Wardite R050643



Name: Wardite
RRUFF ID: R050643
Ideal Chemistry: NaAl3(PO4)2(OH)4·2H2O
Locality: Big Fish River, Yukon Territory, Canada
Source: Rock Currier
Owner: RRUFF
Description: Tan bipyramidal pseudo-octahedral crystals
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Wardite (2) ]
CHEMISTRY 
RRUFF ID: R050643.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Na0.93   0.05Ca0.02)Σ=1(Al2.97Fe3+0.03)Σ=3(P1.00O4)2((OH)3.88F0.12)Σ=4·2H2O
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050643
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050643.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050643.1
Sample Description: Powder
Cell Refinement Output: a: 7.0582(2)Å    b: 7.0582(2)Å    c: 19.0678(6)Å
alpha: 90.°    beta: 90.°    gamma: 90.°   Volume: 949.94(6)Å3    Crystal System: tetragonal
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Wardite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Davison J M (1896) Wardite: a new hydrous basic phosphate of alumina, American Journal of Science, 152, 154-155   [view file]

Larsen E S, Shannon E V (1930) The minerals of the phosphate nodules from near Fairfield, Utah, American Mineralogist, 15, 307-337   [view file]

Lindberg M L (1957) Relationship of the minerals avelinoite, cyrilovite, and wardite, American Mineralogist, 42, 204-213   [view file]

Fanfani L, Nunzi A, Zanazzi P F (1970) The crystal structure of wardite, Mineralogical Magazine, 37, 598-605   [view file]

Frost R L, Erickson K L (2005) Near-infrared spectroscopic study of selected hydrated hydroxylated phosphates, Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, 61, 45-50   [link]