- R050030 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Hedenbergite R050030

Name: Hedenbergite
RRUFF ID: R050030
Ideal Chemistry: CaFe²⁺Si₂O₆
Locality: Heroult, Ontario, Canada
Source: University of Arizona Mineral Museum 4120 [view label]
Owner: RRUFF
Description: Green fragments
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ pyroxene (81) ]

Quick search: [ All Hedenbergite samples (4) ]

CHEMISTRY

RRUFF ID:	R050030.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	(Ca_.993Na_.007)(Fe_.860Mn_.111Mg_.029)(Si_.993Al_.007)₂O₆

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Sample is oriented, mounted onto a pin and polished

Pin ID:

M00111

Orientation:

Laser parallel to a* (1 0 0). Fiducial mark perpendicular to laser is parallel to b [0 1 0].

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R050030

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R050030.1

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R050030.1

Sample Description:

Powder

Cell Refinement Output:

a: 9.8416(8)Å b: 9.0253(5)Å c: 5.2520(3)Å
alpha: 90.° beta: 104.86(1)° gamma: 90.° Volume: 450.89(5)Å³ Crystal System: monoclinic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Hedenbergite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Berzelius J J (1819) Hedenbergite, in Nouveau Système de Minéralogie Méquignon-Marvis Paris 269-270 [view file]
Dana E S (1904) Monoclinic Section. Pyroxene, in The System of Mineralogy of James Dwight Data 1837-1868, Sixth Edition John Wiley & Sons New York 352-371 [view file]
Kuno H, Hess H H (1953) Unit cell dimensions of clinoenstatite and pigeonite in relation to other common clinopyroxenes, American Journal of Science, 251, 741-752
Nolan J (1969) Physical properties of synthetic and natural pyroxenes in the system diopside-hedenbergite-acmite, Mineralogical Magazine, 37, 216-229 [view file]
Rutstein M S, Yund R A (1969) Unit-cell parameters of synthetic diopside-hedenbergite solid solutions, American Mineralogist, 54, 238-245 [view file]
Cameron M, Sueno S, Prewitt C T, Papike J J (1973) High-temperature crystal chemistry of acmite, diopside, hedenbergite, jadeite, spodumene, and ureyite, American Mineralogist, 58, 594-618 [view file]
Turnock A C, Lindsley D H, Grover J E (1973) Synthesis and unit cell parameters of Ca-Mg-Fe pyroxenes, American Mineralogist, 58, 50-59 [view file]
Ohashi Y, Burnham C W, Finger L W (1975) The effect of Ca-Fe on the clinopyroxene crystal structure, American Mineralogist, 60, 423-434 [view file]
Cameron M, Papike J J (1981) Structural and chemical variations in pyroxenes, American Mineralogist, 66, 1-50 [view file]
Morimoto N (1988) Nomenclature of pyroxenes, Mineralogical Magazine, 52, 535-550 [view file]
Raudsepp M, Hawthorne F C, Turnock A C (1990) Evaluation of the Rietveld method for the characterization of fine-grained products of mineral synthesis: the diopside-hedenbergite join, The Canadian Mineralogist, 28, 93-109 [view file]
Inoue A, Utada M (1991) Pumpellyite and related minerals from hydrothermally altered rocks at the Kamikita area, northern Honshu Japan, The Canadian Mineralogist, 29, 255-270 [view file]
Nakano T (1991) An antipathetic relation between the hedenbergite and johannsenite components in skarn clinopyroxene from the Kagata tungsten deposit, central Japan, The Canadian Mineralogist, 29, 427-434 [view file]
Huang E, Chen C H, Huang T, Lin E H, Xu J (2000) Raman spectroscopic characteristics of Mg-Fe-Ca pyroxenes, American Mineralogist, 85, 473-479 [view file]
Redhammer G J, Amthauer G, Lottermoser W, Treutmann W (2000) Synthesis and structural properties of clinopyroxenes of the hedenbergite CaFeSi₂O₆ - aegirine NaFeSi₂O₆ solid-solution series, European Journal of Mineralogy, 12, 105-120
Wang A, Jolliff B L, Haskin L A, Kuebler K E, Viskupic K M (2001) Characterization and comparison of structural and compositional features of planetary quadrilateral pyroxenes by Raman spectroscopy, American Mineralogist, 86, 790-806 [view file]
Heuer M, Huber A L, Bromiley G D, Fehr K T, Bente K (2002) Characterization of synthetic hedenbergite (CaFeSi₂O₆)–petedunnite (CaZnSi₂O₆) solid solution series by X-ray single crystal diffraction, Physics and Chemistry of Minerals, 32, 552-563
Redhammer G J, Amthauer G, Roth G, Tippelt G, Lottermoser W (2006) Single crystal X-ray diffraction and temperature dependent ⁵⁷Fe Mössbauer spectroscopy on the hedenbergite - aegirine (Ca,Na)(Fe²⁺,Fe³⁺)Si₂O₆ solid solution, American Mineralogist, 91, 1271-1292 [view file]
Nestola F, Tribaudino M, Boffa Ballaran T, Liebske C, Bruno M (2007) The crystal structure of pyroxenes along the jadeite-hedenbergite and jadeite-aegirine joins, American Mineralogist, 92, 1492-1501 [view file]
Buzatu A, Buzgar N (2010) The Raman study of single-chain silicates, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 56, 107-125 [view file]
Abdu Y A, Hawthorne F C (2013) Local structure in C2/c clinopyroxenes on the hedenbergite (CaFeSi₂O₆)-ferrosilite (Fe₂Si₂O₆) join: A new interpretation for the Mössbauer spectra of Ca-rich C2/c clinopyroxenes and implications for pyroxene exsolution, American Mineralogist, 98, 1227-1234
Mantovani L, Tribaudino M, Mezzadri F, Calestani G, Bromiley G (2013) The structure of (Ca,Co)CoSi₂O₆ pyroxenes and the Ca-M²⁺ substitution in (Ca,M²⁺)M²⁺Si₂O₆ pyroxenes (M²⁺ = Co, Fe, Mg), American Mineralogist, 98, 1241-1252
Kolitsch U, Rieck B, Brandstätter F, Schreiber F, Fabritz K H, Blaß G, Gröbner J (2014) Neufunde aus dem altem Bergbau und den Schlacken von Lavrion (II), Mineralien Welt, 25, 82-95
Mantovani L, Tribaudino M, Bertoni G, Salvianti G, Bromiley G (2014) Solid solutions and phase transitions in (Ca,M²⁺)M²⁺Si₂O₆ pyroxenes (M²⁺ = Co, Fe, Mg), American Mineralogist, 99, 704-711
Tribaudino M, Mantovani L (2014) Thermal expansion in C2/c pyroxenes: a review and new high-temperature structural data for a pyroxene of composition (Na_0.53Ca_0.47)(Al_0.53Fe_0.47)Si₂O₆ (Jd₅₃Hd₄₇), Mineralogical Magazine, 78, 311-324
Nespolo M, Aroyo M I (2016) The modular structure of pyroxenes, European Journal of Mineralogy, 28, 189-203
Nagashima M, Nishio-Hamane D (2018) Transmission electron microscopy study of the epitaxial association of hedenbergite whiskers with babingtonite, Mineralogical Magazine, 82, 23-33

