Tripuhyite R070383



Name: Tripuhyite
RRUFF ID: R070383
Ideal Chemistry: Fe3+Sb5+O4
Locality: Cetine mine, Chiusdino, Siena Province, Tuscany, Italy
Source: Michael Scott S104750 [view label]
Owner: RRUFF
Description: Transparent grey greenish acicular crystals associated with valentinite, clinocervantite R070385, and rosiaite R070384
Status: The identification of this mineral has been confirmed only by single crystal X-ray diffraction.
Mineral Group: [ Rutile (18) ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R070383
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
POWDER DIFFRACTION 
RRUFF ID: R070383.9
Sample Description: Single crystal, powder profile is calculated
Cell Refinement Output: a: 4.634(1)Å    b: 4.634(1)Å    c: 9.209(3)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 197.75(6)Å3    Crystal System: tetragonal
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Tripuhyite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Hussak E, Prior G T (1897) On tripuhyite, a new antimonate of iron, from Tripuhy, Brazil, Mineralogical Magazine, 11, 302-303   [view file]

Byström A, Hök B, Mason B (1942) The crystal structure of zinc metantimonate and similar compounds, Arkiv för Kemi, Mineralogi och Geologi, 15B4, 1-8

Donaldson J D, Kjekshus A, Nicholson D G, Rakke T (1975) Properties of Sb-compounds with rutile-like structures, Acta Chemica Scandinavica, A29, 803-809

Basso R, Cabella R, Lucchetti G, Marescotti P, Martinelli A (2003) Structural studies on synthetic and natural Fe-Sb-oxides of MO2 type, Neues Jahrbuch für Mineralogie, Monatshefte, 2003, 407-420

Berlepsch P, Armbuster T, Brugger J, Criddle A J, Graeser S (2003) Tripuhyite, FeSbO4, revisited, Mineralogical Magazine, 67, 31-46   [view file]

Grice J D, Ferraris G (2003) New minerals approved in 2002 and nomenclature modifications approved in 1998-2002 by the Commission on the New Minerals and Mineral Names, International Mineralogical Association, The Canadian Mineralogist, 41, 795-802   [view file]

Leverett P, Reynolds J K, Roper A J, Williams P A (2012) Tripuhyite and schafarzikite: two of the ultimate sinks for antimony in the natural environment, Mineralogical Magazine, 76, 891-902   [view file]

Roper A J, Leverett P, Murphy T D, Williams P A (2018) The stability of the rare sodium antimonate, brizziite, and it's role in Sb mobility, Mineralogical Magazine, 82, 89-93