R130048 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Piypite R130048

Name: Piypite
RRUFF ID: R130048
Ideal Chemistry: K₄Cu₄O₂(SO₄)₄·(Na,Cu)Cl
Locality: Second scoria cone, Northern Breakthrough (North Breach), Great Fissure (Main Fracture) eruption, Tolbachik volcano, Kamchatka Oblast', Far-Eastern Region, Russia
Source: Don Doell [view label]
Owner: RRUFF
Description: Sprays of bright green acicular crystals
Status: The identification of this mineral has been confirmed by single-crystal X-ray diffraction.

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample; sample burns when above 30% power on 780 laser

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R130048

Wavelength:

Sample Description:

Unoriented sample; sample burns when above 30% power on 780 laser

Instrument settings:

Almega 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R130048.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 13.599(6)Å b: 13.599(6)Å c: 4.995(2)Å
alpha: 90° beta: 90° gamma: 90° Volume: 923.8(4)Å³ Crystal System: tetragonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Piypite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Effenberger H, Zemann J (1984) The crystal structure of caratiite, Mineralogical Magazine, 48, 541-546 [view file]
Vergasova L P, Filatov S K, Serafimova E K, Starova G L (1984) Piypite K₂Cu₂O(SO₄)₂ - a new mineral of volcanic sublimates, Doklady Akademii Nauk SSSR, 275, 714-717 [view file]
Dunn P J, Gobel V, Grice J D, Puziewicz J, Shigley J E, Vanko D A, Zilczer J (1985) New mineral names, American Mineralogist, 70, 436-441 [view file]
Filatov S K, Vergasova L P (1989) Discrediting of caratiite and priority for piypite, Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva, 118, issue 3 88-90 [view file]
Kahlenberg V, Piotrowski A, Giester G (2000) Crystal structure of Na₄[Cu₄O₂(SO4)4]·MeCl (Me: Na, Cu, ◻) – the synthetic Na-analogue of piypite (caratiite), Mineralogical Magazine, 64, 1099-1108 [view file]
Shablinskii A P, Filatov S K, Biryukov Y P, Yuriev A A, Vergasova L P (2023) Thermal expansion of fedotovite K₂Cu₃O(SO₄)₃ and piypite K₄Cu₄O(SO₄)₄·(Na,Cu)Cl, Glass Physics and Chemistry, 49, 386-393

REFERENCES for Piypite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Effenberger H, Zemann J (1984) The crystal structure of caratiite, Mineralogical Magazine, 48, 541-546 [view file]

Vergasova L P, Filatov S K, Serafimova E K, Starova G L (1984) Piypite K₂Cu₂O(SO₄)₂ - a new mineral of volcanic sublimates, Doklady Akademii Nauk SSSR, 275, 714-717 [view file]

Dunn P J, Gobel V, Grice J D, Puziewicz J, Shigley J E, Vanko D A, Zilczer J (1985) New mineral names, American Mineralogist, 70, 436-441 [view file]

Filatov S K, Vergasova L P (1989) Discrediting of caratiite and priority for piypite, Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva, 118, issue 3 88-90 [view file]

Kahlenberg V, Piotrowski A, Giester G (2000) Crystal structure of Na₄[Cu₄O₂(SO4)4]·MeCl (Me: Na, Cu, ◻) – the synthetic Na-analogue of piypite (caratiite), Mineralogical Magazine, 64, 1099-1108 [view file]

Shablinskii A P, Filatov S K, Biryukov Y P, Yuriev A A, Vergasova L P (2023) Thermal expansion of fedotovite K₂Cu₃O(SO₄)₃ and piypite K₄Cu₄O(SO₄)₄·(Na,Cu)Cl, Glass Physics and Chemistry, 49, 386-393