Abstract: The Kruidfontein volcanic complex is a Proterozoic collapsed carbonatitic caldera structure, the inner caldera of which is filled with carbonatitic bedded volcaniclastic rocks cut by carbonatite dykes, and the outer with bedded silicate tuffs. As well as numerous fragments of phonolitic pumice in the silicate tuffs, there are unusual banded fragments composed of alternating silicate and carbonate compositions which appear to have been originally glasses, and which give evidence for mechanical mixing of magmas which may originally have been magmas separated by liquid immiscibility. The fragments have also been strongly fenitized with the introduction of K and the replacement of Al by Fe.