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Name: Magnetite RRUFF ID: R060656 Ideal Chemistry: Fe2+Fe3+2O4 Locality: Jacupiranga Pegmatite, Sao Paulo State, Brazil Source: Michael Scott S101168 [view label] Owner: RRUFF Description: Black rounded octahedra associated with phlogopite and diopside Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis |
Mineral Group: [ Spinel (66) ] | ||
Quick search: [ All Magnetite samples (6) ] |
CHEMISTRY | ||||||||
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RAMAN SPECTRUM | ||||||||||||||||||||
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BROAD SCAN WITH SPECTRAL ARTIFACTS | ||||||||||||
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POWDER DIFFRACTION | ||||||||
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RRUFF ID: | R060656.1 | |||||||
Sample Description: | Powder | |||||||
Cell Refinement Output: |
a: 8.4003(1)Å b: 8.4003(1)Å c: 8.4003(1)Å alpha: 90.° beta: 90.° gamma: 90.° Volume: 592.78(3)Å3 Crystal System: cubic |
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REFERENCES for Magnetite | |
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American Mineralogist Crystal Structure Database Record: [view record] |
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Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file] |
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Hoffmann C A S (1789) Mineralsystem des Herrn Inspektor Werners mit dessen Erlaubnis herausgegeben von C A S Hoffmann, Bergmannisches Journal, 1, 369-398 [view file] |
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Haidinger W (1845) Zweite Klasse: Geogenide. XI. Ordnung, Erze. X. Eisennerz. Magnetit., in Handbuch der Bestimmenden Mineralogie Bei Braumüller and Seidel Wien 546-555 [view file] |
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Hutton C O (1950) Studies of heavy detrital minerals, Bulletin of the Geological Society of America, 61, 635-710 [view file] |
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Bernal J D, Dasgupta D R, Mackay A L (1959) The oxides and hydroxides of iron and their structural inter-relationships, Clay Minerals Bulletin, 4, 15-30 |
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Feitknecht W, Brunner P, Oswalk HR (1962) Über den Einfluβ der Feuchtigkeit auf die Oxydation von Manganhydroxid durch molekularen Sauerstoff, Zeitschrift für Anorganische und Allgemeine Chemie, 316, 154-160 |
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Gorton A T, Bitsianes G, Joseph T L (1965) Thermal expansion coefficients for iron and its oxides from X-ray diffraction measurements at elevated temperatures, Transactions of the Metallurgical Society of AIME, 233, 1519-1525 |
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Pajari G E (1966) Abstract of paper presented at the eleventh meeting: The variation of magnetiteulvospinel and hematiteilmenite compositions in a differentiated alkaline intrusive, The Canadian Mineralogist, 8, 670-670 [view file] |
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Annersten H, Hafner S S (1973) Vacancy distribution in synthetic spinels of the series Fe304γFe2O3, Zeitschrift für Kristallographie, 137, 321-340 |
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Volenik K, Seberini M, Neid J (1975) A Mössbauer and X-ray diffraction study of nonstoichiometry in magnetite, Czechoslovak Journal of Physics, 25, 1063-1071 |
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Henriquez F, Martin R F (1978) Crystal-growth texture in magnetite flows and feeder dykes, El Laco, Chile, The Canadian Mineralogist, 16, 581-589 [view file] |
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Fleet M E, Bilcox G A, Barnett R L (1980) Oriented magnetite inclusions in pyroxenes from the Grenville province, The Canadian Mineralogist, 18, 89-99 [view file] |
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D’arco P, Maury R C (1981) Comparative geothermometry of some magnetite–ilmenite–orthopyroxene–clinopyroxene associations from volcanic rocks, The Canadian Mineralogist, 19, 461-467 [view file] |
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Fleet M E (1981) The structure of magnetite, Acta Crystallographica, B37, 917-920 |
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Spear F S (1982) Phase equilibria of amphibolites from the post pond volcanics, Mt. cube quadrangle, Vermont, Journal of Petrology, 23, 383-426 |
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Fleet M E (1984) The structure of magnetite: two annealed natural magnetites, Fe3.005O4 and Fe2.96Mg0.04O4, Acta Crystallographica, C40, 1491-1493 |
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Wechsler B A, Lindsley D H, Prewitt C T (1984) Crystal structure and cation distribution in titanomagnetites (Fe3-xTixO4), American Mineralogist, 69, 754-770 [view file] |
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Fleet M E (1986) The structure of magnetite: symmetry of cubic spinels, Journal of Solid State Chemistry, 62, 75-82 |
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Hill R L, Sack R O (1987) Thermodynamic properties of Fe-Mg titaniferous magnetite spinels, The Canadian Mineralogist, 25, 443-464 [view file] |
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Schwertmann U, Murad E (1990) The influence of aluminum on iron oxides: XIV. Al-substituted magnetite synthesized at ambient temperatures, Clays and Clay Minerals, 38, 196-202 [view file] |
