) R100127 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Important Update News

The RRUFF Project is being updated to improve its interface and content. The beta version of the update is accessible to the public at RRUFF.net. New data is only being added to the beta site. Please note that it is in development, and some components are not functional. Existing RRUFF.info links will resolve to the new site after RRUFF.net is officially released.

We are grateful to NASA for the funding of this effort.

Sillimanite R100127

Name: Sillimanite
RRUFF ID: R100127
Ideal Chemistry: Al₂SiO₅
Locality: Andana Tea Plantation, near Khawatha, Rathapura District, Sri Lanka
Source: William W. Pinch [view label]
Owner: RRUFF
Description: Transparent bluish-gray crystal fragment
Status: The identification of this mineral has been confirmed by single-crystal X-ray diffraction.

Mineral Group: [ Not in a structural group (133) ]

Quick search: [ All Sillimanite samples (5) ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented Raman on the primary sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R100127

Wavelength:

Sample Description:

Unoriented Raman on the primary sample

Instrument settings:

Thermo Almega XR 532nm @ 10% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R100127.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 7.487(2)Å b: 7.676(2)Å c: 5.7718(9)Å
alpha: 90° beta: 90° gamma: 90° Volume: 331.7(2)Å³ Crystal System: orthorhombic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Sillimanite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Bowen G T (1824) Description and analysis of sillimanite, a new mineral, American Journal of Science and Arts, 8, 113-118 [view file]
Bowen G T (1824) Description and analysis of sillimanite, a new mineral from Saybrook, in Connecticut, U.S., The Annals of Philosophy, 8, 315-316 [view file]
Richmond W E (1940) Crystal chemistry of the phosphates, arsenates and vanadates of the type A₂XO₄(Z), American Mineralogist, 25, 441-478 [view file]
Hutton C O (1950) Studies of heavy detrital minerals, Bulletin of the Geological Society of America, 61, 635-710 [view file]
Agrell S O, Smith J V (1957) X-ray crystallography of mullite, sillimanite and praguite, Acta Crystallographica, 10, 761-761
Foster C T (1982) Textural variation of sillimanite segregations, The Canadian Mineralogist, 20, 379-392 [view file]
Ghent E D, Knitter C C, Raeside R P, Stout M Z (1982) Geothermometry and geobarometry of pelitic rocks, upper kyanite and sillimanite zones, Mica Creek area, British Columbia, The Canadian Mineralogist, 20, 295-305 [view file]
Pigage L C (1982) Linear regression analysis of sillimanite–forming reactions at Azure Lake, British Columbia, The Canadian Mineralogist, 20, 349-378 [view file]
Grambling J A (1984) Coesxisting paragonite and quartz in sillimanitic rocks from New Mexico, American Mineralogist, 69, 79-87 [view file]
Foster C T (1991) The role of biotite as a catalyst in reaction mechanisms that form sillimanite, The Canadian Mineralogist, 29, 943-963 [view file]
Gordon T M, Ghent E D, Stout M Z (1991) Algebraic analysis of the biotite-sillimanite isograd in the File Lake area, Manitoba, The Canadian Mineralogist, 29, 673-686 [view file]
Mernagh T P, Liu L (1991) Raman spectra from the Al₂SiO₅ polymorphs at high pressure and room temperature, Physics and Chemistry of Minerals, 18, 126-130
Niven M L, Waters D J, Moore J M (1991) The crystal structure of werdingite, (Mg,Fe)₂Al₁₂(Al,Fe)₂Si₄(B,Al)₄O₃₇, and its relationship to sillimanite, mullite, and grandidierite, American Mineralogist, 76, 246-256 [view file]
Černý P, Novák M, Chapman R (1992) Effects of sillimanite-grade metamorphism and shearing on Nb-Ta oxide minerals in granitic pegmatites: Maršikov, northern Moravia, Czechoslovakia, The Canadian Mineralogist, 30, 699-718 [view file]
Peacor D R, Rouse R C, Grew E S (1999) Crystal structure of boralsilite and its relation to a family of boroaluminosilicates, sillimanite, and andalusite, American Mineralogist, 84, 1152-1161 [view file]
Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]
Burt J B, Ross N L, Angel R J, Koch M (2006) Equations of state and structures of andalusite to 9.8 GPa and sillimanite to 8.5 GPa, American Mineralogist, 91, 319-326 [view file]
Ohuchi F S, Ghose S, Engelhard M H, Baer D R (2006) Chemical bonding and electronic structures of the Al₂SiO₅ polymorphs, andalusite, sillimanite, and kyanite: X-ray photoelectron- and electron energy loss spectroscopy studies, American Mineralogist, 91, 740-746 [view file]
Gunter M E (2010) Defining asbestos: differences between the built and natural environments, Chimia, 64, 747-752
Fischer R X, Tikhonova V, Birkenstock J, Fischer L A, Herrmann K, Mengel K, Schneider H (2015) A new mineral from the Bellerberg, Eifel, Germany, intermediate between mullite and sillimanite, American Mineralogist, 100, 1493-1501 [view file]
Igami Y, Kuribayashi T, Miyake A (2018) Determination of Al/Si order in sillimanite by high angular resolution electron channeling X-ray spectroscopy, and implications for determining peak temperatures of sillimanite, American Mineralogist, 103, 944-951
Igami Y, Ohi S, Kogiso T, Furukawa N, Miyake A (2019) High-temperature structural change and microtexture formation of sillimanite and its phase relation with mullite, American Mineralogist, 104, 1051-1061
Whitney D L, Samuelson W J (2019) Crystallization sequences of coexisting andalusite, kyanite, and sillimanite, and a report on a new locality: Lesjaverk, Norway, European Journal of Mineralogy, 31, 731-737

