" X050153 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

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Spodumene X050153

Name: Spodumene
RRUFF ID: X050153
Ideal Chemistry: LiAlSi₂O₆
Locality: Pala, California, USA
Source: G.R. Rossman 1658
Owner: Caltech
Description:
Status: The identification of this mineral has been determined only by Raman spectroscopy

Mineral Group: [ pyroxene (81) ]

Quick search: [ All Spodumene samples (7) ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

de-polarized laser oriented perpendicular to the (010) face

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File
	Raman Mode Analysis

REFERENCES for Spodumene
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
d’Andrada J B (1800) Der Eigenschaften und Kennzeichen einiger neuen Fossilien aus Schweden und Norwegen nebst einigen chemischen Bemerkungen über dieselben, Allgemeines Journal der Chemie, 4, 28-39 [view file]
d’Andrada J B (1801) Description of some new fossils (Old English translation), A Journal of Natural Philosophy, Chemistry, and the Arts, 5, 193-196; 211-213 [view file]
Baskerville C, Kunz G F (1904) Kunzite and its unique properties, American Journal of Science, 18, 25-28 [view file]
Dana E S (1904) Monoclinic Section. Pyroxene, in The System of Mineralogy of James Dwight Data 1837-1868, Sixth Edition John Wiley & Sons New York 352-371 [view file]
Davis R O E (1904) Analysis of kunzite, American Journal of Science, 18, 29-29 [view file]
Megathlin G R (1928) Spodumeme and autunite from Alsead, New Hampshire, American Mineralogist, 13, 578-579 [view file]
Li C T, Peacor D R (1968) The crystal structure LiAlSi₂O₆-II (“β spodumene”), Zeitschrift für Kristallographie, 126, 46-65 [view file]
Li C T (1968) The crystal structure of LiAlSi₂O₆ III (high-quartz solid solution), Zeitschrift für Kristallographie, 127, 327-348 [view file]
Clarke P T, Spink J M (1969) The crystal structure of β spodumene LiAlSi₂O₆-II, Zeitschrift für Kristallographie, 130, 420-426 [view file]
Clark J R, Appleman D E, Papike J J (1969) Crystal-chemical characterization of clinopyroxenes based on eight new structure refinements, Mineralogical Society of America Special Paper, 2, 31-50 [view file]
Černý P, Ferguson R B (1972) The Tanco pegmatite at Bernic Lake, Manitoba. IV. Petalite and spodumene relations, The Canadian Mineralogist, 11, 660-678 [view file]
Černý P (1972) The Tanco pegmatite at Bernic Lake, Manitoba. VIII. Secondary minerals from the spodumene-rich zones, The Canadian Mineralogist, 11, 714-726 [view file]
Cameron M, Sueno S, Prewitt C T, Papike J J (1973) High-temperature crystal chemistry of acmite, diopside, hedenbergite, jadeite, spodumene, and ureyite, American Mineralogist, 58, 594-618 [view file]
International Mineralogical Association (1980) International Mineralogical Association: Commission on new minerals and mineral names, Mineralogical Magazine, 43, 1053-1055 [view file]
Cameron M, Papike J J (1981) Structural and chemical variations in pyroxenes, American Mineralogist, 66, 1-50 [view file]
Morimoto N (1988) Nomenclature of pyroxenes, Mineralogical Magazine, 52, 535-550 [view file]
Morimoto N (1989) Nomenclature of pyroxenes, The Canadian Mineralogist, 27, 143-156 [view file]
Charoy B, Lhote F, Dusausoy Y (1992) The crystal chemistry of spodumene in some granitic aplite-pegmatite of northern Portugal, The Canadian Mineralogist, 30, 639-651 [view file]
Scanu T, Guglielmi J, Colomban P (1994) Ion exchange and hot corrosion of ceramic composites matrices - A vibrational and microstructural study, Solid State Ionics, 70, 109-120 [link]
Charoy B, Noronha F, Lima A (2001) Spodumene – petalite – eucryptite: mutual relationships and pattern of alteration in Li-rich aplite-pegmatite dykes from northern Portugal, The Canadian Mineralogist, 39, 729-746 [view file]
Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]
Pommier C J S, Denton M B, Downs R T (2003) Raman spectroscopic study of spodumene (LiAlSi₂O₆) through the pressure-induced phase change from C2/c to P2₁/c, Journal of Raman Spectroscopy, 34, 769-775
Tribaudino M, Nestola F, Prencipe M, Rundlof H (2003) A single-crystal neutron-diffraction investigation of spodumene at 54 K, The Canadian Mineralogist, 41, 521-527 [view file]
Gatta G D, Boffa Ballaran T, Iezzi G (2005) High-pressure X-ray and Raman study of a ferrian magnesian spodumene, Physics and Chemistry of Minerals, 32, 132-139
Buzatu A, Buzgar N (2010) The Raman study of single-chain silicates, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 56, 107-125 [view file]
Pagliai M, Miranda M M, Cardini G, Schettino V (2011) Raman and infrared spectra of minerals from ab initio molecular dynamics simulations: the spodumene crystal, Journal of Molecular Structure, 993, 151-154
Iezzi G, Bromiley G D, Cavallo A, Das P P, Karavassili F, Margiolaki I, Stewart A A, Tribaudino M, Wright J P (2016) Solid solution along the synthetic LiAlSi₂O₆-LiFeSi₂O₆ (spodumene-ferri-spodumene) join: A general picture of solid solutions, bond lengths, lattice strains, steric effects, symmetries, and chemical compositions of Li clinopyroxenes, American Mineralogist, 101, 2498-2513
Nespolo M, Aroyo M I (2016) The modular structure of pyroxenes, European Journal of Mineralogy, 28, 189-203
O'Bannon E, Williams Q (2016) A Cr³⁺ luminescence study of spodumene at high pressures: Effects of site geometry, a phase transition, and a level-crossing, American Mineralogist, 101, 1406-1413
Dias F, Lima A, Roda-Robles E (2019) Mutual relationships between spodumene and petalite from the Iberian massif pegmatites: More than PT changes?, The Canadian Mineralogist, 57, 731-732
Simmons W B, Falster A U, Nizamoff J W, Freeman G (2019) Giant spodumene and montebrasite crystals from the Plumbago North pegmatite, Oxford County, Maine, The Canadian Mineralogist, 57, 795-797
Ding X, Li J, Chou I, Chen Z, Li S. (2020) Raman spectroscopic identification of cookeite in the crystal-rich inclusions in spodumene from the Jiajika lithium pegmatite deposit, China, and its geological implications, European Journal of Mineralogy, 32, 67-75 [view file]

