Hureaulite R070452
Name: Hureaulite
RRUFF ID: R070452
Ideal Chemistry: Mn2+5(PO3OH)2(PO4)2·4H2O
Locality: Tip Top mine, Fourmile, Custer District, Custer County, South Dakota, USA
Source: Michael Scott S102347 [view label]
Owner: RRUFF
Description: Massive coarse pink granular
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Hureaulite (4) ]
Quick search: [ All Hureaulite samples (2) ]
CHEMISTRY 
RRUFF ID: R070452.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Mn2+3.83Fe2+0.62Mg0.33Ca0.22)Σ=5(P1.00O4)2(P1.00O3OH)2·4H2O; H2O estimated by difference; OH by charge balance
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R070452
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
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Raman Data (RAW) View Graph
RRUFF File
POWDER DIFFRACTION 
RRUFF ID: R070452.1
Sample Description: Powder
Cell Refinement Output: a: 17.610(1)Å    b: 9.1093(9)Å    c: 9.4906(9)Å
alpha: 90°    beta: 96.600(8)°    gamma: 90°   Volume: 1512.4(2)Å3    Crystal System: monoclinic
  File Type Information Close
Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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Cell Refinement Data
Cell Refinement Output Data
DIF File
X-ray Data (XY - Processed)
RRUFF File
X-ray Data (XY - RAW) View Graph
RRUFF File
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REFERENCES for Hureaulite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Vauquelin L N (1825) Analyse de l´huraulite, minéral trouvé dans la commune d´Hureaux, Annales de Chimie et de Physique, 3, 302-307   [view file]

Alluaud F (1826) Notices sur l'hétérosite, l'hureaulite (fer et manganèse phosphatés), et sur quelques autres minéraux du département de la Haute-Vienne, Anneles des Sciences Naturelles, 8, 334-354   [view file]

Brush G J, Dana E S, Wells H L (1890) On the mineral locality at Branchville, Connecticut: Fifth paper, American Journal of Science, 39, 201-216   [view file]

Yagi K, Fleischer M (1955) New mineral names, American Mineralogist, 40, 367-370   [view file]

Fisher D J (1964) Lithian hureaulite from the Black Hills, American Mineralogist, 49, 398-406   [view file]

Moore P B, Araki T (1973) Hureaulite, Mn52+ (H2O)4[PO3(OH)]2[PO4]2: Its atomic arrangement, American Mineralogist, 58, 302-307   [view file]

Shigley J E, Brown G E (1985) Occurance and alteration of phosphate minerals at the Stewart Pegmatite, Pala District, San Diego County, California, American Mineralogist, 70, 395-408   [view file]

Corbin D R, Whitney J F, Fultz W C, Stucky G D, Eddy M M, Cheetham A K (1986) Synthesis of open-framework transition-metal phosphates using organometallic precursors in acidic media. Preparation and structural characterization of Fe5P4O20H10 and NaFe3P3O12, Inorganic Chemistry, 25, 2279-2280

Frost R L, Erickson K L (2005) Near-infrared spectroscopic study of selected hydrated hydroxylated phosphates, Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, 61, 45-50   [link]

Dyar M D, Jawin E R, Breves E, Marchand G, Nelms M, Lane M D, Mertzman S A, Bish D L and Bishop J L (2014) Mössbauer parameters of iron in phosphate minerals: Implications for interpretation of martian data, American Mineralogist, 99, 914-942   [view file]

Gatta G D, Redhammer G J, Vignola P, Meven M, McIntyre G J (2016) Single-crystal neutron diffraction and Mössbauer spectroscopic study of hureaulite, (Mn,Fe)5(PO4)2(HPO4)2(H2O)4, European Journal of Mineralogy, 28, 93-103

Đorđević T, Gerger S, Karanović L (2017) Hydrothermal and ionothermal synthesis of mineral-related arsenates in the system CdO–MO–As2O5 (M2+ = Mg, Co, Ni, Cu, Zn) and their crystal structures, European Journal of Mineralogy, 29, 73-89