Olivenite R050532



Name: Olivenite
RRUFF ID: R050532
Ideal Chemistry: Cu2(AsO4)(OH)
Locality: Tsumeb mine, Tsumeb, Otavi District, Oshikoto, Namibia
Source: University of Arizona Mineral Museum 4809 [view label]
Owner: RRUFF
Description: Dark green prismatic crystals on botryoidal bayldonite R050670
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Andalusite (17) ]
Quick search: [ All Olivenite samples (2) ]
CHEMISTRY 
RRUFF ID: R050532.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Cu0.99Zn0.01)2(As1.00O4)(OH)
Reference File: [ View PDF ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050532
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050532.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050532.1
Sample Description: Powder
Cell Refinement Output: a: 8.6115(4)Å    b: 8.230(1)Å    c: 5.9382(7)Å
alpha: 90.12(2)°    beta: 90°    gamma: 90°   Volume: 420.87(8)Å3    Crystal System: monoclinic
  File Type Information Close
Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Olivenite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Hoffmann C A S (1789) Mineralsystem des Herrn Inspektor Werners mit dessen Erlaubnis herausgegeben von C A S Hoffmann, Bergmannisches Journal, 1, 369-398   [view file]

Jameson R (1820) Olivenite, System of Mineralogy, II, Archibald Constable and Co. Edinburgh, U.K. 331-346   [view file]

Larsen E S (1921) The microscopic determination of the nonopaque minerals, U.S. Geological Survey Bulletin, 671, 5-294   [view file]

Heritsch H (1938) Die struktur des olivenites Cu2(OH)(AsO4), Zeitschrift für Kristallographie, 99, 466-479   [view file]

Richmond W E (1940) Crystal chemistry of the phosphates, arsenates and vanadates of the type A2XO4(Z), American Mineralogist, 25, 441-478   [view file]

Berry L G (1951) Observations on chonichalcite, cornwallite, euchroite liroconite and olivenite, American Mineralogist, 36, 484-503   [view file]

Sumin de Portilla V I (1974) Infrared spectroscopic investigation of the structure of some natural arsenates and the nature of H-bonds in their structures, The Canadian Mineralogist, 12, 262-268   [view file]

Toman K (1977) The symmetry and crystal structure of olivenite, Acta Crystallographica, B33, 2628-2631

Toman K (1978) Ordering in olivenite-adamite solid solutions, Acta Crystallographica, B34, 715-721

Braithwaite R S W (1983) Infrared spectroscopic analysis of the olivenite-adamite series, and of phosphate substitution in olivenite, Mineralogical Magazine, 47, 51-57   [view file]

Chisholm J E (1985) Cation segregation and the O-H stretching vibration of the olivenite-adamite series, Physics and Chemistry of Minerals, 12, 185-190

Burns P C, Hawthorne F C (1995) Rietveld refinement of the crystal structure of olivenite: a twinned monoclinic structure, The Canadian Mineralogist, 33, 885-888   [view file]

Frost R L, Martens W N, Williams P A (2002) Raman spectroscopy of the phase-related basic copper arsenate minerals olivenite, cornwallite, cornubite and clinoclase, Journal of Raman Spectroscopy, 33, 475-484   [link]

Martens W N, Frost R L, Kloprogge J T, Williams P A (2003) The basic copper arsenate minerals olivenite, cornubite, cornwallite, and clinoclase: An infrared emission and Raman spectroscopic study, American Mineralogist, 88, 501-508   [view file]

Li C, Yang H, Downs R T (2008) Redetermination of olivenite from an untwinned single-crystal, Acta Crystallographica, E64, i60-i61   [view file]

Majzlan J, Zittlau A H, Grevel K, Schliesser J, Woodfield B F, Dachs E, Števko M, Chovan M, Plášil J, Sejkora J, Milovská S (2015) Thermodynamic properties and phase equilibria of the secondary copper minerals libethenite, olivenite, pseudomalachite, kröhnkite, cyanochroite, and devilline, The Canadian Mineralogist, 53, 937-960

Tarantino S C, Zema M, Callegari A M, Boiocchi M, Carpenter M A (2018) Monoclinic-to-orthorhombic phase transition in Cu2(AsO4)(OH) olivenite at high temperature: strain and mode decomposition analyses, Mineralogical Magazine, 82, 347-365