REFERENCES for Hedenbergite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Berzelius J J (1819) Hedenbergite, in Nouveau Système de Minéralogie Méquignon-Marvis Paris 269-270 [view file]

Dana E S (1904) Monoclinic Section. Pyroxene, in The System of Mineralogy of James Dwight Data 1837-1868, Sixth Edition John Wiley & Sons New York 352-371 [view file]

Kuno H, Hess H H (1953) Unit cell dimensions of clinoenstatite and pigeonite in relation to other common clinopyroxenes, American Journal of Science, 251, 741-752

Nolan J (1969) Physical properties of synthetic and natural pyroxenes in the system diopside-hedenbergite-acmite, Mineralogical Magazine, 37, 216-229 [view file]

Rutstein M S, Yund R A (1969) Unit-cell parameters of synthetic diopside-hedenbergite solid solutions, American Mineralogist, 54, 238-245 [view file]

Cameron M, Sueno S, Prewitt C T, Papike J J (1973) High-temperature crystal chemistry of acmite, diopside, hedenbergite, jadeite, spodumene, and ureyite, American Mineralogist, 58, 594-618 [view file]

Turnock A C, Lindsley D H, Grover J E (1973) Synthesis and unit cell parameters of Ca-Mg-Fe pyroxenes, American Mineralogist, 58, 50-59 [view file]

Ohashi Y, Burnham C W, Finger L W (1975) The effect of Ca-Fe on the clinopyroxene crystal structure, American Mineralogist, 60, 423-434 [view file]

Cameron M, Papike J J (1981) Structural and chemical variations in pyroxenes, American Mineralogist, 66, 1-50 [view file]

