- R110109 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Rutile R110109

Name: Rutile
RRUFF ID: R110109
Ideal Chemistry: TiO₂
Locality: Synthetic
Source: Gemological Institute of America 10-12-2010-14 [view label]
Owner: RRUFF
Description: A cut, pale yellow (1.50ct) gemstone, grown by flame fusion.
Status: The identification of this mineral has been confirmed by single-crystal X-ray diffraction.

Mineral Group: [ Rutile (23) ]

Quick search: [ All Rutile samples (7) ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented Raman on the primary sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

Raman Mode Analysis

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R110109

Wavelength:

Sample Description:

Unoriented Raman on the primary sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R110109.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 4.605(3)Å b: 4.605(3)Å c: 2.968(1)Å
alpha: 90° beta: 90° gamma: 90° Volume: 62.94(2)Å³ Crystal System: tetragonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Rutile
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Lampadius W A (1800) Noch ein Paar Bemertungen über den Uran- und Titangehalt einiger Fossilien. Der rothe schörl (Rutil, nach herrn Bergrath Werner), in Sammlung practisch-chemischer Abhandlungen und vermischter Bemerkungen, Volume 3 Walther Dresden [view file]
Ludwig C F (1803) Rutil, in Handbuch der Mineralogie nach A. G. Werner, Volume 1 Siegfried Lebrécht Crusius Leipzig 305-306 [view file]
Schoβberger, F. (1942) Über die umwandlungen des titandioxyds, Journal of Solid State Chemistry, 104, 358-374
Hutton C O (1950) Studies of heavy detrital minerals, Bulletin of the Geological Society of America, 61, 635-710 [view file]
Baur W H (1956) Über die verfeinerung der kristallstrukturbestimmung einiger vertreter des rutiltyps: TiO₂, SnO₂, GeO₂ und MgF₂, Acta Crystallographica, 9, 515-520 [link]
Bond W L (1965) Measurement of the refractive indices of several crystals, Journal of Applied Physics, 36, 1674-1677 [view file]
Papezik V S, De Witt M J (1973) Shorter communications: Coarse-grained rutile from northern Newfoundland, The Canadian Mineralogist, 12, 224-225 [view file]
Corlett M I, McIlreath I A (1974) An authigenic quartz-calcite-rutile assemblage in ordovician limestones, The Canadian Mineralogist, 12, 411-416 [view file]
Meagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO₂ polymorphs: refinement of the crystal structures of rutile and brookite at high temperature, The Canadian Mineralogist, 17, 77-85 [view file]
Černý P, Paul B J, Hawthorne F C, Chapman R (1981) A niobian rutile – disordered columbite intergrowth from the Huron Claim pegmatite, southeastern Manitoba, The Canadian Mineralogist, 19, 541-548 [view file]
Spear F S (1982) Phase equilibria of amphibolites from the post pond volcanics, Mt. cube quadrangle, Vermont, Journal of Petrology, 23, 383-426
Andrews A J, Masliwec A, Morris W A, Owsiacki L, York D (1986) The silver deposits at Cobalt and Gowganda, Ontario. II: An experiment in age determinations employing radiometric and paleomagnetic measurements, Canadian Journal of Earth Sciences, 23, 1507-1518
Kudoh Y, Takeda H (1986) Single crystal X-ray diffraction study on the bond compressibility of fayalite, Fe₂SiO₄ and rutile, TiO₂ under high pressure, Physica B, 139, 333-336
Tollo R P, Haggerty S E (1987) Nb–Cr-rutile in the Orapa kimberlite, Botswana, The Canadian Mineralogist, 25, 251-264 [view file]
Howard C J, Sabine T M, Dickson F (1991) Structural and thermal parameters for rutile and anatase, Acta Crystallographica, B47, 462-468
Sugiyama K, Takéuchi Y (1991) The crystal structure of rutile as a function of temperature up to 1600°C, Zeitschrift für Kristallographie, 194, 305-313 [view file]
Bursill (1996) Boron incorporation into rutile. phase equilibria and structure considerations, Journal of Solid State Chemistry, 127, 240-247
Rams J, Tejeda A, Cabrera J M (1997) Refractive indices of rutile as a function of temperature and wavelength, Journal of Applied Physics, 82, 994-997
Gesenhues U, Rentschler T (1999) Crystal growth and defect structure of Al³⁺-doped rutile, Journal of Solid State Chemistry, 143, 210-218
Bokhimi X, Morales A, Pedraza F (2002) Crystallography and crystallite morphology of rutile synthesized at low temperature, Journal of Solid State Chemistry, 169, 176-181
Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]
Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file]
Toledo-Antonio J A, Gutierrez-Baez R, Sebastian P J, Vazquez A (2003) Thermal stability and structural deformation of rutile SnO₂, Journal of Solid State Chemistry, 174, 241-248
Clarke D B, Carruzzo S (2007) Assimilation of country-rock ilmenite and rutile in the South Mountain batholith, Nova Scotia, Canada, The Canadian Mineralogist, 45, 31-42 [view file]
Glass B P, Fries M (2008) Micro-Raman spectroscopic study of fine-grained, shock-metamorphosed rock fragments from the Australasian microtektite layer, Meteoritics and Planetary Science, 43, 1487-1496 [view file]
Gunter M E (2010) Defining asbestos: differences between the built and natural environments, Chimia, 64, 747-752
Armbruster T, Lazic B, Reznitsky L Z, Sklyarov E V (2013) Kyzylkumite, Ti₂V³⁺O₅(OH): new structure type, modularity and revised formula, Mineralogical Magazine, 77, 33-44 [view file]
Daneu N, Rečnik A, Mader W (2014) Atomic structure and formation mechanism of (101) rutile twins from Diamantina (Brazil), American Mineralogist, 99, 612-624
Robinson P, Langenhorst F, McEnroe S A, Fabian K, Ballaran T B (2014) Ferroan geikielite and coupled spinel-rutile exsolution from titanohematite: interface characterization and magnetic properties, American Mineralogist, 99, 1694-1712
MacDonald R, Bagiński B, Kartashov P M, Zozulya D, Dzierżanowski (2015) Interaction of rare-metal minerals with hydrothermal fluids: Evidence from quartz-epidote metasomatites of the Haldzan Buragtag Massif, Mongolian Altai, The Canadian Mineralogist, 53, 1015-1034
Di Cecco V E, Tait K T, Spooner E T C, Scherba C (2018) The vanadium-bearing oxide minerals of the Green Giant vanadium-graphite deposit, southwest Madagascar, The Canadian Mineralogist, 56, 247-257
Negrão L B A, Da Costa M L, Pöllmann H, Horn A (2018) An application of the Rietveld refinement method to the mineralogy of a bauxite-bearing regolith in the Lower Amazon, Mineralogical Magazine, 82, 413-431
Tschauner O (2019) High-pressure minerals, American Mineralogist, 104, 1701-1731

