Magnetite R080025

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Record 5 of 6  


Name: Magnetite
RRUFF ID: R080025
Ideal Chemistry: Fe2+Fe3+2O4
Locality: 2500' level, Zinc Corporation of America mine #4, Balmat, New York, USA
Source: William W. Pinch [view label]
Owner: RRUFF
Description: Black cubes
Status: The identification of this mineral has been confirmed by X-ray diffraction.
Mineral Group: [ Spinel (57) ]
Quick search: [ All Magnetite samples (6) ]
CHEMISTRY 
RRUFF ID: R080025.2
Sample Description: Microprobe Fragment
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
DOWNLOADS:

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Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R080025
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R080025.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R080025.1
Sample Description: Powder
Cell Refinement Output: a: 8.3995(3)Å    b: 8.3995(3)Å    c: 8.3995(3)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 592.59(6)Å3    Crystal System: cubic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Magnetite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Hoffmann C A S (1789) Mineralsystem des Herrn Inspektor Werners mit dessen erlaubnis herausgegeben von C A S Hoffmann, Bergmannisches Journal, 1, 369-398   [view file]

Haidinger W (1845) Zweite Klasse: Geogenide. XI. Ordnung, Erze. X. Eisennerz. Magnetit., in Handbuch der Bestimmenden Mineralogie Bei Braumüller and Seidel Wien 546-555   [view file]

Hutton C O (1950) Studies of heavy detrital minerals, Bulletin of the Geological Society of America, 61, 635-710   [view file]

Feitknecht W, Brunner P, Oswalk HR (1962) Über den Einfluβ der Feuchtigkeit auf die Oxydation von Manganhydroxid durch molekularen Sauerstoff, Zeitschrift für Anorganische und Allgemeine Chemie, 316, 154-160

Pajari G E (1966) Abstract of paper presented at the eleventh meeting: The variation of magnetite–ulvospinel and hematite–ilmenite compositions in a differentiated alkaline intrusive, The Canadian Mineralogist, 8, 670-670   [view file]

Annersten H, Hafner S S (1973) Vacancy distribution in synthetic spinels of the series Fe304–γ–Fe2O3, Zeitschrift für Kristallographie, 137, 321-340

Volenik K, Seberini M, Neid J (1975) A Mössbauer and X-ray diffraction study of nonstoichiometry in magnetite, Czechoslovak Journal of Physics, 25, 1063-1071

Henriquez F, Martin R F (1978) Crystal-growth texture in magnetite flows and feeder dykes, El Laco, Chile, The Canadian Mineralogist, 16, 581-589   [view file]

Fleet M E, Bilcox G A, Barnett R L (1980) Oriented magnetite inclusions in pyroxenes from the Grenville province, The Canadian Mineralogist, 18, 89-99   [view file]

D’arco P, Maury R C (1981) Comparative geothermometry of some magnetite–ilmenite–orthopyroxene–clinopyroxene associations from volcanic rocks, The Canadian Mineralogist, 19, 461-467   [view file]

Fleet M E (1981) The structure of magnetite, Acta Crystallographica, B37, 917-920

Spear F S (1982) Phase equilibria of amphibolites from the post pond volcanics, Mt. cube quadrangle, Vermont, Journal of Petrology, 23, 383-426

Fleet M E (1984) The structure of magnetite: two annealed natural magnetites, Fe3.005O4 and Fe2.96Mg0.04O4, Acta Crystallographica, C40, 1491-1493

Wechsler B A, Lindsley D H, Prewitt C T (1984) Crystal structure and cation distribution in titanomagnetites (Fe3-xTixO4), American Mineralogist, 69, 754-770   [view file]

Fleet M E (1986) The structure of magnetite: symmetry of cubic spinels, Journal of Solid State Chemistry, 62, 75-82

Hill R L, Sack R O (1987) Thermodynamic properties of Fe-Mg titaniferous magnetite spinels, The Canadian Mineralogist, 25, 443-464   [view file]

Schwertmann U and Murad E (1990) The influence of aluminum on iron oxides: XIV. Al-substituted magnetite synthesized at ambient temperatures, Clays and Clay Minerals, 38, 196-202

Maier W D, Barnes S J (1996) Unusually high concentrations of magnetite at Caraíba and other Cu-sulfide deposits in the Curaçá Valley, Bahia, Brazil, The Canadian Mineralogist, 34, 717-731   [view file]

de Faria D L A, Silva S V, de Oliveira M T (1997) Raman microspectroscopy of some iron oxides and oxyhydroxides, Journal of Raman Spectroscopy, 28, 873-878   [link]

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Gasparov L V, Tanner D B, Romero D B, Berger H, Margaritondo G, Forro L (2000) Infrared and Raman studies of the Verwey transition in magnetite, Physical Review B, 62, issue 12 7939-7944

Beard J S, Tracy R J (2002) Spinels and other oxides in Mn-rich rocks from the Hutter Mine, Pittsylvania County, Virginia, U.S.A.: implications for miscibility and solvus relations among jacobsite, galaxite, and magnetite, American Mineralogist, 87, 690-698   [view file]

