Ferri-leakeite
Hawthorne F C, Oberti R, Ungaretti L, Grice J D
American Mineralogist 77 (1992) 1112-1115
Leakeite, NaNa2(Mg2Fe2Li)Si8O22(OH)2, a new alkali amphibole from the
Kajlidongri manganese mine, Jhabua district, Madhya Pradesh, India
Locality: Kajlidongri manganese mine, Jhabua district, Madhya Pradesh, India
_database_code_amcsd 0001541
9.822 17.836 5.286 90 104.37 90 C2/m
atom x y z occ Biso B(1,1) B(2,2) B(3,3) B(1,2) B(1,3) B(2,3)
O1 .1100 .0905 .2154 0.0013 0.0006 0.0081 -.0001 0.0005 -.0001
O2 .1184 .1685 .7284 0.0016 0.0006 0.0083 .0001 0.0006 0.0004
O3 .1110 0 .6985 0.0023 0.0005 0.0111 -.0004 0.0005 -.0001
O4 .3623 .2504 .8027 0.0033 0.0004 0.0096 -.0003 0.0017 0
O5 .3486 .1281 .0850 0.0014 0.0008 0.0068 .0001 0.0006 0.0007
O6 .3436 .1193 .5854 0.0016 0.0008 0.0059 0 0.0005 -.0006
O7 .3338 0 .2983 0.0021 0.0003 0.0149 0 0.0007 0
Si1 .2780 .0862 .2944 0.0013 0.0003 0.0048 0 0.0004 -.0001
Si2 .2883 .1712 .8018 0.0011 0.0003 0.0050 -.0001 0.0005 0
Mg1 0 .0848 .5 .72 0.0017 0.0007 0.0061 0 0.0012 0
Fe1 0 .0848 .5 .28 0.0017 0.0007 0.0061 0 0.0012 0
Mg2 0 .1796 0 .28 0.0013 0.0003 0.0056 0 0.0006 0
Fe2 0 .1796 0 .72 0.0013 0.0003 0.0056 0 0.0006 0
Li3 0 0 0 .83 0.0023 0.0003 0.0065 0 -.0002 0
Mg3 0 0 0 .17 0.0023 0.0003 0.0065 0 -.0002 0
Na4 0 .2763 .5 .98 0.0037 0.0007 0.0160 0 0.0045 0
Ca4 0 .2763 .5 .02 0.0037 0.0007 0.0160 0 0.0045 0
NaA 0 .5 0 .85 0.0201 0.0009 0.0771 0 0.0384 0
Nam .0399 .5 .0930 .038 0.0108 0.0016 0.0337 0 0.0149 0
Na2 0 .4766 0 .038 4.14
H .1845 0 .7705
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Ferri-leakeite
Hawthorne F C, Ungaretti L, Oberti R, Cannillo E
American Mineralogist 79 (1994) 443-451
The mechanism of Li incorporation in amphiboles
Sample: A1
Locality: Kajlidongri, Madhya Pradesh, India
_database_code_amcsd 0001655
9.748 17.842 5.287 90 104.12 90 C2/m
atom x y z occ Biso
Si1 .2811 .0857 .2929 .41
Si2 .2889 .1710 .7998 .42
Mg1 0 .0823 .5 .57 .72
Al1 0 .0823 .5 .025 .72
Ti1 0 .0823 .5 .205 .72
Fe1 0 .0823 .5 .13 .72
Mn1 0 .0823 .5 .07 .72
Mg2 0 .1796 0 .415 .48
Al2 0 .1796 0 .045 .48
Fe2 0 .1796 0 .35 .48
Mn2 0 .1796 0 .19 .48
Li3 0 0 0 .67 .69
Mg3 0 0 0 .33 .69
Na4 0 .2751 .5 .95 1.17
Ca4 0 .2751 .5 .05 1.17
NaA 0 .5 0 .16 6.5
KA 0 .5 0 .03 6.5
NaAm .0508 .5 .1091 .16 2.87
KAm .0508 .5 .1091 .03 2.87
NaA2 0 .4680 0 .16 4.68
KA2 0 .4680 0 .03 4.68
