----- R050257 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Triphylite R050257

Name: Triphylite
RRUFF ID: R050257
Ideal Chemistry: LiFe²⁺(PO₄)
Locality: Palermo mine, North Groton, Grafton County, New Hampshire, USA
Source: Marcus Origlieri
Owner: RRUFF
Description: Dark gray massive
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ Olivine (61) ]

Quick search: [ All Triphylite samples (6) ]

CHEMISTRY

RRUFF ID:	R050257.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	Li_1.00(Fe²⁺_0.73Mn²⁺_0.19Mg_0.08)_Σ=1P_1.00O₄

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

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To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R050257

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R050257.1

Sample Description:

Powder

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

RRUFF ID:

R050257.1

Sample Description:

Powder

Instrument settings:

PIKE GladiATR - Far-IR on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R050257.1

Sample Description:

Powder

Cell Refinement Output:

a: 4.7019(5)Å b: 10.3440(6)Å c: 6.0142(5)Å
alpha: 90° beta: 90° gamma: 90° Volume: 292.51(3)Å³ Crystal System: orthorhombic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Triphylite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Fuchs J N (1834) Ueber ein neues Mineral (Triphylin), Journal für Praktische Chemie, 3, 98-104 [view file]
Björling C O, Westgren A (1938) Minerals of the Varusträsk Pegmatite. IX. X-ray studies of triphylite, varulite and their oxidation products, Geologiska Föreningens i Stockholm Förhandlingar, 60, 67-72 [view file]
Björling C O, Westgren A (1938) Minerals of the Varuträsk Pegmatite, Geologiska Föreningens i Stockholm Förhandlingar, 60, 67-72 [view file]
Fontan P F, Huvelin P, Orliac M, Permingeat F (1976) La ferrisicklérite des pegmatites de sidi bou othmane (Jebilet, Maroc) et le groupe des minéraux à structure de triphylite, Bulletin de la Société Française de Minéralogie et de Cristallographie, 99, 274-286 [view file]
Fransolet A M (1977) Intercroissances et inclusions dans les associations graftonite-sarcopside-triphylite, Bulletin de la Société Française de Minéralogie et de Cristallographie, 100, 198-207 [view file]
Yakubovich O V, Simonov M A, Belov N V (1977) The crystal structure of a synthetic triphylite LiFe[PO₄], Soviet Physics - Doklady, 22, 347-348
Deganello S (1978) The crystal structure of triphylite after oxidation at 670°C, Neues Jahrbuch für Mineralogie, Monatshefte, 1978, 128-134
Fransolet A-M, Antenucci D, Speetjens J-M, Tarte P (1984) An X-ray determinative method for the divalent cation ratio in the triphylite-lithiophilite series, Mineralogical Magazine, 48, 373-381 [view file]
Shigley J E, Brown G E (1985) Occurance and alteration of phosphate minerals at the Stewart Pegmatite, Pala District, San Diego County, California, American Mineralogist, 70, 395-408 [view file]
Wise M A, Černý P (1990) Beusite-triphylite intergrowths from the Yellowknife pegmatite field, Northwest Territories, The Canadian Mineralogist, 28, 133-139 [view file]
Streltsov V A, Belokoneva E L, Tsirelson V G, Hansen N K (1993) Multipole analysis of the electron density in triphylite, LiFePO₄, using X-ray diffraction data, Acta Crystallographica, B49, 147-153
Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]
Losey A, Rakovan J, Hughes J M, Francis C A, Dyar M D (2004) Structural variation in the lithiophilite-triphylite series and other olivine-group structures, The Canadian Mineralogist, 42, 1105-1115 [view file]
Fehr K Y, Hochleitner R, Schmidbauer E, Schneider J (2007) Mineralogy, Mössbauer spectra and electrical conductivity of triphylite Li(Fe²⁺,Mn²⁺)PO₄, Physics and Chemistry of Minerals, 34, 485-494
Dyar M D, Jawin E R, Breves E, Marchand G, Nelms M, Lane M D, Mertzman S A, Bish D L and Bishop J L (2014) Mössbauer parameters of iron in phosphate minerals: Implications for interpretation of martian data, American Mineralogist, 99, 914-942 [view file]
Roda-Robles E, Pesquera A, García de Madinabeitia S , Gil Ibarguchi J, Nizamoff J, Simmons W, Falster A, Galliski M A (2014) On the geochemical character of primary Fe-Mn phosphates belonging to the triphylite-lithiophilite, graftonite-beusite, and triplite-zwieselite series: first results and implications for pegmatite petrogenesis, The Canadian Mineralogist, 52, 321-335 [view file]
Birch W D (2018) Minerals in the arrojadite, alluaudite and jahnsite-whiteite groups from the Mount Wills pegmatite field, Victoria, Australia, European Journal of Mineralogy, 30, 635-645
Lyalina L M, Selivanova E A, Hatert F (2023) Nomenclature of the triphylite group of minerals, European Journal of Mineralogy, 35, 427-437 [view file]

