T (1999) Crystal growth and defect structure of Al³⁺-doped rutile, Journal of Solid State Chemistry, 143, 210-218
Bokhimi X, Morales A, Pedraza F (2002) Crystallography and crystallite morphology of rutile synthesized at low temperature, Journal of Solid State Chemistry, 169, 176-181
Toledo-Antonio J A, Gutierrez-Baez R, Sebastian P J, Vazquez A (2003) Thermal stability and structural deformation of rutile SnO₂, Journal of Solid State Chemistry, 174, 241-248
Clarke D B, Carruzzo S (2007) Assimilation of country-rock ilmenite and rutile in the South Mountain batholith, Nova Scotia, Canada, The Canadian Mineralogist, 45, 31-42 [view file]

REFERENCES for Rutile

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Schoβberger, F. (1942) Über die umwandlungen des titandioxyds, Journal of Solid State Chemistry, 104, 358-374

Baur W H (1956) Über die verfeinerung der kristallstrukturbestimmung einiger vertreter des rutiltyps: TiO₂, SnO₂, GeO₂ und MgF₂, Acta Crystallographica, 9, 515-520 [link]

Papezik V S, De Witt M J (1973) Shorter communications: Coarse-grained rutile from northern Newfoundland, The Canadian Mineralogist, 12, 224-225 [view file]

Corlett M I, McIlreath I A (1974) An authigenic quartz-calcite-rutile assemblage in ordovician limestones, The Canadian Mineralogist, 12, 411-416 [view file]

Meagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO₂ polymorphs: refinement of the crystal structures of rutile and brookite at high temperature, The Canadian Mineralogist, 17, 77-85 [view file]

Cerný P, Paul B J, Hawthorne F C, Chapman R (1981) A niobian rutile – disordered columbite intergrowth from the Huron Claim pegmatite, southeastern Manitoba, The Canadian Mineralogist, 19, 541-548 [view file]

Kudoh Y, Takeda H (1986) Single crystal X-ray diffraction study on the bond compressibility of fayalite, Fe₂SiO₄ and rutile, TiO₂ under high pressure, Physica B, 139, 333-336

Tollo R P, Haggerty S E (1987) Nb–Cr-rutile in the Orapa kimberlite, Botswana, The Canadian Mineralogist, 25, 251-264 [view file]

Sugiyama K, Takéuchi Y (1991) The crystal structure of rutile as a function of temperature up to 1600°C, Zeitschrift für Kristallographie, 194, 305-313 [view file]

Bursill (1996) Boron incorporation into rutile. phase equilibria and structure considerations, Journal of Solid State Chemistry, 127, 240-247

Gesenhues U, Rentschler T (1999) Crystal growth and defect structure of Al³⁺-doped rutile, Journal of Solid State Chemistry, 143, 210-218

Bokhimi X, Morales A, Pedraza F (2002) Crystallography and crystallite morphology of rutile synthesized at low temperature, Journal of Solid State Chemistry, 169, 176-181

Toledo-Antonio J A, Gutierrez-Baez R, Sebastian P J, Vazquez A (2003) Thermal stability and structural deformation of rutile SnO₂, Journal of Solid State Chemistry, 174, 241-248

Clarke D B, Carruzzo S (2007) Assimilation of country-rock ilmenite and rutile in the South Mountain batholith, Nova Scotia, Canada, The Canadian Mineralogist, 45, 31-42 [view file]