Lazurite R040023


Name: Lazurite
RRUFF ID: R040023
Ideal Chemistry: Na3Ca(Si3Al3)O12S
Locality: Chile
Source: University of Arizona Mineral Museum 6685 [view label]
Owner: RRUFF
Description: Blue fine-grained massive
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Groups: [ cancrinite-sodalite (35) ] [ sodalite (23) ]
CHEMISTRY 
RRUFF ID: R040023.2
Sample Description: Microprobe fragment, dark material is lazurite, medium gray is calcite, light material is a phosphate
Measured Chemistry: (Na0.99K0.01)6(Ca0.99Na0.01)2Al6.00Si6.00O24[(SO4)0.67S0.32Cl0.01]2
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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Raman Mode Analysis
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R040023
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R040023.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R040023.1
Sample Description: Powder
Cell Refinement Output: a: 9.0744(3)Å    b: 9.0744(3)Å    c: 9.0744(3)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 747.24(9)Å3    Crystal System: cubic
  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Lazurite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Hoffmann C A S (1789) Mineralsystem des Herrn Inspektor Werners mit dessen erlaubnis herausgegeben von C A S Hoffmann, Bergmannisches Journal, 1, 369-398   [view file]

Brögger W C, Bäckström H (1891) Die mineralien der Granatgruppe, Zeitschrift für Krystallographie und Mineralogie, 18, 209-276   [view file]

Leoni L, Mellini M, Merlino S, Orlandi P (1979) Cancrinite-like minerals: new data and crystal chemical considerations, Rendiconti della Società Italiana di Mineralogia e Petrologia, 35, 713-719   [view file]

Hassan I, Grundy H D (1984) The crystal structures of sodalite-group minerals, Acta Crystallographica, B40, 6-13

Hassan I, Peterson R C, Grundy H D (1985) The structure of lazurite, ideally Na6Ca2(Al6Si6O24)S2, a member of the sodalite group, Acta Crystallographica, C41, 827-832

Jambor J L, Puziewicz J (1991) New mineral names, American Mineralogist, 76, 1728-1735   [view file]

Jambor J L, Burke E A J (1993) New mineral names, American Mineralogist, 78, 845-849   [view file]

Jambor J L, Puziewicz J, Roberts A C (1994) New mineral names, American Mineralogist, 79, 763-767   [view file]

Ballirano P, Maras A, Buseck P R (1996) Crystal chemistry and IR spectroscopy of Cl- and SO4-bearing cancrinite-like minerals, American Mineralogist, 81, 1003-1012   [view file]

Evsyunin V G, Sapozhnikov A N, Kashaev A A, Rastsvetaeva R K (1997) Crystal structure of triclinic lazurite, Crystallography Reports, 42, 938-945

Evsyunin V G, Rastsvetaeva R K, Sapozhnikov A N, Kashaev A A (1998) Modulated structure of orthorhombic lazurite, Crystallography Reports, 43, 999-1002

Ostroumov M, Fritsch E, Faulques E, Chauvet O (2002) Etude spectrometrique de la lazurite du Pamir, Tajikistan, The Canadian Mineralogist, 40, 885-893   [view file]

Rastsvetaeva R K, Bolotina N B, Sapozhnikov A N, Kashaev A A, Schoenleber A, Chapuis G (2002) Average structure of cubic lazurite with a three-dimensional incommensurate modulation, Crystallography Reports, 47, 404-407

Tauson V L, Sapozhnikov A N (2003) On the nature of lazurite coloring, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 132, issue 5 102-107   [view file]

Brown K L, Clark R J H (2004) The Lindisfarne Gospels and two other 8th century Anglo-Saxon/insular manuscripts: pigment identification by Raman microscopy, Journal of Raman Spectroscopy, 35, 4-12

Fleet M E, Lui X, Harmer S L, Nesbitt H W (2005) Chemical state of sulfur in natural and synthetic lazurite by S K-edge XANES and X-ray photoelectron spectroscopy, The Canadian Mineralogist, 43, 1589-1603   [view file]

Hettmann K, Wenzel T, Marks M, Markl G (2012) The sulfur speciation in S-bearing minerals: New constraints by a combination of electron microprobe analysis and DFT calculations with special reference to sodalite-group minerals, American Mineralogist, 97, 1653-1661