Adamite R050020

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Record 2 of 3  

Name: Adamite
RRUFF ID: R050020
Ideal Chemistry: Zn2(AsO4)(OH)
Locality: Mina Ojuela, Mapimi, Durango, Mexico
Source: Eugene Schlepp
Owner: RRUFF
Description: Light green prismatic crystal
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Andalusite (17) ]
Quick search: [ All Adamite samples (3) ]
CHEMISTRY 
RRUFF ID: R050020.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Zn1.97Cu0.03)Σ=2((As0.98P0.02)Σ=1O4)(OH)
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Sample is oriented, mounted onto a pin and polished
Pin ID: L00511
Orientation: Laser parallel to  a*  (1 0 0).     Fiducial mark perpendicular to laser is parallel to  b   [0 1 0].
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Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050020
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050020.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050020.1
Sample Description: Powder
Cell Refinement Output: a: 8.3126(3)Å    b: 8.5274(5)Å    c: 6.0565(3)Å
alpha: 90.°    beta: 90.°    gamma: 90.°   Volume: 429.31(2)Å3    Crystal System: orthorhombic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Adamite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Friedel C, Daubrée G A (1866) Sur l‘adamine, nouvelle espèce minérale, Comptes Rendus Hebdomadaires des Séances de l'Académie des Sciences, 62, 692-695   [view file]

Richmond W E (1940) Crystal chemistry of the phosphates, arsenates and vanadates of the type A2XO4(Z), American Mineralogist, 25, 441-478   [view file]

Mrose M E, Mayers D E, Wise F A (1948) Adamite from the Ojuela Mine, Mapimi, Mexico, American Mineralogist, 33, 449-457

Sumin de Portilla V I (1974) Infrared spectroscopic investigation of the structure of some natural arsenates and the nature of H-bonds in their structures, The Canadian Mineralogist, 12, 262-268   [view file]

Hawthorne F C (1976) A refinement of the crystal structure of adamite, The Canadian Mineralogist, 14, 143-148   [view file]

Hill R J (1976) The crystal structure and infrared properties of adamite, American Mineralogist, 61, 979-986   [view file]

Kato T, Miura Y (1977) The crystal structures of adamite and paradamite, Mineralogical Journal, 8, 320-328   [view file]

Toman K (1978) Ordering in olivenite-adamite solid solutions, Acta Crystallographica, B34, 715-721

Braithwaite R S W (1983) Infrared spectroscopic analysis of the olivenite-adamite series, and of phosphate substitution in olivenite, Mineralogical Magazine, 47, 51-57   [view file]

Chisholm J E (1985) Cation segregation and the O-H stretching vibration of the olivenite-adamite series, Physics and Chemistry of Minerals, 12, 185-190

Braithwaite R S W, Green D I, Tindle A G (2009) The distribution and composition of adamite and zincolivenite in Britian and Ireland, Journal of the Russell Society, 12, 3-9

Jinnouchi S, Yoshiasa A, Sugiyama K, Shimura R, Arima H, Momma H, Miyawaki R (2016) Crystal structure refinements of legrandite, adamite, and paradamite: The complex structure and characteristic hydrogen bonding network of legrandite, Journal of Mineralogical and Petrological Sciences, 111, 35-43

Zema M, Tarantino S C, Boiocchi M, Callegari A M (2016) Crystal structure of adamite at high temperature, Mineralogical Magazine, 80, 901-914