data_global
_chemical_name_mineral 'Polylithionite'
loop_
_publ_author_name
'Brigatti M F'
'Lugli C'
'Poppi L'
'Foord E E'
'Kile D E'
_journal_name_full 'American Mineralogist'
_journal_volume 85 
_journal_year 2000
_journal_page_first 1275
_journal_page_last 1286
_publ_section_title
;
 Crystal chemical variations in Li- and Fe-rich micas from
 Pikes Peak batholith (central Colorado)
 sample: 130(2)
;
_database_code_amcsd 0002500
_chemical_formula_sum 'Si3.328 Al1.69 Li1.093 Fe.484 Mg.022 Mn.062 Ca.006 Na.016 K.964 O10.456 F1.544 H.186'
_cell_length_a 5.275
_cell_length_b 9.105
_cell_length_c 10.084
_cell_angle_alpha 90
_cell_angle_beta 100.70
_cell_angle_gamma 90
_cell_volume 475.902
_exptl_crystal_density_diffrn      2.880
_symmetry_space_group_name_H-M 'C 1 2 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
SiT1   0.07550   0.16870   0.22887   0.83200
AlT1   0.07550   0.16870   0.22887   0.16800
SiT11   0.58500   0.33220   0.22855   0.83200
AlT11   0.58500   0.33220   0.22855   0.16800
LiM1   0.00000   0.99201   0.50000   0.53100
AlM1   0.00000   0.99201   0.50000   0.01800
FeM1   0.00000   0.99201   0.50000   0.41900
AlM2   0.00000   0.32250   0.50000   1.00000
LiM3   0.50000   0.16060   0.50000   0.56200
MgM3   0.50000   0.16060   0.50000   0.02200
FeM3   0.50000   0.16060   0.50000   0.06500
MnM3   0.50000   0.16060   0.50000   0.06200
CaA   0.00000   0.50140   0.00000   0.00600
NaA   0.00000   0.50140   0.00000   0.01600
KA   0.00000   0.50140   0.00000   0.96400
O1   0.03790   0.99980   0.17180   1.00000
O2   0.32090   0.23910   0.17290   1.00000
O22   0.81420   0.25930   0.15840   1.00000
O3   0.11580   0.17460   0.39350   1.00000
O33   0.66100   0.32700   0.39260   1.00000
F4   0.11090   0.47250   0.39870   0.77200
O4   0.11090   0.47250   0.39870   0.13500
O-H4   0.11090   0.47250   0.39870   0.09300
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
SiT1 0.01064 0.00659 0.01001 0.00065 0.00190 -0.00014
AlT1 0.01064 0.00659 0.01001 0.00065 0.00190 -0.00014
SiT11 0.01140 0.00595 0.01127 0.00026 0.00127 0.00014
AlT11 0.01140 0.00595 0.01127 0.00026 0.00127 0.00014
LiM1 0.01444 0.00760 0.01495 0.00000 0.00341 0.00000
AlM1 0.01444 0.00760 0.01495 0.00000 0.00341 0.00000
FeM1 0.01444 0.00760 0.01495 0.00000 0.00341 0.00000
AlM2 0.01089 0.00583 0.00798 0.00000 0.00062 0.00000
LiM3 0.01038 0.00798 0.01482 0.00000 0.00062 0.00000
MgM3 0.01038 0.00798 0.01482 0.00000 0.00062 0.00000
FeM3 0.01038 0.00798 0.01482 0.00000 0.00062 0.00000
MnM3 0.01038 0.00798 0.01482 0.00000 0.00062 0.00000
CaA 0.03002 0.02444 0.02773 0.00000 0.00455 0.00000
NaA 0.03002 0.02444 0.02773 0.00000 0.00455 0.00000
KA 0.03002 0.02444 0.02773 0.00000 0.00455 0.00000
O1 0.03027 0.01140 0.01672 0.00253 -0.00062 -0.00151
O2 0.02064 0.02685 0.01393 -0.00822 0.00151 -0.00142
O22 0.01900 0.02216 0.01342 0.00646 0.00151 0.00037
O3 0.01621 0.00912 0.01115 0.00065 0.00026 -0.00037
O33 0.01279 0.01191 0.01266 -0.00065 0.00177 -0.00027
F4 0.01431 0.00950 0.01241 -0.00100 0.00291 0.00192
O4 0.01431 0.00950 0.01241 -0.00100 0.00291 0.00192
O-H4 0.01431 0.00950 0.01241 -0.00100 0.00291 0.00192