Nickelskutterudite R100194

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Record 2 of 3  


Name: Nickelskutterudite
RRUFF ID: R100194
Ideal Chemistry: (Ni,Co,Fe)As3
Locality: Schneeberg, Saxony, Germany
Source: University of Arizona Mineral Museum 1197 [view label]
Owner: RRUFF
Description: Silver euhedral twinned crystals, roughly dodecahedral
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.
Mineral Groups: [ Skutterudite (6) ] [ Perovskite (38) ]
Quick search: [ All Nickelskutterudite samples (3) ]
CHEMISTRY 
RRUFF ID: R100194.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Ni0.69Co0.26Fe0.06)Σ=1.01(As2.95S0.04Bi0.01)Σ=3.00 ; Dark Band ; (Ni0.86Co0.14Fe0.01)Σ=1.01(As2.99S0.01)Σ=3.00 Light Band
Microprobe Data File: [ Download Excel File ]
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented Raman on the primary sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R100194
Wavelength:
Sample Description: Unoriented Raman on the primary sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
POWDER DIFFRACTION 
RRUFF ID: R100194.9
Sample Description: Single crystal, powder profile is calculated
Cell Refinement Output: a: 8.2876(5)Å    b: 8.2876(5)Å    c: 8.2876(5)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 569.2(1)Å3    Crystal System: cubic
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REFERENCES for Nickelskutterudite

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Breithaupt J F A (1845) Ueber das nickel-biarseniet, Annalen der Physik und Chemie, 64, 184-185   [view file]

Waller E, Moses A J (1893) A probably new nickel arsenide (preliminary notice), The School of Mines Quarterly, 14, 49-51   [view file]

Oftedal I (1928) Die Kristallstruktur von Skutterudit und Speiskobalt-Chloanthit, Zeitschrift für Kristallographie, 66, 517-546

Fleischer M (1943) New mineral names, American Mineralogist, 28, 61-64   [view file]

Holmes R J (1947) Higher mineral arsenides of cobalt, nickel, and iron, Geological Society of America Bulletin, 58, 299-392   [view file]

Roseboom E H (1962) Skutterudites (Co,Ni,Fe)As3-x: Composition and cell dimensions, American Mineralogist, 47, 310-327   [view file]

Kjekshus A, Rakke T (1974) Compounds with the skutterudite type crystal structure. III. Structural data for arsenides and antimonides, Acta Chemica Scandinavica, A28, 99-103

Bayliss P (2001) Dienerite - a mystification, Mineralogical Magazine, 65, 685-687   [view file]

Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147   [view file]

Spiridonov E M, Gritsenko Y D (2007) Ferroskutterudite, nickelskutterudite, and skutterudite from the Norilsk ore field, New Data on Minerals. Moscow, 42, 16-27   [view file]

Burke E A J (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks, The Mineralogical Record, 39, 131-135   [view file]

Hålenius U, Hatert F, Pasero M, Mills S J (2017) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) Newsletter 35. New minerals and nomenclature modifications approved in 2016 and 2017, Mineralogical Magazine, 81, 209-213   [view file]

Mitchell R H, Welch M D, Chakhmouradian A R (2017) Nomenclature of the perovskite supergroup: A hierarchical system of classification based on crystal structure and composition, Mineralogical Magazine, 81, 411-461   [view file]

Schumer B N, Andrade M B, Evans S H, Downs R T (2017) A new formula and crystal structure for nickelskutterudite, (Ni,Co,Fe)As3, and occupancy of the icosahedral cation site in the skutterudite group, American Mineralogist, 102, 205-209