Hedenbergite R050030

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Record 59 of 79  


Name: Hedenbergite
RRUFF ID: R050030
Ideal Chemistry: CaFe2+Si2O6
Locality: Heroult, Ontario, Canada
Source: University of Arizona Mineral Museum 4120 [view label]
Owner: RRUFF
Description: Green fragments
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ pyroxene (79) ]
Quick search: [ All Hedenbergite samples (4) ]
CHEMISTRY 
RRUFF ID: R050030.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Ca.993Na.007)(Fe.860Mn.111Mg.029)(Si.993Al.007)2O6
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Sample is oriented, mounted onto a pin and polished
Pin ID: M00111
Orientation: Laser parallel to  a*  (1 0 0).     Fiducial mark perpendicular to laser is parallel to  b   [0 1 0].
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Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050030
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050030.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050030.1
Sample Description: Powder
Cell Refinement Output: a: 9.8416(8)Å    b: 9.0253(5)Å    c: 5.2520(3)Å
alpha: 90.°    beta: 104.86(1)°    gamma: 90.°   Volume: 450.89(5)Å3    Crystal System: monoclinic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Hedenbergite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Berzelius J J (1819) Hedenbergite, in Nouveau Système de Minéralogie Méquignon-Marvis Paris 269-270   [view file]

Dana E S (1904) Monoclinic Section. Pyroxene, in The System of Mineralogy of James Dwight Data 1837-1868, Sixth Edition John Wiley & Sons New York 352-371   [view file]

Kuno H, Hess H H (1953) Unit cell dimensions of clinoenstatite and pigeonite in relation to other common clinopyroxenes, American Journal of Science, 251, 741-752

Nolan J (1969) Physical properties of synthetic and natural pyroxenes in the system diopside-hedenbergite-acmite, Mineralogical Magazine, 37, 216-229   [view file]

Rutstein M S, Yund R A (1969) Unit-cell parameters of synthetic diopside-hedenbergite solid solutions, American Mineralogist, 54, 238-245   [view file]

Cameron M, Sueno S, Prewitt C T, Papike J J (1973) High-temperature crystal chemistry of acmite, diopside, hedenbergite, jadeite, spodumene, and ureyite, American Mineralogist, 58, 594-618   [view file]

Turnock A C, Lindsley D H, Grover J E (1973) Synthesis and unit cell parameters of Ca-Mg-Fe pyroxenes, American Mineralogist, 58, 50-59   [view file]

Ohashi Y, Burnham C W, Finger L W (1975) The effect of Ca-Fe on the clinopyroxene crystal structure, American Mineralogist, 60, 423-434   [view file]

Cameron M, Papike J J (1981) Structural and chemical variations in pyroxenes, American Mineralogist, 66, 1-50   [view file]

Morimoto N (1988) Nomenclature of pyroxenes, Mineralogical Magazine, 52, 535-550   [view file]

Raudsepp M, Hawthorne F C, Turnock A C (1990) Evaluation of the Rietveld method for the characterization of fine-grained products of mineral synthesis: the diopside-hedenbergite join, The Canadian Mineralogist, 28, 93-109   [view file]

Inoue A, Utada M (1991) Pumpellyite and related minerals from hydrothermally altered rocks at the Kamikita area, northern Honshu Japan, The Canadian Mineralogist, 29, 255-270   [view file]

Nakano T (1991) An antipathetic relation between the hedenbergite and johannsenite components in skarn clinopyroxene from the Kagata tungsten deposit, central Japan, The Canadian Mineralogist, 29, 427-434   [view file]

Huang E, Chen C H, Huang T, Lin E H, Xu J (2000) Raman spectroscopic characteristics of Mg-Fe-Ca pyroxenes, American Mineralogist, 85, 473-479   [view file]

Redhammer G J, Amthauer G, Lottermoser W, Treutmann W (2000) Synthesis and structural properties of clinopyroxenes of the hedenbergite CaFeSi2O6 - aegirine NaFeSi2O6 solid-solution series, European Journal of Mineralogy, 12, 105-120

Wang A, Jolliff B L, Haskin L A, Kuebler K E, Viskupic K M (2001) Characterization and comparison of structural and compositional features of planetary quadrilateral pyroxenes by Raman spectroscopy, American Mineralogist, 86, 790-806   [view file]

Heuer M, Huber A L, Bromiley G D, Fehr K T, Bente K (2002) Characterization of synthetic hedenbergite (CaFeSi2O6)–petedunnite (CaZnSi2O6) solid solution series by X-ray single crystal diffraction, Physics and Chemistry of Minerals, 32, 552-563

Redhammer G J, Amthauer G, Roth G, Tippelt G, Lottermoser W (2006) Single crystal X-ray diffraction and temperature dependent 57Fe Mössbauer spectroscopy on the hedenbergite - aegirine (Ca,Na)(Fe2+,Fe3+)Si2O6 solid solution, American Mineralogist, 91, 1271-1292   [view file]

Nestola F, Tribaudino M, Boffa Ballaran T, Liebske C, Bruno M (2007) The crystal structure of pyroxenes along the jadeite-hedenbergite and jadeite-aegirine joins, American Mineralogist, 92, 1492-1501   [view file]

Buzatu A, Buzgar N (2010) The Raman study of single-chain silicates, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 56, 107-125   [view file]

Abdu Y A, Hawthorne F C (2013) Local structure in C2/c clinopyroxenes on the hedenbergite (CaFeSi2O6)-ferrosilite (Fe2Si2O6) join: A new interpretation for the Mössbauer spectra of Ca-rich C2/c clinopyroxenes and implications for pyroxene exsolution, American Mineralogist, 98, 1227-1234

Mantovani L, Tribaudino M, Mezzadri F, Calestani G, Bromiley G (2013) The structure of (Ca,Co)CoSi2O6 pyroxenes and the Ca-M2+ substitution in (Ca,M2+)M2+Si2O6 pyroxenes (M2+ = Co, Fe, Mg), American Mineralogist, 98, 1241-1252

Kolitsch U, Rieck B, Brandstätter F, Schreiber F, Fabritz K H, Blaß G, Gröbner J (2014) Neufunde aus dem altem Bergbau und den Schlacken von Lavrion (II), Mineralien Welt, 25, 82-95   [view file]

Mantovani L, Tribaudino M, Bertoni G, Salvianti G, Bromiley G (2014) Solid solutions and phase transitions in (Ca,M2+)M2+Si2O6 pyroxenes (M2+ = Co, Fe, Mg), American Mineralogist, 99, 704-711

Tribaudino M, Mantovani L (2014) Thermal expansion in C2/c pyroxenes: a review and new high-temperature structural data for a pyroxene of composition (Na0.53Ca0.47)(Al0.53Fe0.47)Si2O6 (Jd53Hd47), Mineralogical Magazine, 78, 311-324

Nespolo M, Aroyo M I (2016) The modular structure of pyroxenes, European Journal of Mineralogy, 28, 189-203

Nagashima M, Nishio-Hamane D (2018) Transmission electron microscopy study of the epitaxial association of hedenbergite whiskers with babingtonite, Mineralogical Magazine, 82, 23-33