REFERENCES for Spodumene

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

d’Andrada J B (1800) Der Eigenschaften und Kennzeichen einiger neuen Fossilien aus Schweden und Norwegen nebst einigen chemischen Bemerkungen über dieselben, Allgemeines Journal der Chemie, 4, 28-39 [view file]

d’Andrada J B (1801) Description of some new fossils (Old English translation), A Journal of Natural Philosophy, Chemistry, and the Arts, 5, 193-196; 211-213 [view file]

Baskerville C, Kunz G F (1904) Kunzite and its unique properties, American Journal of Science, 18, 25-28 [view file]

Dana E S (1904) Monoclinic Section. Pyroxene, in The System of Mineralogy of James Dwight Data 1837-1868, Sixth Edition John Wiley & Sons New York 352-371 [view file]

Davis R O E (1904) Analysis of kunzite, American Journal of Science, 18, 29-29 [view file]

Megathlin G R (1928) Spodumeme and autunite from Alsead, New Hampshire, American Mineralogist, 13, 578-579 [view file]

Li C T, Peacor D R (1968) The crystal structure LiAlSi₂O₆-II (“β spodumene”), Zeitschrift für Kristallographie, 126, 46-65 [view file]

Li C T (1968) The crystal structure of LiAlSi₂O₆ III (high-quartz solid solution), Zeitschrift für Kristallographie, 127, 327-348 [view file]

Clarke P T, Spink J M (1969) The crystal structure of β spodumene LiAlSi₂O₆-II, Zeitschrift für Kristallographie, 130, 420-426 [view file]

Clark J R, Appleman D E, Papike J J (1969) Crystal-chemical characterization of clinopyroxenes based on eight new structure refinements, Mineralogical Society of America Special Paper, 2, 31-50 [view file]

Černý P, Ferguson R B (1972) The Tanco pegmatite at Bernic Lake, Manitoba. IV. Petalite and spodumene relations, The Canadian Mineralogist, 11, 660-678 [view file]