Morimoto N (1988) Nomenclature of pyroxenes, Mineralogical Magazine, 52, 535-550 [view file]

Raudsepp M, Hawthorne F C, Turnock A C (1990) Evaluation of the Rietveld method for the characterization of fine-grained products of mineral synthesis: the diopside-hedenbergite join, The Canadian Mineralogist, 28, 93-109 [view file]

Inoue A, Utada M (1991) Pumpellyite and related minerals from hydrothermally altered rocks at the Kamikita area, northern Honshu Japan, The Canadian Mineralogist, 29, 255-270 [view file]

Nakano T (1991) An antipathetic relation between the hedenbergite and johannsenite components in skarn clinopyroxene from the Kagata tungsten deposit, central Japan, The Canadian Mineralogist, 29, 427-434 [view file]

Huang E, Chen C H, Huang T, Lin E H, Xu J (2000) Raman spectroscopic characteristics of Mg-Fe-Ca pyroxenes, American Mineralogist, 85, 473-479 [view file]

Redhammer G J, Amthauer G, Lottermoser W, Treutmann W (2000) Synthesis and structural properties of clinopyroxenes of the hedenbergite CaFeSi₂O₆ - aegirine NaFeSi₂O₆ solid-solution series, European Journal of Mineralogy, 12, 105-120

Wang A, Jolliff B L, Haskin L A, Kuebler K E, Viskupic K M (2001) Characterization and comparison of structural and compositional features of planetary quadrilateral pyroxenes by Raman spectroscopy, American Mineralogist, 86, 790-806 [view file]

Heuer M, Huber A L, Bromiley G D, Fehr K T, Bente K (2002) Characterization of synthetic hedenbergite (CaFeSi₂O₆)–petedunnite (CaZnSi₂O₆) solid solution series by X-ray single crystal diffraction, Physics and Chemistry of Minerals, 32, 552-563

Redhammer G J, Amthauer G, Roth G, Tippelt G, Lottermoser W (2006) Single crystal X-ray diffraction and temperature dependent ⁵⁷Fe Mössbauer spectroscopy on the hedenbergite - aegirine (Ca,Na)(Fe²⁺,Fe³⁺)Si₂O₆ solid solution, American Mineralogist, 91, 1271-1292 [view file]

Nestola F, Tribaudino M, Boffa Ballaran T, Liebske C, Bruno M (2007) The crystal structure of pyroxenes along the jadeite-hedenbergite and jadeite-aegirine joins, American Mineralogist, 92, 1492-1501 [view file]

Buzatu A, Buzgar N (2010) The Raman study of single-chain silicates, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 56, 107-125 [view file]

Abdu Y A, Hawthorne F C (2013) Local structure in C2/c clinopyroxenes on the hedenbergite (CaFeSi₂O₆)-ferrosilite (Fe₂Si₂O₆) join: A new interpretation for the Mössbauer spectra of Ca-rich C2/c clinopyroxenes and implications for pyroxene exsolution, American Mineralogist, 98, 1227-1234

Mantovani L, Tribaudino M, Mezzadri F, Calestani G, Bromiley G (2013) The structure of (Ca,Co)CoSi₂O₆ pyroxenes and the Ca-M²⁺ substitution in (Ca,M²⁺)M²⁺Si₂O₆ pyroxenes (M²⁺ = Co, Fe, Mg), American Mineralogist, 98, 1241-1252

Kolitsch U, Rieck B, Brandstätter F, Schreiber F, Fabritz K H, Blaß G, Gröbner J (2014) Neufunde aus dem altem Bergbau und den Schlacken von Lavrion (II), Mineralien Welt, 25, 82-95

Mantovani L, Tribaudino M, Bertoni G, Salvianti G, Bromiley G (2014) Solid solutions and phase transitions in (Ca,M²⁺)M²⁺Si₂O₆ pyroxenes (M²⁺ = Co, Fe, Mg), American Mineralogist, 99, 704-711

Tribaudino M, Mantovani L (2014) Thermal expansion in C2/c pyroxenes: a review and new high-temperature structural data for a pyroxene of composition (Na_0.53Ca_0.47)(Al_0.53Fe_0.47)Si₂O₆ (Jd₅₃Hd₄₇), Mineralogical Magazine, 78, 311-324

Nespolo M, Aroyo M I (2016) The modular structure of pyroxenes, European Journal of Mineralogy, 28, 189-203

Nagashima M, Nishio-Hamane D (2018) Transmission electron microscopy study of the epitaxial association of hedenbergite whiskers with babingtonite, Mineralogical Magazine, 82, 23-33