Marialite R040043

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Record 1 of 10  

Name: Marialite
RRUFF ID: R040043
Ideal Chemistry: Na4Al3Si9O24Cl
Locality: Gouverneur, New York, USA
Source: University of Arizona Mineral Museum 8081 [view label]
Owner: RRUFF
Description: White prismatic crystals, associated with calcite
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Scapolite (11) ]
Quick search: [ All Marialite samples (10) ]
CHEMISTRY 
RRUFF ID: R040043.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Na.493Ca.446K.061)4(Si.634Al.366)12O24((CO3).581Cl.419)
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Sample is oriented, mounted onto a pin and polished
Pin ID: S00028
Orientation: Laser parallel to  a*  (1 0 0).     Fiducial mark perpendicular to laser is parallel to  c   [0 0 1].
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Raman Mode Analysis
Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R040043
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
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Raman Data (Processed)
RRUFF File
Raman Data (RAW) View Graph
RRUFF File
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R040043.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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Infrared Data (Processed)
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POWDER DIFFRACTION 
RRUFF ID: R040043.1
Sample Description: Powder, 78% marialite, 22% calcite, by weight
Cell Refinement Output: a: 12.1020(4)Å    b: 12.1020(4)Å    c: 7.5798(3)Å
alpha: 90.°    beta: 90.°    gamma: 90.°   Volume: 1110.13(7)Å3    Crystal System: tetragonal
  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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Cell Refinement Data
Cell Refinement Output Data
X-ray Data (XY - RAW) View Graph
RRUFF File
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REFERENCES for Marialite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

d’Andrada J B (1800) Der Eigenschaften und Kennzeichen einiger neuen Fossilien aus Schweden und Norwegen nebst einigen chemischen Bemerkungen über dieselben, Allgemeines Journal der Chemie, 4, 28-39   [view file]

d’Andrada J B (1801) Description of some new fossils (Old English translation), A Journal of Natural Philosophy, Chemistry, and the Arts, 5, 193-196; 211-213   [view file]

Haüy R J (1801) Wernerite, Traité de Minéralogie, 3, 119-125   [view file]

vom Rath G (1866) Mineralogisch-geognostische Fragmente aus Italien, Zeitschrift der Deutschen Geologischen Gesellschaft, 18, 487-642   [view file]

Pauling L (1930) The structure of some sodium and calcium aluminosilicates, Proceedings of the National Academy of Sciences, 16, 453-459   [view file]

Papike J J, Zoltai T (1965) The crystal structure of a marialite scapolite, American Mineralogist, 50, 641-655   [view file]

Lin S B, Burley B J (1973) Crystal structure of a sodium and chlorine-rich scapolite, Acta Crystallographica, B29, 1272-1278

Ulbrich H H (1973) Crystallographic data and refractive indices of scapolites, American Mineralogist, 58, 81-92   [view file]

Lin S B, Burley B J (1974) The crystal structure of an intermediate scapolite - wernerite, Tschermaks Mineralogische und Petrographische Mitteilungen, 21, 196-215

Llambías E J, Gordillo C E, Bedlivy D (1977) Scapolite veins in a quartz monzodiorite stock from Los Molles, Mendoza, Argentina, American Mineralogist, 62, 132-135   [view file]

Bayliss P (1987) Mineral nomenclature: scapolite, Mineralogical Magazine, 51, 176-176   [view file]

Zolotarev A A (1993) Gem scapolite from the Eastern Pamirs and some general consitutional features of scapolites, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 122, 90-102   [view file]

Sokolova E V, Kabalov Y K, Sherriff B L, Teertstra D K, Jenkins D M, Kunath-Fandrei G, Goetz S, Jäger C (1996) Marialite: Rietveld structure-refinement and 29Si MAS and 27Al satellite transition NMR spectroscopy, The Canadian Mineralogist, 34, 1039-1050   [view file]

Teertstra D K, Sherriff B L (1996) Scapolite cell-parameter trends along the solid-solution series, American Mineralogist, 81, 169-180   [view file]

Zolotarev A A (1996) Once more about schemes and rows of isomorphism within the scapolite group, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 125, issue 1 69-73   [view file]

Antao S M, Hassan I (2008) Increase in Al-Si and Na-Ca disorder with temperature in scapolite Me32.9, The Canadian Mineralogist, 46, 1577-1591   [view file]

Sokolova E, Hawthorne F C (2008) The crystal chemistry of the scapolite-group minerals. I. crystal structure and long-range order, The Canadian Mineralogist, 46, 1527-1554   [view file]

Antao S M, Hassan I (2011) Complete Al-Si order in scapolite Me37.5, ideally Ca3Na5[Al8Si16O48]Cl(CO3), and implications for antiphase domain boundaries (APBs), The Canadian Mineralogist, 49, 581-586   [view file]

Antao S M, Hassan I (2011) The structure of marialite (Me6) and meionite (Me93) in space groups P42/n and I4/m, and the absence of phase transitions in the scapolite series, International Centre for Diffraction Data, 26, 78-91   [view file]

Almeida K M F, Jenkins D M (2017) Stability field of the Cl-rich scapolite marialite, American Mineralogist, 102, 2484-2493