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Banin A, Ben-Shlomo T, Margulies L, Blake D F, Mancinelli R L (1993) The nanophase iron mineral(s) in Mars soil, Journal of Geophysical Research, 98, 20831-20853 |
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O'Neill H S C, Dollase W A (1994) Crystal structures and cation distributions in simple spinels from Powder XRD structural refinements: MgCr2O4, ZnCr2O4, Fe3O4 and the temperature dependence of the cation distribution in ZnAl2O4, Physics and Chemistry of Minerals, 20, 541-555 [view file] |
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Maier W D, Barnes S J (1996) Unusually high concentrations of magnetite at Caraíba and other Cu-sulfide deposits in the Curaçá Valley, Bahia, Brazil, The Canadian Mineralogist, 34, 717-731 [view file] |
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de Faria D L A, Silva S V, de Oliveira M T (1997) Raman microspectroscopy of some iron oxides and oxyhydroxides, Journal of Raman Spectroscopy, 28, 873-878 [link] |
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Oh S J, Cook D C, Townsend H E (1998) Characterization of iron oxides commonly formed as corrosion products on steel, Hyperfine Interactions, 112, 59-65 [link] |
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Gasparov L V, Tanner D B, Romero D B, Berger H, Margaritondo G, Forro L (2000) Infrared and Raman studies of the Verwey transition in magnetite, Physical Review B, 62, 7939-7944 |
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Beard J S, Tracy R J (2002) Spinels and other oxides in Mn-rich rocks from the Hutter Mine, Pittsylvania County, Virginia, U.S.A.: implications for miscibility and solvus relations among jacobsite, galaxite, and magnetite, American Mineralogist, 87, 690-698 [view file] |
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Frankel R B, Bazylinski D A (2003) Biologically induced mineralization by bacteria, Reviews in Mineralogy and Geochemistry, 54, 95-114 |
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Kretz R (2003) Dendritic magnetite and ilmenite in 590 Ma Grenville dikes near Otter Lake, Quebec, Canada, The Canadian Mineralogist, 41, 1049-1059 [view file] |
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Ondru P, Veselovský F, Gabaová A, Hlouek J, rein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file] |
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Shebanova O N, Lazor P (2003) Raman study of magnetite (Fe3O4): laser-induced thermal effects and oxidation, Journal of Raman Spectroscopy, 34, 845-852 |
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Tracy R J, Beard J S (2003) Manganoan kinoshitalite in Mn-rich marble and skarn from Virginia, American Mineralogist, 88, 740-747 [view file] |
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Yang J B, Zhou X D, Yelon W B, James W J, Cai Q, Gopalakrishnan K V, Malik S K, Sun X C, Nikles D E (2004) Magnetic and structural studies of the Verwey transition in Fe3δO4 nanoparticles, Journal of Applied Physics, 95, 7540-7542 |
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Hamilton V E, McSween H Y, Hapke B (2005) Mineralogy of Martian atmospheric dust inferred from thermal infrared spectra of aerosols, Journal of Geophysical Research, 110, E12006 [link] |
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Cvejic Z, Rakic S, Kremenovic A, Antic B, Jovalekic C, Colomban P (2006) Nanosize ferrites obtained by ball milling: crystal structure, cation distribution, size-strain analysis and Raman investigations, Solid State Sciences, 8, 908-915 |
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Schmidbauer E, Keller M (2006) Magnetic hysteresis properties, Mossbauer spectra and structural data of spherical 250 nm particles of solid solutions Fe3O4-γ-Fe2O3, Journal of Magnetism and Magnetic Materials, 297, 107-117 |
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Gatta G D, Kantor I, Ballaran T B, Dubrovinsky L, McCammon C (2007) Effect of non-hydrostatic conditions on the elastic behaviour of magnetite: an in situ single-crystal X-ray diffraction study, Physics and Chemistry of Minerals, 34, 627-635 |
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Glass B P, Fries M (2008) Micro-Raman spectroscopic study of fine-grained, shock-metamorphosed rock fragments from the Australasian microtektite layer, Meteoritics and Planetary Science, 43, 1487-1496 [view file] |
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Bosi F, Hålenius U, Skogby H (2009) Crystal chemistry of the magnetite-ulvöspinel series, American Mineralogist, 94, 181-189 [view file] |
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Gotic M, Koscec G, Music S (2009) Study of the reduction and reoxidation of substoichiometric magnetite, Journal of Molecular Structure, 924-26, 347-354 |
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Gorski C A, Scherer M M (2010) Determination of nanoparticulate magnetite stoichiometry by Mössbauer spectroscopy, acidic dissolution, and powder X-ray diffraction: A critical review, American Mineralogist, 95, 1017-1026 |
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Crisan O, Crisan A D (2011) Phase transformation and exchange bias effects in mechanically alloyed Fe/magnetite powders, Journal of Alloys and Compounds, 509, 6522-6527 |
