Phlogopite R070330

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Record 4 of 4  


Name: Phlogopite
RRUFF ID: R070330
Ideal Chemistry: KMg3(AlSi3O10)(OH)2
Locality: Little Chief mine, Whitehorse, Yukon Territory, Canada
Source: Mark Mauthner 3479 [view label]
Owner: RRUFF
Description: Green micaceous
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Groups: [ mica (50) ] [ Clay (86) ]
Quick search: [ All Phlogopite samples (4) ]
CHEMISTRY 
RRUFF ID: R070330.2
Sample Description: Microprobe Fragment
Measured Chemistry: K1.00(Mg2.65Fe2+0.34Ti0.01)Σ=3(Si2.98Al1.02)O10((OH)1.77F0.23)Σ=2; (gray area) trace amounts of Mn; OH by charge balance; light phase is diopside: Ca1.00(Mg0.96Fe0.04)Σ=1Si2.00O6; dark phase: Mg-rich chlorite
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R070330
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
POWDER DIFFRACTION 
RRUFF ID: R070330.1
Sample Description: Powder
Cell Refinement Output: a: 5.3725(3)Å    b: 9.1621(3)Å    c: 10.2967(4)Å
alpha: 90°    beta: 100.50(1)°    gamma: 90°   Volume: 498.35(3)Å3    Crystal System: monoclinic
  File Type Information Close
Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Phlogopite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Breithaupt J F A (1841) Phengites Phlogopites, in Vollständige Charakteristik des Mineral-Systems 2nd Edition Arnoldische Buchhandlung Dresden and Leipzig 398-399   [view file]

Ross C S, Kerr P F (1932) The manganese minerals of a vein near Bald Knob, North Carolina, American Mineralogist, 17, 1-18   [view file]

Yoder H S, Eugster H P (1954) Phlogopite synthesis and stability range, Geochimica et Cosmochimica Acta, 6, 157-185

Faye G H (1968) The optical absorption spectra of iron in six-coordinate sites in chlorite, biotite, phlogopite and vivianite. Some aspects of pleochroism in the sheet silicates, The Canadian Mineralogist, 9, 403-425   [view file]

Faye G H, Hogarth D D (1969) On the origin of 'reverse pleochroism' of a phlogopite, The Canadian Mineralogist, 10, 25-34   [view file]

Hogarth D D, Brown F F, Pritchard (1970) Biabsorption, Mössbauer spectra, and chemical investigation of five phlogopite samples from Quebec, The Canadian Mineralogist, 10, 710-722   [view file]

Joswig W (1972) Neutronenbeugungsmessungen an einem 1M-Phlogopit, Neues Jahrbuch für Mineralogie, Monatshefte, 1972, 1-11

Hazen R M, Burnham C W (1973) The crystal structures of one-layer phlogopite and annite, American Mineralogist, 58, 889-900   [view file]

Krausz K (1974) Potassium-barium exchange in phlogopite, The Canadian Mineralogist, 12, 394-398   [view file]

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International Mineralogical Association (1980) International Mineralogical Association: Commission on new minerals and mineral names, Mineralogical Magazine, 43, 1053-1055   [view file]

Kwak T A P (1981) Sector–zoned annite85phlogopite15 micas from the Mt. Lindsay Sn—W—F(—Be) deposit, Tasmania, Australia, The Canadian Mineralogist, 19, 643-650   [view file]

Miyano T, Miyano S (1982) Ferri-annite from the Dales Gorge Member iron-formations, Wittenoom area, Western Australia, American Mineralogist, 67, 1179-1194   [view file]

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Knurr R A, Bailey S W (1986) Refinement of Mn-substituted muscovite and phlogopite, Clays and Clay Minerals, 34, 7-16

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Brigatti M F, Poppi L (1993) Crystal chemistry of Ba-rich trioctahedral micas-1M, European Journal of Mineralogy, 5, 857-871

Shaw C S J, Penczak R S (1996) Barium- and titanium-rich biotite and phlogopite from the Western and Eastern Gabbro, Coldwell alkaline complex, northeastern Ontario, The Canadian Mineralogist, 34, 967-975   [view file]

Alietti E, Brigatti M F, Poppi L (1997) Clintonite-1M: Crystal chemistry and its relationships to closely associated Al-rich phlogopite, American Mineralogist, 82, 936-945   [view file]

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McKeown D A, Bell M I, Etz E S (1999) Raman spectra and vibrational analysis of the trioctahedral mica phlogopite, American Mineralogist, 84, 970-976   [view file]

Brigatti M F, Medici L, Poppi L, Vaccaro C (2001) Crystal chemistry of trioctahedral micas-1M from the Alto Paranaíba Igneous Province, southeastern Brazil, The Canadian Mineralogist, 39, 1333-1345   [view file]

Ferraris G, Gula A, Ivaldi G, Nespolo M, Sokolova E, Uvarova Y, Khomyakov A P (2001) First structure determination of an MDO-2O mica polytype associated with a 1M polytype, European Journal of Mineralogy, 13, 1013-1023

Schingaro E, Scordari F, Ventruti G (2001) Trioctahedral micas-1M from Mt. Vulture (Italy): Structural disorder and crystal chemistry, European Journal of Mineralogy, 13, 1057-1069

