Aravaipaite Diffraction data computed using the structure from the paper listed below, along with the cell parameters refined from single crystal data of R100032 Kampf A R, Yang H, Downs R T, Pinch W W American Mineralogist 96 (2011) 402-407 The crystal structures and Raman spectra of aravaipaite and calcioaravaipaite Locality: Grand Reef mine, Aravaipa mining district, Arizona, USA CELL PARAMETERS: 5.6560 5.8580 12.6920 98.750 94.000 90.710 SPACE GROUP: P-1 ATOM X Y Z OCCUPANCY ISO(B) Pb 0.30470 0.11693 0.36471 1.000 1.194 Pb 0.76753 0.04754 0.11751 1.000 1.895 Pb 0.27468 0.51132 0.11789 1.000 1.386 Al 0.79400 0.61810 0.30820 1.000 0.979 F 0.04860 0.77450 0.27400 1.000 2.092 F 0.73690 0.50940 0.16610 1.000 1.966 F 0.84880 0.71990 0.44550 1.000 2.290 F 0.51920 0.47520 0.33060 1.000 2.029 F 0.61580 0.86760 0.28630 1.000 2.092 F 0.95870 0.36350 0.31700 1.000 3.111 F 0.49960 0.24300 0.99240 1.000 1.484 F 0.00070 0.24750 0.99530 1.000 1.390 F 0.29420 0.12830 0.17100 1.000 3.214 O 0.66210 0.22570 0.51280 1.000 1.579 H 0.59700 0.33800 0.55500 1.000 3.948 H 0.81400 0.25300 0.50900 1.000 3.948 X-RAY WAVELENGTH: 1.541838 BOUNDS ON TWO THETA: 5.0 90.0 LIMITS IMPOSED ON THE INDICES ARE: +/- 5 +/- 5 +/- 11 MAX. ABS. INTENSITY / VOLUME**2: 84.22104232 The INTENSITY cut off value is 1.00 2-THETA INTENSITY D-SPACING H K L 7.07 100.00 12.5113 0 0 1 15.31 7.89 5.7882 0 1 0 15.71 4.33 5.6407 1 0 0 16.77 12.51 5.2879 -1 0 1 17.71 2.69 5.0080 1 0 1 17.84 21.21 4.9708 0 1 1 19.23 1.29 4.6161 0 -1 2 20.42 11.25 4.3489 -1 0 2 21.74 2.42 4.0877 -1 1 0 21.97 9.09 4.0458 1 0 2 22.26 3.59 3.9934 1 1 0 22.28 1.43 3.9903 -1 -1 1 22.47 1.19 3.9568 0 1 2 23.27 6.13 3.8231 -1 1 1 24.32 14.02 3.6604 0 -1 3 24.44 37.41 3.6422 1 1 1 24.49 46.39 3.6351 -1 -1 2 25.35 78.38 3.5128 1 -1 2 25.63 1.58 3.4760 -1 0 3 26.71 85.96 3.3377 -1 1 2 27.50 5.08 3.2429 1 0 3 28.34 57.32 3.1491 1 1 2 28.41 47.14 3.1414 -1 -1 3 28.54 55.61 3.1278 0 0 4 29.74 16.43 3.0042 1 -1 3 30.33 1.12 2.9473 0 -1 4 30.62 41.79 2.9197 0 -2 1 30.90 17.19 2.8941 0 2 0 31.49 2.54 2.8411 -1 1 3 31.69 1.65 2.8236 -1 0 4 31.73 41.40 2.8203 2 0 0 32.02 15.62 2.7951 -2 0 1 34.50 5.84 2.6000 1 -2 1 34.63 2.19 2.5906 0 1 4 34.69 