Phosgenite R050640



Name: Phosgenite
RRUFF ID: R050640
Ideal Chemistry: Pb2(CO3)Cl2
Locality: Monte Poni, Sardinia, Italy
Source: University of Arizona Mineral Museum 2007 [view label]
Owner: RRUFF
Description: Gray rectangular prismatic crystal
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
CHEMISTRY 
RRUFF ID: R050640.2
Sample Description: Microprobe Fragment
Measured Chemistry: Pb2.00(CO3)Cl2.03 ; C estimated by difference
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050640
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050640.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050640.1
Sample Description: Powder
Cell Refinement Output: a: 8.1599(1)Å    b: 8.1599(1)Å    c: 8.8757(4)Å
alpha: 90.°    beta: 90.°    gamma: 90.°   Volume: 590.99(3)Å3    Crystal System: tetragonal
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Phosgenite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Karsten D L G (1800) Tabellarische uebersicht der mineralogisch - einfachen fossilien [as hornblei], in Mineralogische Tabellen Heinrich August Rottmann Berlin 50-50   [view file]

Breithaupt J F A (1841) Phosgenites plumbosus kürzer phosgenit, in Vollständige Charakteristik des Mineral-Systems 2nd Edition Arnoldische Buchhandlung Dresden and Leipzig 183-184   [view file]

Köchlin R (1887) Ueber phosgenit und ein muthmasslich neues mineral vom Laurion, Annalen des K.K. Naturhistorischen Hofmuseums, 2, 185-190   [view file]

Giuseppetti G, Tadini C (1974) Reexamination of the crystal structure of phosgenite, Pb2Cl2(CO3), Tschermaks Mineralogische und Petrographische Mitteilungen, 21, 101-109

Frost R L, Williams P A, Martens W (2003) Raman spectroscopy of the minerals boléite, cumengéite, diaboléite and phosgenite - implications for the analysis of cosmetics of antiquity, Mineralogical Magazine, 67, 103-111   [view file]

Frost R L, Williams P A (2004) Raman spectroscopy of some basic chloride containing minerals of lead and copper, Spectrochimica Acta Part A, 60, 2071-2077

Frost R L, Dickfos M J (2007) Raman spectroscopy of halogen-containing carbonates, Journal of Raman Spectroscopy, 38, 1516-1522