) R100092 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Lithiophosphate R100092

Name: Lithiophosphate
RRUFF ID: R100092
Ideal Chemistry: Li₃(PO₄)
Locality: Cachoeira mine, Itinga, Minas Gerais, Brazil
Source: Luiz Menezes [view label]
Owner: RRUFF
Description: Colorless fragments and prismatic crystals
Status: The identification of this mineral has been confirmed by single-crystal X-ray diffraction.

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented Raman on the primary sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R100092

Wavelength:

Sample Description:

Unoriented Raman on the primary sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R100092.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 6.109(3)Å b: 5.228(3)Å c: 4.842(2)Å
alpha: 90° beta: 90° gamma: 90° Volume: 154.64(5)Å³ Crystal System: orthorhombic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Lithiophosphate
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Fleischer M (1957) New mineral names, American Mineralogist, 42, 580-586 [view file]
Matias V V, Bondareva A M (1957) Lithiophosphate - a new mineral, Doklady Akademii Nauk SSSR, 112, 124-126 [view file]
Fisher J (1958) Note on lithiophosphate, American Mineralogist, 43, 761-762 [view file]
Zemann J (1960) Die kristallstruktur von lithiumphosphat, Li₃PO₄, Acta Crystallographica, 13, 863-867
Swanson H E, Morris M C, Evans E H (1965) Lithium Phosphate, low form (lithiophosphate), Li₃PO₄ (orthorhombic) revised. Standard X-ray diffraction powder patterns, U.S. National Bureau of Standards, Monograph 25, Sec 4, 21-22 [view file]
Keffer C, Mighell A D, Mauer F, Swanson H, Block S (1967) The crystal structure of twinned low-temperature lithium phosphate, Inorganic Chemistry, 6, 119-125
White J S (1969) A lithiophosphate occurrence in North Carolina, American Mineralogist, 54, 1467-1469 [view file]
Bondareva O S, Simonov M A, Belov N V (1978) The crystal structure of the synthetic analogue of the lithiophospate γ-Li₃PO₄, Doklady Akademii Nauk SSSR, 240, 75-77 [view file]
Baur W H (1980) Solid solutions between octahedral and tetrahedral olivine types in Li-Zn-germanates, Inorganic and Nuclear Chemistry Letters, 16, 525-527
Rastsvetaeva R K, Khomyakov A P (1994) A comparative crystal-chemical study of the lithium-sodium phosphates (lithiophosphate, nalipoite, olympite, and Na₃PO₄), Crystallography Reports, 39, 35-41
Wang B, Chakoumakos B C, Sales B C, Kwak B S, Bates J B (1995) Synthesis, crystal structure, and ionic conductivity of a polycrystalline lithium phosphorus oxynitride with the γ-Li₃PO₄ structure, Journal of Solid State Chemistry, 115, 313-323
Yakubovich O V, Urosova V S (1997) Electron density distribution in lithiophosphatite Li₃PO₄: Crystallochemical features of orthophosphates with hexagonal close packing, Crystallography Reports, 42, 261-268

REFERENCES for Lithiophosphate

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Fleischer M (1957) New mineral names, American Mineralogist, 42, 580-586 [view file]

Matias V V, Bondareva A M (1957) Lithiophosphate - a new mineral, Doklady Akademii Nauk SSSR, 112, 124-126 [view file]

Fisher J (1958) Note on lithiophosphate, American Mineralogist, 43, 761-762 [view file]

Zemann J (1960) Die kristallstruktur von lithiumphosphat, Li₃PO₄, Acta Crystallographica, 13, 863-867

Swanson H E, Morris M C, Evans E H (1965) Lithium Phosphate, low form (lithiophosphate), Li₃PO₄ (orthorhombic) revised. Standard X-ray diffraction powder patterns, U.S. National Bureau of Standards, Monograph 25, Sec 4, 21-22 [view file]

Keffer C, Mighell A D, Mauer F, Swanson H, Block S (1967) The crystal structure of twinned low-temperature lithium phosphate, Inorganic Chemistry, 6, 119-125

White J S (1969) A lithiophosphate occurrence in North Carolina, American Mineralogist, 54, 1467-1469 [view file]

Bondareva O S, Simonov M A, Belov N V (1978) The crystal structure of the synthetic analogue of the lithiophospate γ-Li₃PO₄, Doklady Akademii Nauk SSSR, 240, 75-77 [view file]

Baur W H (1980) Solid solutions between octahedral and tetrahedral olivine types in Li-Zn-germanates, Inorganic and Nuclear Chemistry Letters, 16, 525-527

Rastsvetaeva R K, Khomyakov A P (1994) A comparative crystal-chemical study of the lithium-sodium phosphates (lithiophosphate, nalipoite, olympite, and Na₃PO₄), Crystallography Reports, 39, 35-41

Wang B, Chakoumakos B C, Sales B C, Kwak B S, Bates J B (1995) Synthesis, crystal structure, and ionic conductivity of a polycrystalline lithium phosphorus oxynitride with the γ-Li₃PO₄ structure, Journal of Solid State Chemistry, 115, 313-323

Yakubovich O V, Urosova V S (1997) Electron density distribution in lithiophosphatite Li₃PO₄: Crystallochemical features of orthophosphates with hexagonal close packing, Crystallography Reports, 42, 261-268