REFERENCES for Triphylite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Fuchs J N (1834) Ueber ein neues Mineral (Triphylin), Journal für Praktische Chemie, 3, 98-104 [view file]

Björling C O, Westgren A (1938) Minerals of the Varusträsk Pegmatite. IX. X-ray studies of triphylite, varulite and their oxidation products, Geologiska Föreningens i Stockholm Förhandlingar, 60, 67-72 [view file]

Björling C O, Westgren A (1938) Minerals of the Varuträsk Pegmatite, Geologiska Föreningens i Stockholm Förhandlingar, 60, 67-72 [view file]

Fontan P F, Huvelin P, Orliac M, Permingeat F (1976) La ferrisicklérite des pegmatites de sidi bou othmane (Jebilet, Maroc) et le groupe des minéraux à structure de triphylite, Bulletin de la Société Française de Minéralogie et de Cristallographie, 99, 274-286 [view file]

Fransolet A M (1977) Intercroissances et inclusions dans les associations graftonite-sarcopside-triphylite, Bulletin de la Société Française de Minéralogie et de Cristallographie, 100, 198-207 [view file]

Yakubovich O V, Simonov M A, Belov N V (1977) The crystal structure of a synthetic triphylite LiFe[PO₄], Soviet Physics - Doklady, 22, 347-348

Deganello S (1978) The crystal structure of triphylite after oxidation at 670°C, Neues Jahrbuch für Mineralogie, Monatshefte, 1978, 128-134

Fransolet A-M, Antenucci D, Speetjens J-M, Tarte P (1984) An X-ray determinative method for the divalent cation ratio in the triphylite-lithiophilite series, Mineralogical Magazine, 48, 373-381 [view file]

Shigley J E, Brown G E (1985) Occurance and alteration of phosphate minerals at the Stewart Pegmatite, Pala District, San Diego County, California, American Mineralogist, 70, 395-408 [view file]

Wise M A, Černý P (1990) Beusite-triphylite intergrowths from the Yellowknife pegmatite field, Northwest Territories, The Canadian Mineralogist, 28, 133-139 [view file]

Streltsov V A, Belokoneva E L, Tsirelson V G, Hansen N K (1993) Multipole analysis of the electron density in triphylite, LiFePO₄, using X-ray diffraction data, Acta Crystallographica, B49, 147-153

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]

Losey A, Rakovan J, Hughes J M, Francis C A, Dyar M D (2004) Structural variation in the lithiophilite-triphylite series and other olivine-group structures, The Canadian Mineralogist, 42, 1105-1115 [view file]

Fehr K Y, Hochleitner R, Schmidbauer E, Schneider J (2007) Mineralogy, Mössbauer spectra and electrical conductivity of triphylite Li(Fe²⁺,Mn²⁺)PO₄, Physics and Chemistry of Minerals, 34, 485-494

Dyar M D, Jawin E R, Breves E, Marchand G, Nelms M, Lane M D, Mertzman S A, Bish D L and Bishop J L (2014) Mössbauer parameters of iron in phosphate minerals: Implications for interpretation of martian data, American Mineralogist, 99, 914-942 [view file]

Roda-Robles E, Pesquera A, García de Madinabeitia S , Gil Ibarguchi J, Nizamoff J, Simmons W, Falster A, Galliski M A (2014) On the geochemical character of primary Fe-Mn phosphates belonging to the triphylite-lithiophilite, graftonite-beusite, and triplite-zwieselite series: first results and implications for pegmatite petrogenesis, The Canadian Mineralogist, 52, 321-335 [view file]

Birch W D (2018) Minerals in the arrojadite, alluaudite and jahnsite-whiteite groups from the Mount Wills pegmatite field, Victoria, Australia, European Journal of Mineralogy, 30, 635-645

Lyalina L M, Selivanova E A, Hatert F (2023) Nomenclature of the triphylite group of minerals, European Journal of Mineralogy, 35, 427-437 [view file]