Chabazite-Ca R050014

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Name: Chabazite-Ca
RRUFF ID: R050014
Ideal Chemistry: Ca2[Al4Si8O24]·13H2O
Locality: Tablo Mountain, Baja California, Mexico
Source: University of Arizona Mineral Museum 13680 [view label]
Owner: RRUFF
Description: Light tan colored rhombohedral single crystals
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Chabazite (8) ]
Quick search: [ All Chabazite-Ca samples (4) ]
CHEMISTRY 
RRUFF ID: R050014.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Ca0.72Mg0.11K0.09Sr0.06Na0.01)Σ=1(Si4.12Al1.88)O12·6H2O
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Sample is oriented and mounted onto a pin.
Pin ID: M00165
Orientation: Laser parallel to  (-1 -1 -1).     Fiducial mark perpendicular to laser is parallel to  [-1 1 0].
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Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050014
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050014.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050014.1
Sample Description: Powder
Cell Refinement Output: a: 9.3992(2)Å    b: 9.3992(2)Å    c: 9.3992(2)Å
alpha: 94.2849(4)°    beta: 94.2849(4)°    gamma: 94.2849(4)°   Volume: 823.04(6)Å3    Crystal System: rhombohedral
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Chabazite-Ca

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Bosc D'Antic L (1792) Mémoire sur la chabazie, Journal d'Histoire Naturelle, 2, 181-184   [view file]

Dent L S, Smith J V (1958) Crystal structure of chabazite, a molecular sieve, Nature, 181, 1794-1796

Smith J V, Rinaldi F, Dent Glasser L S (1963) Crystal structures with a chabazite framework. II. Hydrated Ca-chabazite* at room temperature, Acta Crystallographica, 16, 45-53

Ames L L (1966) Alkali metal cation equilibria with chabazite, The Canadian Mineralogist, 8, 572-581   [view file]

Passaglia E (1970) The crystal chemistry of chabazites, American Mineralogist, 55, 1278-1301   [view file]

Bailey S W (1977) Report of the I.M.A-I.U.Cr. Joint Committee on Nomenclature, American Mineralogist, 62, 411-415   [view file]

Alberti A, Galli E, Vezzalini G, Passaglia E, Zanazzi P F (1982) Position of cations and water molecules in hydrated chabazite. Natural and Na-, Ca-, Sr- and K-exchanged chabazites, Zeolites, 2, 303-309

Calligaris M, Nardin G, Randaccio L (1982) Cation-site location in a natural chabazite, Acta Crystallographica, B38, 602-605

Mazzi F, Galli E (1983) The tetrahedral framework of chabazite, Neues Jahrbuch für Mineralogie, Monatshefte, 1983, 461-480

Goryainov S V, Belitsky I A (1995) Raman spectroscopy of water tracer diffusion of zeolite single crystals, Physics and Chemistry of Minerals, 22, 443-452   [link]

Coombs D S, Alberti A, Armbruster T, Artioli G, Colella C, Galli E, Grice J D, Liebau F, Mandarino J A, Minato H, Nickel E H, Passaglia E, Peacor D R, Quartieri S, Rinaldi R, Ross M, Sheppard R A, Tillmanns E, Vezzalini G, (1997) Recommended nomenclature for zeolite minerals: report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names, The Canadian Mineralogist, 35, 1571-1606   [view file]

Jambor J L, Grew E S, Roberts A C (1998) New mineral names, American Mineralogist, 83, 1347-1352   [view file]

Passaglia E, Ferro O (2002) Occurrence and crystal structure of magnesian chabazite, Studies in Surface Science and Catalysis, 142, 1729-1735

Nakatsuka A, Okada H, Fujiwara K, Nakayama N, Mizota T (2007) Crystallographic configurations of water molecules and exchangeable cations in a hydrated natural CHA-zeolite (chabazite), Microporous and Mesoporous Materials, 102, 188-195