Kogure T, Banno Y, Miyawaki R (2004) Interlayer structure in aspidolite, the Na analogue of phlogopite, European Journal of Mineralogy, 16, 891-897

Brigatti M F, Caprilli E, Funiciello R, Giordano G, Mottana A, Poppi L (2005) Crystal chemistry of ferroan phlogopites from the Albano maar lake (Colli Albani volcano, central Italy), European Journal of Mineralogy, 17, 611-621

Chon C M, Lee C K, Song Y, Kim S A (2006) Structural changes and oxidation of ferroan phlogopite with increasing temperature: in situ neutron powder diffraction and Fourier transform infrared spectroscopy, Physics and Chemistry of Minerals, 33, 289-299

Mesto E, Schingaro E, Scordari F, Ottolini L (2006) An electron microprobe analysis, secondary ion mass spectrometry and single crystal X-ray diffraction study of phlogopites from Mt. Vulture, Potenza, Italy: Consideration of cation partitioning, American Mineralogist, 91, 182-190   [view file]

Scordari F, Ventruti G, Sabato A, Bellatreccia F, Della Ventura G, Pedrazzi G (2006) Ti-rich phlogopite from Mt. Vulture (Potenza, Italy) investigated by a multianalytical approach: substitutional mechanisms and orientation of the OH dipoles, European Journal of Mineralogy, 18, 379-391

Armbruster T, Richards R P, Gnos E, Pettke T, Herwegh M (2007) Unusual fibrous sodian tainiolite epitactic on phlogopite from marble xenoliths of Mont Saint-Hilaire, Quebec, Canada, The Canadian Mineralogist, 45, 541-549   [view file]

Laurora A, Brigatti M F, Mottana A, Malferrari D, Caprilli E (2007) Crystal chemistry of trioctahedral micas in alkaline and subalkaline volcanic rocks: A case study from Mt. Sassetto (Tolfa district, Latium, central Italy), American Mineralogist, 92, 468-480   [view file]

Matarrese S, Schingaro E, Scordari F, Stoppa F, Rosatelli G, Pedrazzi G, Ottolini L (2008) Crystal chemistry of phlogopite from Vulture-S. Michele Subsynthem volcanic rocks (Mt. Vulture, Italy) and volcanological implications, American Mineralogist, 93, 426-437   [view file]

Nazzareni S, Comodi P, Bindi L, Safonov O G, Litvin Y A, Perchuk L L (2008) Synthetic hypersilicic Cl-bearing mica in the phlogopite-celadonite join: a mulitmethodical characterization of the missing link between di- and tri-octahedral micas at high pressures, American Mineralogist, 93, 1429-1436   [view file]

Ventruti G, Zema M, Scordari F, Pedrazzi G (2008) Thermal behavior of a Ti-rich phlogopite from Mt. Vulture (Potenza, Italy): An in situ X-ray single-crystal diffraction study, American Mineralogist, 93, 632-643   [view file]

Zema M, Ventruti G, Lacalamita M, Scordari F (2010) Kinetics of Fe-oxidation/deprotonation process in Fe-rich phlogopite under isothermal conditions, American Mineralogist, 95, 1458-1466   [view file]

Scordari F, Schingaro E, Lacalamita, Mesto E (2012) Crystal chemistry of trioctahedral micas-2M1 from Bunyaruguru kamafugite (southwest Uganda), American Mineralogist, 97, 430-439   [view file]

Scordari F, Schingaro E, Mesto E, Lacalamita M (2012) 2M1-phlogopite from Black Hills (South Australia): The first case of configurational polytype in micas, American Mineralogist, 97, 2016-2023   [view file]

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Schingaro E, Lacalamita M, Scordari F, Mesto E (2013) 3T-phlogopite from Kasenyi kamafugite (SW Uganda): EPMA, XPS, FTIR, and SCXRD study, American Mineralogist, 98, 709-717

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Zhang M, Tarantino S C, Su W, Lou X, Ren X, Salje E K, Carpenter M A, Redfern S A (2016) Optical phonons, OH vibrations, and structural modifications of phlogopite at high temperatures: An in-situ infrared spectroscopic study, American Mineralogist, 101, 1873-1883

Breiter K, Vaňková M, Galiová M V, Korbelová Z, Kanický V (2017) Lithium and trace-element concentrations in trioctahedral micas from granites of different geochemical types measured via laser ablation ICP-MS, Mineralogical Magazine, 81, 15-33

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Pascal M L, Fonteilles M, Tournis V, Baptiste B, Robert J L, Boulliard J C (2018) Ba-, Si- and vacancy-rich phlogopites from the talc-bearing sulfide ore deposit of La Creuse, Beaujolais, France, Mineralogical Magazine, 82, 1187-1210

Lacalamita M, Schingaro E, Mesto E, Zaccarini F, Biagioni C (2020) Crystal‐chemistry of micas belonging to the yangzhumingite‐fluorophlogopite and phlogopite‐fluorophlogopite series from the Apuan Alps (northern Tuscany, Italy), Physics and Chemistry of Minerals, 47, 54   [view file]

Sun J, Yang Y, Ingrin J, Wang Z, Xia Q (2022) Impact of fluorine on the thermal stability of phlogopite, American Mineralogist, 107, 815-825