Abstract: Wonchi volcano (Ethiopia) is the second locality for wilkinsonite, the new mineral related to aenigmatite via the coupled substitution 2Fe³⁺ = TiFe²⁺. Wilkinsonite occurs as relics surrounded by rims of riebeckite and biotite in a syenitic ejectum which also contains microphenocrysts of aenigmatite. The two minerals do not represent an equilibrium pair. They both formed in the magma chamber under plutonic to hypabyssal conditions, but during two following stages of crystallisation separated by a major drop in ƒ_O2 conditions.