REFERENCES for Sillimanite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Bowen G T (1824) Description and analysis of sillimanite, a new mineral, American Journal of Science and Arts, 8, 113-118 [view file]

Bowen G T (1824) Description and analysis of sillimanite, a new mineral from Saybrook, in Connecticut, U.S., The Annals of Philosophy, 8, 315-316 [view file]

Richmond W E (1940) Crystal chemistry of the phosphates, arsenates and vanadates of the type A₂XO₄(Z), American Mineralogist, 25, 441-478 [view file]

Hutton C O (1950) Studies of heavy detrital minerals, Bulletin of the Geological Society of America, 61, 635-710 [view file]

Agrell S O, Smith J V (1957) X-ray crystallography of mullite, sillimanite and praguite, Acta Crystallographica, 10, 761-761

Foster C T (1982) Textural variation of sillimanite segregations, The Canadian Mineralogist, 20, 379-392 [view file]

Ghent E D, Knitter C C, Raeside R P, Stout M Z (1982) Geothermometry and geobarometry of pelitic rocks, upper kyanite and sillimanite zones, Mica Creek area, British Columbia, The Canadian Mineralogist, 20, 295-305 [view file]

Pigage L C (1982) Linear regression analysis of sillimanite–forming reactions at Azure Lake, British Columbia, The Canadian Mineralogist, 20, 349-378 [view file]

Grambling J A (1984) Coesxisting paragonite and quartz in sillimanitic rocks from New Mexico, American Mineralogist, 69, 79-87 [view file]

Foster C T (1991) The role of biotite as a catalyst in reaction mechanisms that form sillimanite, The Canadian Mineralogist, 29, 943-963 [view file]

Gordon T M, Ghent E D, Stout M Z (1991) Algebraic analysis of the biotite-sillimanite isograd in the File Lake area, Manitoba, The Canadian Mineralogist, 29, 673-686 [view file]

Mernagh T P, Liu L (1991) Raman spectra from the Al₂SiO₅ polymorphs at high pressure and room temperature, Physics and Chemistry of Minerals, 18, 126-130

Niven M L, Waters D J, Moore J M (1991) The crystal structure of werdingite, (Mg,Fe)₂Al₁₂(Al,Fe)₂Si₄(B,Al)₄O₃₇, and its relationship to sillimanite, mullite, and grandidierite, American Mineralogist, 76, 246-256 [view file]

Černý P, Novák M, Chapman R (1992) Effects of sillimanite-grade metamorphism and shearing on Nb-Ta oxide minerals in granitic pegmatites: Maršikov, northern Moravia, Czechoslovakia, The Canadian Mineralogist, 30, 699-718 [view file]

Peacor D R, Rouse R C, Grew E S (1999) Crystal structure of boralsilite and its relation to a family of boroaluminosilicates, sillimanite, and andalusite, American Mineralogist, 84, 1152-1161 [view file]

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]

Burt J B, Ross N L, Angel R J, Koch M (2006) Equations of state and structures of andalusite to 9.8 GPa and sillimanite to 8.5 GPa, American Mineralogist, 91, 319-326 [view file]

Ohuchi F S, Ghose S, Engelhard M H, Baer D R (2006) Chemical bonding and electronic structures of the Al₂SiO₅ polymorphs, andalusite, sillimanite, and kyanite: X-ray photoelectron- and electron energy loss spectroscopy studies, American Mineralogist, 91, 740-746 [view file]

Gunter M E (2010) Defining asbestos: differences between the built and natural environments, Chimia, 64, 747-752

Fischer R X, Tikhonova V, Birkenstock J, Fischer L A, Herrmann K, Mengel K, Schneider H (2015) A new mineral from the Bellerberg, Eifel, Germany, intermediate between mullite and sillimanite, American Mineralogist, 100, 1493-1501 [view file]

Igami Y, Kuribayashi T, Miyake A (2018) Determination of Al/Si order in sillimanite by high angular resolution electron channeling X-ray spectroscopy, and implications for determining peak temperatures of sillimanite, American Mineralogist, 103, 944-951

Igami Y, Ohi S, Kogiso T, Furukawa N, Miyake A (2019) High-temperature structural change and microtexture formation of sillimanite and its phase relation with mullite, American Mineralogist, 104, 1051-1061

Whitney D L, Samuelson W J (2019) Crystallization sequences of coexisting andalusite, kyanite, and sillimanite, and a report on a new locality: Lesjaverk, Norway, European Journal of Mineralogy, 31, 731-737