Frankel R B, Bazylinski D A (2003) Biologically induced mineralization by bacteria, Reviews in Mineralogy and Geochemistry, 54, 95-114

Kretz R (2003) Dendritic magnetite and ilmenite in 590 Ma Grenville dikes near Otter Lake, Quebec, Canada, The Canadian Mineralogist, 41, 1049-1059   [view file]

Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147   [view file]

Shebanova O N, Lazor P (2003) Raman study of magnetite (Fe3O4): laser-induced thermal effects and oxidation, Journal of Raman Spectroscopy, 34, 845-852

Yang J B, Zhou X D, Yelon W B, James W J, Cai Q, Gopalakrishnan K V, Malik S K, Sun X C, Nikles D E (2004) Magnetic and structural studies of the Verwey transition in Fe3–δO4 nanoparticles, Journal of Applied Physics, 95, 7540-7542

Cvejic Z, Rakic S, Kremenovic A, Antic B, Jovalekic C, Colomban P (2006) Nanosize ferrites obtained by ball milling: crystal structure, cation distribution, size-strain analysis and raman investigations, Solid State Sciences, 8, 908-915

Schmidbauer E, Keller M (2006) Magnetic hysteresis properties, Mossbauer spectra and structural data of spherical 250 nm particles of solid solutions Fe3O4-γ-Fe2O3, Journal of Magnetism and Magnetic Materials, 297, 107-117

Gatta G D, Kantor I, Ballaran T B, Dubrovinsky L, McCammon C (2007) Effect of non-hydrostatic conditions on the elastic behaviour of magnetite: an in situ single-crystal X-ray diffraction study, Physics and Chemistry of Minerals, 34, 627-635

Glass B P, Fries M (2008) Micro-Raman spectroscopic study of fine-grained, shock-metamorphosed rock fragments from the Australasian microtektite layer, Meteoritics and Planetary Science, 43, 1487-1496   [view file]

Bosi F, Hålenius U, Skogby H (2009) Crystal chemistry of the magnetite-ulvöspinel series, American Mineralogist, 94, 181-189   [view file]

Gotic M, Koscec G, Music S (2009) Study of the reduction and reoxidation of substoichiometric magnetite, Journal of Molecular Structure, 924-26, 347-354

Gorski C A, Scherer M M (2010) Determination of nanoparticulate magnetite stoichiometry by Mössbauer spectroscopy, acidic dissolution, and powder X-ray diffraction: A critical review, American Mineralogist, 95, 1017-1026

Zinin P, Tatsumi-Petrochilos L, Bonal L, Acosta T, Hammer J, Gilder S, Fuller M (2011) Raman spectroscopy of titanomagnetites: Calibration of the intensity of Raman peaks as a sensitive indicator for their Ti content, American Mineralogist, 96, 1537-1546   [view file]

Glazyrin K, McCammon C, Dubrovinsky L, Merlini M, Schollenbruch K, Woodland A, Hanfland M (2012) Effect of high pressure on the crystal structure and electronic properties of magnetite below 25 GPa, American Mineralogist, 97, 128-133   [view file]

Woodland A B, Frost D J, Trots D M, Klimm K, Mezouar M (2012) In situ observation of the breakdown of magnetite (Fe3O4) to Fe4O5 and hematite at high pressures and temperatures, American Mineralogist, 97, 1808-1811   [view file]

Yamanaka T, Kyono A, Nakamoto Y, Meng Y, Kharlamova S, Struzhkin V V, Mao H (2013) High-pressure phase transitions of Fe3-xTixO4 solid solution up to 60 GPa correlated with electronic spin transition, American Mineralogist, 98, 736-744

Guignard J, Crichton W A (2014) Synthesis and recovery of bulk Fe4O5 from magnetite, Fe3O4. A member of a self-similar series of structures for the lower mantle and transition zone, Mineralogical Magazine, 78, 361-371

Koch-Müller M, Mugnaioli E, Rhede D, Speziale S, Kolb U, Wirth R (2014) Synthesis of a quenchable high-pressure form of magnetite (h-Fe3O4) with composition Fe1(Fe2+0.75Mg0.26)Fe2(Fe3+0.70Cr0.15Al0.11Si0.04)2O4, American Mineralogist, 99, 2405-2415

Wang M, Chou I, Lu W, de Vivo B (2015) Effects of CH4 and CO2 on the sulfidization of goethite and magnetite: an in situ Raman spectroscopic study in high-pressure capillary optical cells at room temperature, European Journal of Mineralogy, 27, 193-201

Giebel R J, Gauert C D K, Marks M A W, Costin G, Markl G (2017) Multi-stage formation of REE minerals in the Palabora Carbonatite Complex, South Africa, American Mineralogist, 102, 1218-1233

Uenver-Thiele L, Woodland A B, Ballaran T B, Miyajima N, Frost D J (2017) Phase relations of Fe-Mg spinels including new high-pressure post-spinel phases and implications for natural samples, American Mineralogist, 102, 2054-2064

Capitani G C, Ventruti G (2018) Ni-serpentine nanoflakes in the garnierite ore from Campello Monti (Strona Valley, Italy): Népouite with some pecoraite outlines and the processing of Ni-containing ore bodies, American Mineralogist, 103, 629-644