) R060574 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Pascoite R060574

Name: Pascoite
RRUFF ID: R060574
Ideal Chemistry: Ca₃V⁵⁺₁₀O₂₈·17H₂O
Locality: Arrowhead Claim, Slick Rock, San Miguel County, Colorado, USA
Source: Michael Scott S100803 [view label]
Owner: RRUFF
Description: Orange vitreous crust
Status: The identification of this mineral has been confirmed by single-crystal X-ray diffraction.

Mineral Group: [ Pascoite (5) ]

CHEMISTRY

RRUFF ID:	R060574.2
Sample Description:	Microprobe Fragment

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R060574

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R060574.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 19.65(1)Å b: 10.185(8)Å c: 10.956(8)Å
alpha: 90° beta: 120.79(2)° gamma: 90° Volume: 1884(3)Å³ Crystal System: monoclinic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Pascoite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Hillebrand W F, Merwin H E, Wright F E (1914) Hewettite, metahewettite and pascoite, hydrous calcium vanadates, Proceedings of the American Philosophical Society, 53, 31-54 [view file]
Swallow A G, Ahmed F R, Barnes W H (1966) The crystal structure of pascoite, Ca₃V₁₀O₂₈·17H₂O, Acta Crystallographica, 21, 397-405
Frost R L, Erickson K L, Weier M L (2004) Hydrogen bonding in selected vanadates: a Raman and infrared spectroscopy study, Spectrochimica Acta Part A, 60, 2419
Hughes J M, Schindler M, Francis C A (2005) The C2/m disordered structure of pascoite, Ca₃[V₁₀O₂₈]·17H₂O: bonding between structural units and interstitial complexes in compounds containing the [V₁₀O₂₈]^6- decavanadanate polyanion, The Canadian Mineralogist, 43, 1379-1386 [view file]
Locock A J, Piilonen P C, Ercit T S, Rowe R, Kolitsch U (2006) New mineral names, American Mineralogist, 91, 710-715 [view file]
Kolitsch U, Rieck B, Brandstätter F, Schreiber F, Fabritz K H, Blaß G, Gröbner J (2014) Neufunde aus dem altem Bergbau und den Schlacken von Lavrion (II), Mineralien Welt, 25, 82-95
Hawthorne F C, Hughes J M, Cooper M A, Kampf A R (2022) Bonding between the decavanadate polyanion and the interstitial complex in pascoite-family minerals, The Canadian Mineralogist, 60, 341-359

REFERENCES for Pascoite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Hillebrand W F, Merwin H E, Wright F E (1914) Hewettite, metahewettite and pascoite, hydrous calcium vanadates, Proceedings of the American Philosophical Society, 53, 31-54 [view file]

Swallow A G, Ahmed F R, Barnes W H (1966) The crystal structure of pascoite, Ca₃V₁₀O₂₈·17H₂O, Acta Crystallographica, 21, 397-405

Frost R L, Erickson K L, Weier M L (2004) Hydrogen bonding in selected vanadates: a Raman and infrared spectroscopy study, Spectrochimica Acta Part A, 60, 2419

Hughes J M, Schindler M, Francis C A (2005) The C2/m disordered structure of pascoite, Ca₃[V₁₀O₂₈]·17H₂O: bonding between structural units and interstitial complexes in compounds containing the [V₁₀O₂₈]^6- decavanadanate polyanion, The Canadian Mineralogist, 43, 1379-1386 [view file]

Locock A J, Piilonen P C, Ercit T S, Rowe R, Kolitsch U (2006) New mineral names, American Mineralogist, 91, 710-715 [view file]

Kolitsch U, Rieck B, Brandstätter F, Schreiber F, Fabritz K H, Blaß G, Gröbner J (2014) Neufunde aus dem altem Bergbau und den Schlacken von Lavrion (II), Mineralien Welt, 25, 82-95

Hawthorne F C, Hughes J M, Cooper M A, Kampf A R (2022) Bonding between the decavanadate polyanion and the interstitial complex in pascoite-family minerals, The Canadian Mineralogist, 60, 341-359