2.53 2.5860 -1 -2 1 35.07 4.57 2.5590 -2 1 0 35.18 3.06 2.5509 1 2 0 35.71 1.91 2.5143 -1 -2 2 35.83 3.47 2.5061 -2 1 1 35.89 8.83 2.5023 0 0 5 36.88 1.23 2.4370 0 -1 5 37.13 3.93 2.4211 1 2 1 37.16 1.69 2.4198 -1 1 4 37.42 4.54 2.4032 2 1 1 38.02 1.65 2.3668 -2 1 2 38.14 3.41 2.3597 -1 -2 3 38.28 3.56 2.3514 -1 0 5 39.03 15.21 2.3081 0 -2 4 39.37 2.24 2.2888 -2 -1 3 39.37 1.05 2.2883 -1 -1 5 39.86 12.01 2.2614 2 0 3 40.40 2.19 2.2324 2 1 2 40.48 1.56 2.2282 1 0 5 40.58 16.15 2.2233 0 2 3 41.36 4.29 2.1831 2 -1 3 41.44 2.16 2.1792 -2 1 3 41.45 6.70 2.1784 0 1 5 41.53 21.27 2.1744 -2 0 4 41.76 1.21 2.1628 -1 -2 4 42.87 3.93 2.1096 -1 2 3 43.83 1.34 2.0654 0 -1 6 44.06 19.66 2.0552 0 -2 5 44.32 21.12 2.0438 -2 2 0 44.52 10.72 2.0352 2 -2 1 44.65 2.97 2.0296 1 2 3 44.80 19.80 2.0229 2 0 4 44.83 28.20 2.0218 -2 -2 1 45.26 1.45 2.0037 -1 0 6 45.42 2.25 1.9967 2 2 0 45.71 3.17 1.9847 1 1 5 45.77 1.69 1.9826 2 -1 4 45.82 6.14 1.9805 -1 -1 6 45.86 2.79 1.9786 -2 1 4 45.87 12.99 1.9784 0 2 4 46.51 2.29 1.9525 0 -3 1 46.75 9.40 1.9430 -2 0 5 47.10 2.53 1.9294 0 3 0 47.58 3.04 1.9113 1 0 6 47.75 3.61 1.9049 1 -2 5 47.82 1.22 1.9020 -2 -1 5 47.85 10.91 1.9009 1 -1 6 48.41 1.94 1.8802 3 0 0 48.85 1.77 1.8643 0 3 1 48.88 1.23 1.8634 0 -3 3 49.95 1.11 1.8257 1 -3 2 50.21 12.72 1.8169 -1 1 6 50.84 1.36 1.7961 -2 2 3 51.08 11.29 1.7880 -1 3 1 51.12 2.29 1.7868 0 -1 7 51.43 1.20 1.7768 3 -1 1 51.50 11.07 1.7746 -1 -3 3 51.71 1.84 1.7677 0 -3 4 51.75 1.31 1.7664 -1 -2 6 51.82 11.38 1.7642 1 -3 3 51.86 1.05 1.7629 -3 -1 2 52.07 5.98 1.7564 2 -2 4 52.19 10.32 1.7528 1 3 1 52.58 10.09 1.7405 -3 1 2 52.61 9.87 1.7396 1 1 6 52.72 9.14 1.7363 -1 -1 7 52.90 9.67 1.7309 3 1 1 53.24 10.40 1.7205 3 -1 2 53.28 1.88 1.7192 -2 -1 6 53.65 3.42 1.7084 -1 3 2 53.70 12.49 1.7067 -3 -1 3 53.94 7.88 1.6999 2 2 3 54.06 1.70 1.6963 -1 -3 4 54.07 9.48 1.6961 -2 -2 5 54.91 4.27 1.6722 1 -1 7 55.03 7.70 1.6689 -2 2 4 55.09 1.35 1.6670 2 1 5 55.12 2.46 1.6663 -3 1 3 55.14 1.18 1.6657 -3 0 4 55.38 3.48 1.6590 3 1 2 55.46 1.41 1.6569 0 3 3 55.60 1.15 1.6529 1 2 5 56.53 4.06 1.6280 2 -2 5 57.41 1.61 1.6051 -1 1 7 58.18 1.49 1.5856 3 -2 1 58.42 1.58 1.5796 -2 3 1 58.60 2.13 1.5754 2 3 0 58.63 2.17 