Abstract: The crystal structure of caratiite, K₄Cu₄O₂ (SO₄)₄MeCl (a 13.60(2), c 4.98(1) Å, Z = 2) was solved in space group I4 from single crystal data, and refined to R = 0.035 for 654F_o > 6σ(F_o). The atomic arrangement is characterized by Cu₂O(SO₄)₂ chains parallel to [001], with Cu in (4 + 1) co-ordination and O surrounded tetrahedrally by four Cu atoms. These chains are interconnected by K atoms to a framework, the channels of which house the Me and Cl atoms. The nature of the Me atoms is not completely clear; most probably the position is half occupied by Cu, fully occupied by Na, or occupied by a mixture of the two.