Baddeleyite R060078

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Record 2 of 3  

Name: Baddeleyite
RRUFF ID: R060078
Ideal Chemistry: ZrO2
Locality: Wetloo mine, Mogok, Burma
Source: Marcus Origlieri
Owner: RRUFF
Description: Dark brown fragment
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Baddeleyite (3) ]
Quick search: [ All Baddeleyite samples (3) ]
CHEMISTRY 
RRUFF ID: R060078.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Zr0.99Hf0.01)Σ=1O2
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Sample is oriented, mounted onto a pin.
Pin ID: L01986
Orientation: Laser parallel to  a*  (1 0 0).     Fiducial mark perpendicular to laser is parallel to  -b   [0 -1 0].
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Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R060078
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R060078.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R060078.1
Sample Description: Powder
Cell Refinement Output: a: 5.1471(3)Å    b: 5.2130(3)Å    c: 5.3148(3)Å
alpha: 90°    beta: 99.215(4)°    gamma: 90°   Volume: 140.766(9)Å3    Crystal System: monoclinic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Baddeleyite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Fletcher L (1893) On baddeleyite (native zirconia), a new mineral, from Rakawana, Ceylon, Mineralogical Magazine, 10, 148-160   [view file]

Hiemstra S A (1955) Baddeleyite from Phalaborwa, Eastern Transvaal, American Mineralogist, 40, 275-282   [view file]

McCullough J D, Trueblood K N (1959) The crystal structure of baddeleyite (monoclinic ZrO2), Acta Crystallographica, 12, 507-511

Smith D K, Newkirk W (1965) The crystal structure of baddeleyite (monoclinic ZrO2) and its relation to the polymorphism of ZrO2, Acta Crystallographica, A18, 983-991

Keramidas V G, White W B (1974) Raman scattering study of the crystallization and phase transformations of ZrO2, Journal of the American Ceramic Society, 57, 22-24

Andrews A J, Masliwec A, Morris W A, Owsiacki L, York D (1986) The silver deposits at Cobalt and Gowganda, Ontario. II: An experiment in age determinations employing radiometric and paleomagnetic measurements, Canadian Journal of Earth Sciences, 23, 1507-1518

Naslund H R (1987) Lamellae of baddeleyite and Fe–Cr-spinel in ilmenite from the Basistoppen sill, east Greenland, The Canadian Mineralogist, 25, 91-96   [view file]

Howard C J, Hill R J, Reichert B E (1988) Structures of the ZrO2 polymorphs at room temperature by high-resolution neutron powder diffraction, Acta Crystallographica, B44, 116-120

Cabella R, Gazzotti M, Lucchetti G (1997) Loveringite and baddeleyite in layers of chromian spinel from the Bracco ophiolitic unit, northern Apennines, Italy, The Canadian Mineralogist, 35, 899-908   [view file]

Torres F J, Amigo J M, Alarcon J (2003) X-ray powder diffraction study of monoclinic V4+–ZrO2 solid solutions obtained from gels, Journal of Solid State Chemistry, 173, 40-44

Swamy V, Dubrovinsky L S, Dubrovinskaia N A, Langenhorst F, Simionovici A S, Drakopoulos M, Dmitriev V, Weber H P (2005) Size effects on the structure and phase transition behavior of baddeleyite TiO2, Solid State Communications, 134, 541-546

Glass B P, Fries M (2008) Micro-Raman spectroscopic study of fine-grained, shock-metamorphosed rock fragments from the Australasian microtektite layer, Meteoritics and Planetary Science, 43, 1487-1496   [view file]

Giebel R J, Gauert C D K, Marks M A W, Costin G, Markl G (2017) Multi-stage formation of REE minerals in the Palabora Carbonatite Complex, South Africa, American Mineralogist, 102, 1218-1233