REFERENCES for Rutile

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Lampadius W A (1800) Noch ein Paar Bemertungen über den Uran- und Titangehalt einiger Fossilien. Der rothe schörl (Rutil, nach herrn Bergrath Werner), in Sammlung practisch-chemischer Abhandlungen und vermischter Bemerkungen, Volume 3 Walther Dresden [view file]

Ludwig C F (1803) Rutil, in Handbuch der Mineralogie nach A. G. Werner, Volume 1 Siegfried Lebrécht Crusius Leipzig 305-306 [view file]

Schoβberger, F. (1942) Über die umwandlungen des titandioxyds, Journal of Solid State Chemistry, 104, 358-374

Hutton C O (1950) Studies of heavy detrital minerals, Bulletin of the Geological Society of America, 61, 635-710 [view file]

Baur W H (1956) Über die verfeinerung der kristallstrukturbestimmung einiger vertreter des rutiltyps: TiO₂, SnO₂, GeO₂ und MgF₂, Acta Crystallographica, 9, 515-520 [link]

Bond W L (1965) Measurement of the refractive indices of several crystals, Journal of Applied Physics, 36, 1674-1677 [view file]

Papezik V S, De Witt M J (1973) Shorter communications: Coarse-grained rutile from northern Newfoundland, The Canadian Mineralogist, 12, 224-225 [view file]

Corlett M I, McIlreath I A (1974) An authigenic quartz-calcite-rutile assemblage in ordovician limestones, The Canadian Mineralogist, 12, 411-416 [view file]

Meagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO₂ polymorphs: refinement of the crystal structures of rutile and brookite at high temperature, The Canadian Mineralogist, 17, 77-85 [view file]