H .1867 0 .7577 .485 2.65
O1 .1115 .0886 .2159 .63
O2 .1178 .1668 .7270 .60
O3 .1104 0 .6965 .41 .76
Oh3 .1104 0 .6965 .485 .76
F3 .1104 0 .6965 .105 .76
O4 .3605 .2508 .8018 .80
O5 .3500 .1280 .0816 .74
O6 .3456 .1198 .5823 .73
O7 .3394 0 .2979 .84
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Ferri-leakeite
Hawthorne F C, Ungaretti L, Oberti R, Cannillo E
American Mineralogist 79 (1994) 443-451
The mechanism of Li incorporation in amphiboles
Sample: A2
Locality: Kajlidongri, Madhya Pradesh, India
_database_code_amcsd 0001656
9.790 17.848 5.287 90 104.10 90 C2/m
atom x y z occ Biso
Si1 .2785 .0862 .2934 .99 .43
Al1 .2785 .0862 .2934 .01 .43
Si2 .2889 .1712 .8023 .99 .43
Al2 .2889 .1712 .8023 .01 .43
Mg1 0 .0865 .5 .83 .54
Al1 0 .0865 .5 .04 .54
Fe1 0 .0865 .5 .10 .54
Mn1 0 .0865 .5 .03 .54
Mg2 0 .1796 0 .16 .48
Al2 0 .1796 0 .05 .48
Fe2 0 .1796 0 .61 .48
Mn2 0 .1796 0 .18 .48
Li3 0 0 0 .74 .79
Mg3 0 0 0 .26 .79
Na4 0 .2764 .5 .98 1.14
Ca4 0 .2764 .5 .02 1.14
NaA 0 .5 0 .15 3.01
KA 0 .5 0 .04 3.01
NaAm .0480 .5 .1028 .15 2.28
KAm .0480 .5 .1028 .04 2.28
NaA2 0 .4744 0 .15 4.87
KA2 0 .4744 0 .04 4.87
H .1826 0 .7335 .64 2.55
O1 .1102 .0905 .2146 .65
O2 .1186 .1694 .7315 .66
O3 .1115 0 .7002 .11 .96
Oh3 .1115 0 .7002 .64 .96
F3 .1115 0 .7002 .24 .96
O4 .3632 .2504 .8018 .81
O5 .3497 .1285 .0851 .77
O6 .3435 .1192 .5845 .73
O7 .3348 0 .2963 .93
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Ferri-leakeite
Hawthorne F C, Ungaretti L, Oberti R, Cannillo E
American Mineralogist 79 (1994) 443-451
The mechanism of Li incorporation in amphiboles
Sample: A3
Note: Site occupancies are set to be the same as ones in sample A2
Locality: Kajlidongri, Madhya Pradesh, India
_database_code_amcsd 0001657
9.822 17.836 5.286 90 104.37 90 C2/m
atom x y z occ Biso
Si1 .2780 .0862 .2944 .99 .46
Al1 .2780 .0862 .2944 .01 .46
Si2 .2883 .1712 .8018 .99 .45
Al2 .2883 .1712 .8018 .01 .45
Mg1 0 .0848 .5 .83 .70
Al1 0 .0848 .5 .04 .70
Fe1 0 .0848 .5 .10 .70
Mn1 0 .0848 .5 .03 .70
Mg2 0 .1796 0 .16 .50
Al2 0 .1796 0 .05 .50
Fe2 0 .1796 0 .61 .50
Mn2 0 .1796 0 .18 .50
Li3 0 0 0 .74 .69
Mg3 0 0 0 .26 .69
Na4 0 .2763 .5 .98 1.21
Ca4 0 .2763 .5 .02 1.21
NaA 0 .5 0 .15 4.51
KA 0 .5 0 .04 4.51
NaAm .0399 .5 .0930 .15 2.81
KAm .0399 .5 .0930 .04 2.81
NaA2 0 .4766 0 .15 4.14
KA2 0 .4766 0 .04 4.14
H .1845 0 .7705 .64 3.11
O1 .1100 .0905 .2154 .71
