Vanadinite R050533



Name: Vanadinite
RRUFF ID: R050533
Ideal Chemistry: Pb5(VO4)3Cl
Locality: Ahumada mine, Los Lamentos, Mexico
Source: University of Arizona Mineral Museum 1028 [view label]
Owner: RRUFF
Description: Greenish-brown hexagonal prisms
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Apatite (55) ]
Quick search: [ All Vanadinite samples (5) ]
CHEMISTRY 
RRUFF ID: R050533.2
Sample Description: Microprobe Fragment
Measured Chemistry: Pb5.00((V0.95As0.05)O4)3Cl1.00
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050533
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050533.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
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POWDER DIFFRACTION 
RRUFF ID: R050533.1
Sample Description: powder
Cell Refinement Output: a: 10.3188(5)Å    b: 10.3188(5)Å    c: 7.3505(6)Å
alpha: 90.°    beta: 90.°    gamma: 120.°   Volume: 677.81(7)Å3    Crystal System: hexagonal
  File Type Information Close
Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Vanadinite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

von Kobell F (1838) Vanadinit, in Grundzüge der Mineralogie Nürnberg 283-283   [view file]

Rammelsberg C (1880) Ueber die vanadinerze aus dem Staat Córdoba in Argentinien, Zeitschrift der Deutschen Geologischen Gesellschaft, 32, 708-713   [view file]

Trotter J, Barnes W H (1958) The structure of vanadinite, The Canadian Mineralogist, 6, 161-173   [view file]

Barnes W H (1962) Shorter communications: The X-ray diffraction powder pattern of vanadinite, The Canadian Mineralogist, 7, 301-306   [view file]

Dai Y, Hughes J M (1989) Crystal-structure refinements of vanadinite and pyromorphite, The Canadian Mineralogist, 27, 189-192   [view file]

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of flourides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970

Frost R L, Crane M, Williams P A, Kloprogge J T (2003) Isomorphic substitution in vanadinite [Pb5(VO4)3Cl]—a Raman spectroscopic study, Journal of Raman Spectroscopy, 34, 214-220

Laufek F, Skala R, Haloda J, Cisarova I (2009) Crystal structure of vanadinite: refinement of anisotropic displacement parameters, Journal of the Czech Geological Society, 51, 271-275

Redfern S A T, Smith S E, Maddrell E R (2012) High-temperature breakdown of the synthetic iodine analogue of vanadinite, Pb5(VO4)3I: an apatite-related compound for iodine radioisotope immobilization, Mineralogical Magazine, 76, 997-1003   [view file]

Okudera H (2013) Relationships among channel typology and atomic displacements in the structures of Pb5(BO4)3Cl with B = P (pyromorphite), V (vanadinite), and As (mimetite), American Mineralogist, 98, 1573-1579

Baikie R, Schreyer M, Wei F, Herrin J S, Ferraris C, Brink F, Topolska J, Piltz R O, Price J, White T J (2014) The influence of stereochemically active lone-pair electrons on crystal symmetry and twist angles in lead apatite-2H type structures, Mineralogical Magazine, 78, 325-345

Markl G, Marks M A W, Holzäpfel J, Wenzel T (2014) Major, minor, and trace element composition of pyromorphite-group minerals as recorder of supergene weathering processes from the Schwarzwald mining district, SW Germany, American Mineralogist, 99, 1133-1146