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Zinin P, Tatsumi-Petrochilos L, Bonal L, Acosta T, Hammer J, Gilder S, Fuller M (2011) Raman spectroscopy of titanomagnetites: Calibration of the intensity of Raman peaks as a sensitive indicator for their Ti content, American Mineralogist, 96, 1537-1546 [view file] |
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Glazyrin K, McCammon C, Dubrovinsky L, Merlini M, Schollenbruch K, Woodland A, Hanfland M (2012) Effect of high pressure on the crystal structure and electronic properties of magnetite below 25 GPa, American Mineralogist, 97, 128-133 [view file] |
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Woodland A B, Frost D J, Trots D M, Klimm K, Mezouar M (2012) In situ observation of the breakdown of magnetite (Fe3O4) to Fe4O5 and hematite at high pressures and temperatures, American Mineralogist, 97, 1808-1811 [view file] |
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Yamanaka T, Kyono A, Nakamoto Y, Meng Y, Kharlamova S, Struzhkin V V, Mao H (2013) High-pressure phase transitions of Fe3-xTixO4 solid solution up to 60 GPa correlated with electronic spin transition, American Mineralogist, 98, 736-744 |
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Guignard J, Crichton W A (2014) Synthesis and recovery of bulk Fe4O5 from magnetite, Fe3O4. A member of a self-similar series of structures for the lower mantle and transition zone, Mineralogical Magazine, 78, 361-371 |
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Koch-Müller M, Mugnaioli E, Rhede D, Speziale S, Kolb U, Wirth R (2014) Synthesis of a quenchable high-pressure form of magnetite (h-Fe3O4) with composition Fe1(Fe2+0.75Mg0.26)Fe2(Fe3+0.70Cr0.15Al0.11Si0.04)2O4, American Mineralogist, 99, 2405-2415 |
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Wang M, Chou I, Lu W, de Vivo B (2015) Effects of CH4 and CO2 on the sulfidization of goethite and magnetite: an in situ Raman spectroscopic study in high-pressure capillary optical cells at room temperature, European Journal of Mineralogy, 27, 193-201 |
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Anjuma S, Tufail R, Rashid K, Zia R, Riaz S (2017) Effect of cobalt doping on crystallinity, stability, magnetic and optical properties of magnetic iron oxide nano-particles, Journal of Magnetism and Magnetic Materials, 432, 198-207 |
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Giebel R J, Gauert C D K, Marks M A W, Costin G, Markl G (2017) Multi-stage formation of REE minerals in the Palabora Carbonatite Complex, South Africa, American Mineralogist, 102, 1218-1233 |
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Uenver-Thiele L, Woodland A B, Ballaran T B, Miyajima N, Frost D J (2017) Phase relations of Fe-Mg spinels including new high-pressure post-spinel phases and implications for natural samples, American Mineralogist, 102, 2054-2064 |
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Capitani G C, Ventruti G (2018) Ni-serpentine nanoflakes in the garnierite ore from Campello Monti (Strona Valley, Italy): Népouite with some pecoraite outlines and the processing of Ni-containing ore bodies, American Mineralogist, 103, 629-644 |
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Morrison S M, Downs R T, Blake D F, Prabhu A, Eleish A, Vaniman D T, Ming D W, Rampe E B, Hazen R M, Achilles C N, Treiman A H, Yen A S, Morris R V, Bristow T F, Chipera S J, Sarrazin P C, Fendrich K V, Morookian J M, Farmer J D, Des Marais D J, Craig P I (2018) Relationships between unit-cell parameters and composition for rock-forming minerals on Earth, Mars, and other extraterrestrial bodies, American Mineralogist, 103, 848-856 [view file] |
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Morrison S M, Downs R T, Blake D F, Vaniman D T, Ming D W, Hazen R M, Treiman A H, Achilles C N, Yen A S, Morris R V, Rampe E B, Bristow T F, Chipera S J, Sarrazin P C, Gellert R, Fendrich K V, Morookian J M, Farmer J D, Des Marais D J, Craig P I (2018) Crystal chemistry of martian minerals from Bradbury Landing through Naukluft Plateau, Gale crater, Mars, American Mineralogist, 103, 857-871 [view file] |
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Plotinskaya O Y, Abramova V D, Groznova E O, Tessalina S G, Seltmann R, Spratt J (2018) Trace-element geochemistry of molybdenite from porphyry Cu deposits of the Birgilda-Tomino ore cluster (South Urals, Russia), Mineralogical Magazine, 82, S281-S306 |
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Bosi F, Biagioni C, Pasero M (2019) Nomenclature and classification of the spinel supergroup, European Journal of Mineralogy, 31, 183-192 [view file] |
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Knafelc J, Filiberto J, Ferré E C, Conder J A, Costello L, Crandall J R, Dyar M D, Friedman S A, Hummer D R, Schwenzer S P (2019) The effect of oxidation on the mineralogy and magnetic properties of olivine, American Mineralogist, 104, 694-702 |
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Siersch N C, Criniti G, Kurnosov A, Glazyrin K, Antonangeli D (2023) Thermal equation of state of Fe3O4 magnetite up to 16 GPa and 1100 K, American Mineralogist, 108, 1322-1329 |
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