O2 .1184 .1685 .7284 .76
O3 .1110 0 .6975 .11 .91
Oh3 .1110 0 .6975 .64 .91
F3 .1110 0 .6975 .24 .91
O4 .3623 .2504 .8027 .89
O5 .3486 .1281 .0850 .74
O6 .3436 .1193 .5854 .74
O7 .3338 0 .2983 .94
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Ferri-leakeite
Oberti R, Camara F, Caballero J M
American Mineralogist 89 (2004) 888-893
Ferri-ottoliniite and ferriwhittakerite, two new end-members of the new
Group 5 for monoclinic amphiboles
Note: this is the previously named ferriwhittakerite
Locality: Pedriza massif, Sierra de Guadarrama, Spain
_database_code_amcsd 0020051
9.712 17.851 5.297 90 103.63 90 C2/m
atom x y z occ Biso B(1,1) B(2,2) B(3,3) B(1,2) B(1,3) B(2,3)
NaA 0 .5 0 .139 2.23 .0066 .0015 .0264 0 .0076 0
KA 0 .5 0 .028 2.23 .0066 .0015 .0264 0 .0076 0
NaAm .0548 .5 .1126 .501 2.21 .0080 .0015 .0287 0 .0151 0
KAm .0548 .5 .1126 .102 2.21 .0080 .0015 .0287 0 .0151 0
MgM1 0 .0867 .5 .690 .77 .0023 .0006 .0070 0 .0010 0
FeM1 0 .0867 .5 .225 .77 .0023 .0006 .0070 0 .0010 0
ZnM1 0 .0867 .5 .085 .77 .0023 .0006 .0070 0 .0010 0
FeM2 0 .1798 0 .740 .61 .0019 .0004 .0058 0 .0004 0
AlM2 0 .1798 0 .050 .61 .0019 .0004 .0058 0 .0004 0
TiM2 0 .1798 0 .060 .61 .0019 .0004 .0058 0 .0004 0
ZnM2 0 .1798 0 .115 .61 .0019 .0004 .0058 0 .0004 0
MgM2 0 .1798 0 .035 .61 .0019 .0004 .0058 0 .0004 0
LiM3 0 0 0 .730 .98 .0030 .0004 .0109 0 -.0012 0
MnM3 0 0 0 .120 .98 .0030 .0004 .0109 0 -.0012 0
FeM3 0 0 0 .130 .98 .0030 .0004 .0109 0 -.0012 0
MgM3 0 0 0 .020 .98 .0030 .0004 .0109 0 -.0012 0
LiM4 0 .2758 .5 .310 1.24 .0044 .0011 .0105 0 .0057 0
CaM4 0 .2758 .5 .055 1.24 .0044 .0011 .0105 0 .0057 0
NaM4 0 .2758 .5 .635 1.24 .0044 .0011 .0105 0 .0057 0
H .218 0 .786 .650 1.79
SiT1 .2809 .0859 .2890 .55 .0020 .0003 .0050 .0000 .0004 -.0001
SiT2 .2916 .1709 .7991 .63 .0022 .0004 .0052 -.0001 -.0001 -.0002
O1 .1110 .0907 .2121 .69 .0024 .0005 .0058 .0003 .0018 .0000
O2 .1195 .1711 .7325 .77 .0019 .0005 .0082 .0000 -.0009 -.0003
O3 .1131 0 .7005 .650 1.27 .0049 .0006 .0097 0 -.0008 0
F3 .1131 0 .7005 .350 1.27 .0049 .0006 .0097 0 -.0008 0
O4 .3660 .2507 .7969 .97 .0035 .0005 .0091 -.0003 .0014 -.0001
O5 .3513 .1290 .0802 1.01 .0028 .0010 .0070 -.0004 .0005 -.0003
O6 .3440 .1202 .5769 .93 .0028 .0007 .0074 .0002 .0000 -.0009
O7 .3362 0 .2960 .84 .0015 .0005 .0116 0 -.0003 0
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