Černý P (1972) The Tanco pegmatite at Bernic Lake, Manitoba. VIII. Secondary minerals from the spodumene-rich zones, The Canadian Mineralogist, 11, 714-726 [view file]

Cameron M, Sueno S, Prewitt C T, Papike J J (1973) High-temperature crystal chemistry of acmite, diopside, hedenbergite, jadeite, spodumene, and ureyite, American Mineralogist, 58, 594-618 [view file]

International Mineralogical Association (1980) International Mineralogical Association: Commission on new minerals and mineral names, Mineralogical Magazine, 43, 1053-1055 [view file]

Cameron M, Papike J J (1981) Structural and chemical variations in pyroxenes, American Mineralogist, 66, 1-50 [view file]

Morimoto N (1988) Nomenclature of pyroxenes, Mineralogical Magazine, 52, 535-550 [view file]

Morimoto N (1989) Nomenclature of pyroxenes, The Canadian Mineralogist, 27, 143-156 [view file]

Charoy B, Lhote F, Dusausoy Y (1992) The crystal chemistry of spodumene in some granitic aplite-pegmatite of northern Portugal, The Canadian Mineralogist, 30, 639-651 [view file]

Scanu T, Guglielmi J, Colomban P (1994) Ion exchange and hot corrosion of ceramic composites matrices - A vibrational and microstructural study, Solid State Ionics, 70, 109-120 [link]

Charoy B, Noronha F, Lima A (2001) Spodumene – petalite – eucryptite: mutual relationships and pattern of alteration in Li-rich aplite-pegmatite dykes from northern Portugal, The Canadian Mineralogist, 39, 729-746 [view file]

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]

Pommier C J S, Denton M B, Downs R T (2003) Raman spectroscopic study of spodumene (LiAlSi₂O₆) through the pressure-induced phase change from C2/c to P2₁/c, Journal of Raman Spectroscopy, 34, 769-775

Tribaudino M, Nestola F, Prencipe M, Rundlof H (2003) A single-crystal neutron-diffraction investigation of spodumene at 54 K, The Canadian Mineralogist, 41, 521-527 [view file]

Gatta G D, Boffa Ballaran T, Iezzi G (2005) High-pressure X-ray and Raman study of a ferrian magnesian spodumene, Physics and Chemistry of Minerals, 32, 132-139

Buzatu A, Buzgar N (2010) The Raman study of single-chain silicates, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 56, 107-125 [view file]

Pagliai M, Miranda M M, Cardini G, Schettino V (2011) Raman and infrared spectra of minerals from ab initio molecular dynamics simulations: the spodumene crystal, Journal of Molecular Structure, 993, 151-154

Iezzi G, Bromiley G D, Cavallo A, Das P P, Karavassili F, Margiolaki I, Stewart A A, Tribaudino M, Wright J P (2016) Solid solution along the synthetic LiAlSi₂O₆-LiFeSi₂O₆ (spodumene-ferri-spodumene) join: A general picture of solid solutions, bond lengths, lattice strains, steric effects, symmetries, and chemical compositions of Li clinopyroxenes, American Mineralogist, 101, 2498-2513

Nespolo M, Aroyo M I (2016) The modular structure of pyroxenes, European Journal of Mineralogy, 28, 189-203

O'Bannon E, Williams Q (2016) A Cr³⁺ luminescence study of spodumene at high pressures: Effects of site geometry, a phase transition, and a level-crossing, American Mineralogist, 101, 1406-1413

Dias F, Lima A, Roda-Robles E (2019) Mutual relationships between spodumene and petalite from the Iberian massif pegmatites: More than PT changes?, The Canadian Mineralogist, 57, 731-732

Simmons W B, Falster A U, Nizamoff J W, Freeman G (2019) Giant spodumene and montebrasite crystals from the Plumbago North pegmatite, Oxford County, Maine, The Canadian Mineralogist, 57, 795-797

Ding X, Li J, Chou I, Chen Z, Li S. (2020) Raman spectroscopic identification of cookeite in the crystal-rich inclusions in spodumene from the Jiajika lithium pegmatite deposit, China, and its geological implications, European Journal of Mineralogy, 32, 67-75 [view file]