Azurite R050497

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Name: Azurite
RRUFF ID: R050497
Ideal Chemistry: Cu3(CO3)2(OH)2
Locality: Tsumeb mine, Tsumeb, Otavi District, Oshikoto, Namibia
Source: Marcus Origlieri
Owner: RRUFF
Description: Blue prismatic single crystal
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Not in a structural group (133) ]
Quick search: [ All Azurite samples (2) ]
CHEMISTRY 
RRUFF ID: R050497.2
Sample Description: Microprobe Fragment
Measured Chemistry: Cu3.00(CO3)2(OH)2
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Sample is oriented and mounted on a pin
Pin ID: L01223
Orientation: Laser parallel to  -a*  (-1 0 0).     Fiducial mark perpendicular to laser is parallel to  b   [0 1 0].
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050497
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
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Raman Data (Processed)
RRUFF File
Raman Data (RAW) View Graph
RRUFF File
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050497.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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Infrared Data (Processed)
RRUFF File
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RRUFF ID: R050497.1
Sample Description: Powder
Instrument settings: PIKE GladiATR - Far-IR on a Nicolet Magna 860 FTIR
Resolution:
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Infrared Data (Processed)
RRUFF File
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POWDER DIFFRACTION 
RRUFF ID: R050497.1
Sample Description: Powder
Cell Refinement Output: a: 5.0095(2)Å    b: 5.8455(2)Å    c: 10.3441(5)Å
alpha: 90.°    beta: 92.420(3)°    gamma: 90.°   Volume: 302.64(1)Å3    Crystal System: monoclinic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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Cell Refinement Data
Cell Refinement Output Data
DIF File
X-ray Data (XY - Processed)
RRUFF File
X-ray Data (XY - RAW) View Graph
RRUFF File
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REFERENCES for Azurite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Jameson R (1805) Azurite, System of Mineralogy, II, Bell and Bradfute Edinburgh, U.K. 542-544   [view file]

Beudant F S (1832) Azurite, in Traité Élémentaire de Minéralogie, 2nd Edition Paris 373-374   [view file]

Zigan F, Schuster H D (1972) Verfeinerung der struktur von azurit, Cu3(OH)2(CO3)2, durch neutronenbeugung, Zeitschrift für Kristallographie, 135, 416-436   [view file]

Seguin M K (1975) Thermogravimetric and differential thermal analysis of malachite and azurite in inert atmospheres and in air, The Canadian Mineralogist, 13, 127-132   [view file]

International Mineralogical Association (1980) International Mineralogical Association: Commission on new minerals and mineral names, Mineralogical Magazine, 43, 1053-1055   [view file]

Belokoneva E L, Gubina Y K, Forsyth J B (2001) The charge density distribution and antiferromagnetic properties of azurite Cu3[CO3]2(OH)2, Physics and Chemistry of Minerals, 28, 498-507

Frost R L, Martens W N, Rintoul L, Mahmutagic E, Kloprogge J T (2002) Raman spectroscopic study of azurite and malachite at 298 and 77 K, Journal of Raman Spectroscopy, 33, 252-259

Buzgar N, Apopei A I (2009) The Raman study of certain carbonates, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 55, 97-112   [view file]

Markl G, Keim M F, Bayerl R (2019) Unusual mineral diversity in hydrothermal vein-type deposit: The Clara mine, SW Germany, as a type example, The Canadian Mineralogist, 57, 427-456