Černý P, Paul B J, Hawthorne F C, Chapman R (1981) A niobian rutile – disordered columbite intergrowth from the Huron Claim pegmatite, southeastern Manitoba, The Canadian Mineralogist, 19, 541-548 [view file]

Spear F S (1982) Phase equilibria of amphibolites from the post pond volcanics, Mt. cube quadrangle, Vermont, Journal of Petrology, 23, 383-426

Andrews A J, Masliwec A, Morris W A, Owsiacki L, York D (1986) The silver deposits at Cobalt and Gowganda, Ontario. II: An experiment in age determinations employing radiometric and paleomagnetic measurements, Canadian Journal of Earth Sciences, 23, 1507-1518

Kudoh Y, Takeda H (1986) Single crystal X-ray diffraction study on the bond compressibility of fayalite, Fe₂SiO₄ and rutile, TiO₂ under high pressure, Physica B, 139, 333-336

Tollo R P, Haggerty S E (1987) Nb–Cr-rutile in the Orapa kimberlite, Botswana, The Canadian Mineralogist, 25, 251-264 [view file]

Howard C J, Sabine T M, Dickson F (1991) Structural and thermal parameters for rutile and anatase, Acta Crystallographica, B47, 462-468

Sugiyama K, Takéuchi Y (1991) The crystal structure of rutile as a function of temperature up to 1600°C, Zeitschrift für Kristallographie, 194, 305-313 [view file]

Bursill (1996) Boron incorporation into rutile. phase equilibria and structure considerations, Journal of Solid State Chemistry, 127, 240-247

Rams J, Tejeda A, Cabrera J M (1997) Refractive indices of rutile as a function of temperature and wavelength, Journal of Applied Physics, 82, 994-997

Gesenhues U, Rentschler T (1999) Crystal growth and defect structure of Al³⁺-doped rutile, Journal of Solid State Chemistry, 143, 210-218

Bokhimi X, Morales A, Pedraza F (2002) Crystallography and crystallite morphology of rutile synthesized at low temperature, Journal of Solid State Chemistry, 169, 176-181

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]

Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file]

Toledo-Antonio J A, Gutierrez-Baez R, Sebastian P J, Vazquez A (2003) Thermal stability and structural deformation of rutile SnO₂, Journal of Solid State Chemistry, 174, 241-248

Clarke D B, Carruzzo S (2007) Assimilation of country-rock ilmenite and rutile in the South Mountain batholith, Nova Scotia, Canada, The Canadian Mineralogist, 45, 31-42 [view file]

Glass B P, Fries M (2008) Micro-Raman spectroscopic study of fine-grained, shock-metamorphosed rock fragments from the Australasian microtektite layer, Meteoritics and Planetary Science, 43, 1487-1496 [view file]

Gunter M E (2010) Defining asbestos: differences between the built and natural environments, Chimia, 64, 747-752

Armbruster T, Lazic B, Reznitsky L Z, Sklyarov E V (2013) Kyzylkumite, Ti₂V³⁺O₅(OH): new structure type, modularity and revised formula, Mineralogical Magazine, 77, 33-44 [view file]

Daneu N, Rečnik A, Mader W (2014) Atomic structure and formation mechanism of (101) rutile twins from Diamantina (Brazil), American Mineralogist, 99, 612-624

Robinson P, Langenhorst F, McEnroe S A, Fabian K, Ballaran T B (2014) Ferroan geikielite and coupled spinel-rutile exsolution from titanohematite: interface characterization and magnetic properties, American Mineralogist, 99, 1694-1712

MacDonald R, Bagiński B, Kartashov P M, Zozulya D, Dzierżanowski (2015) Interaction of rare-metal minerals with hydrothermal fluids: Evidence from quartz-epidote metasomatites of the Haldzan Buragtag Massif, Mongolian Altai, The Canadian Mineralogist, 53, 1015-1034

Di Cecco V E, Tait K T, Spooner E T C, Scherba C (2018) The vanadium-bearing oxide minerals of the Green Giant vanadium-graphite deposit, southwest Madagascar, The Canadian Mineralogist, 56, 247-257

Negrão L B A, Da Costa M L, Pöllmann H, Horn A (2018) An application of the Rietveld refinement method to the mineralogy of a bauxite-bearing regolith in the Lower Amazon, Mineralogical Magazine, 82, 413-431

Tschauner O (2019) High-pressure minerals, American Mineralogist, 104, 1701-1731