1.5745 2 2 4 59.07 5.79 1.5639 0 0 8 59.75 2.18 1.5477 2 -3 3 61.35 1.65 1.5112 -2 -3 4 63.42 1.41 1.4667 2 -1 7 63.58 5.18 1.4633 0 -4 1 63.75 1.71 1.4599 0 -4 2 64.01 1.13 1.4546 0 1 8 65.45 1.12 1.4261 0 2 7 66.00 1.08 1.4156 1 -4 2 66.14 5.33 1.4127 -4 0 1 66.19 1.49 1.4118 -2 0 8 66.23 1.13 1.4110 -1 -4 2 66.28 2.72 1.4102 4 0 0 66.51 1.38 1.4059 -1 2 7 66.72 1.95 1.4020 -1 3 5 67.11 3.51 1.3948 -1 -3 7 67.36 1.52 1.3901 0 0 9 68.05 3.14 1.3777 -3 1 6 68.19 2.63 1.3753 3 1 5 68.59 4.02 1.3682 1 -3 7 68.86 4.09 1.3635 1 3 5 69.15 1.30 1.3585 3 -2 5 69.74 4.08 1.3484 3 -1 6 69.82 1.84 1.3471 3 -3 2 69.86 1.42 1.3465 -3 3 1 69.93 2.15 1.3453 0 -4 5 70.27 3.89 1.3396 -3 -1 7 70.51 3.52 1.3356 0 -2 9 70.78 1.30 1.3311 3 3 0 70.84 2.44 1.3301 -3 -3 3 71.00 3.78 1.3275 2 0 8 71.61 1.23 1.3178 0 -3 8 71.65 2.00 1.3171 3 -3 3 71.71 2.34 1.3162 -3 3 2 71.78 1.02 1.3150 1 4 2 72.26 1.60 1.3074 4 0 3 72.29 3.12 1.3070 2 -4 1 72.33 3.12 1.3065 0 4 3 72.59 3.11 1.3023 3 3 1 72.60 2.38 1.3023 -1 3 6 72.70 1.88 1.3007 -3 -3 4 72.98 1.03 1.2963 -1 -3 8 73.05 2.18 1.2953 0 2 8 73.20 1.94 1.2930 -2 -4 2 73.34 1.33 1.2909 -2 -4 1 73.75 1.07 1.2847 0 -4 6 73.77 1.85 1.2844 -2 0 9 73.90 1.71 1.2825 -3 1 7 74.00 1.94 1.2810 3 1 6 74.10 3.79 1.2795 -4 2 0 74.28 1.54 1.2769 2 -2 8 74.85 2.60 1.2685 -4 0 5 74.99 2.73 1.2665 -4 -2 1 75.50 1.50 1.2592 -1 -4 6 76.01 2.01 1.2520 4 0 4 76.43 1.08 1.2462 1 -4 6 76.99 2.27 1.2385 2 2 7 77.21 2.47 1.2355 -2 -2 9 78.73 1.57 1.2155 1 -1 10 79.17 2.66 1.2099 -2 2 8 79.46 2.80 1.2061 2 -4 5 79.49 2.43 1.2057 -2 4 3 81.02 2.19 1.1868 -4 -2 5 81.16 2.76 1.1851 4 -2 4 81.30 2.56 1.1834 -4 2 4 81.54 1.36 1.1805 2 -2 9 81.60 2.18 1.1798 -2 -4 6 81.74 2.44 1.1781 -1 1 10 82.77 1.97 1.1661 2 4 3 83.17 2.72 1.1615 4 2 3 83.45 1.03 1.1583 -3 -3 7 84.70 1.04 1.1444 -4 -2 6 84.71 1.04 1.1443 0 -5 4 84.76 1.99 1.1437 1 1 10 84.90 2.06 1.1422 -1 -1 11 85.18 1.12 1.1392 1 -5 3 86.15 1.51 1.1288 1 5 0 86.78 1.79 1.1222 -1 -5 4 86.91 1.12 1.1209 -1 5 1 87.59 1.37 1.1140 3 -3 7 87.72 1.60 1.1126 -3 3 6 87.79 1.27 1.1119 1 -1 11 88.44 1.84 1.1054 3 3 5 88.70 1.39 1.1028 -3 -3 8 89.69 1.78 1.0932 -5 -1 3 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.