Valentinite R050389

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Record 3928 of 4216  

Name: Valentinite
RRUFF ID: R050389
Ideal Chemistry: Sb2O3
Locality: Bohemia Region, Pribram, Czech Republic
Source: University of Arizona Mineral Museum 2886 [view label]
Owner: RRUFF
Description: Colorless prismatic parallel crystals
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Quick search: [ All Valentinite samples (3) ]
CHEMISTRY 
RRUFF ID: R050389.2
Sample Description: Microprobe Fragment
Measured Chemistry: Sb2.00O3
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050389
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050389.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050389.1
Sample Description: Powder
Cell Refinement Output: a: 4.9122(5)Å    b: 12.482(1)Å    c: 5.4154(9)Å
alpha: 90.°    beta: 90.°    gamma: 90.°   Volume: 332.06(6)Å3    Crystal System: orthorhombic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Valentinite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Haidinger W (1845) Zweite Klasse: Geogenide. II. Ordnung. Baryte VIII. Antimonbaryt. Valentinit., in Handbuch der Bestimmenden Mineralogie Bei Braumüller and Seidel Wien 499-506   [view file]

Buerger M J, Hendricks S B (1938) The crystal structure of valentinite (orthorhombic Sb2O3), Zeitschrift für Kristallographie, 98, 1-30   [view file]

Mason B, Vitaliano C J (1952) The mineralogy of the antimony oxides and antimonates, Mineralogical Magazine, 30, 100-112   [view file]

Svensson C (1974) The crystal structure of orthorhombic antimony trioxide, Sb2O3, Acta Crystallographica, B30, 458-461

International Mineralogical Association (1980) International Mineralogical Association: Commission on new minerals and mineral names, Mineralogical Magazine, 43, 1053-1055   [view file]

Whitten AE, Dittrich B, Spackman MA, Turner P, Brown TC (2004) Charge density analysis of two polymorphs of antimony(III) oxide, Dalton Transactions, 2004, 23-29

Kolitsch U, Rieck B, Brandstätter F, Schreiber F, Fabritz K H, Blaß G, Gröbner J (2014) Neufunde aus dem altem Bergbau und den Schlacken von Lavrion (II), Mineralien Welt, 25, 82-95

Moseley D H, Bridges C A, Daemen L L, Zhang Q, McGuire M A, Cakmak E, Hermann R P (2023) Structure and anharmonicity of α- and β-Sb2O3 at low temperature, Crystals, 13, 752   [link]   [view file]