Anhydrite R040061 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Anhydrite R040061

Name: Anhydrite
RRUFF ID: R040061
Ideal Chemistry: Ca(SO₄)
Locality: Chester County, Pennsylvania, USA
Source: University of Arizona Mineral Museum 6088 [view label]
Owner: RRUFF
Description: Pale purple fractured single crystal
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ Not in a structural group (133) ]

Quick search: [ All Anhydrite samples (4) ]

CHEMISTRY

RRUFF ID:	R040061.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	Ca_0.98S_1.01O₄

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Sample is oriented, mounted onto a pin and polished

Pin ID:

M00369

Orientation:

Laser parallel to a* (1 0 0). Fiducial mark perpendicular to laser is parallel to b [0 1 0].

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R040061

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R040061.1

Sample Description:

Powder

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R040061.1

Sample Description:

Powder

Cell Refinement Output:

a: 6.9984(4)Å b: 6.9927(5)Å c: 6.2383(3)Å
alpha: 90° beta: 90° gamma: 90° Volume: 305.29(2)Å³ Crystal System: orthorhombic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Anhydrite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Poda A N (1794) Bom Lilalith, in Mineralogische Aufsätze Mathias Andreas Schmidt Wein 226-236 [view file]
Haüy R J (1801) Chaux sulfatée anhydre, c'est-à-dire, privée d'eau, 4, in Traité de Minéralogie 348-353 [view file]
Klaproth M H (1803) Chemische Untersuchung des Muriacit, Neues Allgemeines Journal der Chemie, 1, 355-362 [view file]
Flurl M (1804) Einige Bemerkungen über den wasserfreyen Gyps (Anhydrit) und den Muriacit oder Würfelspath, Physikalische Abhandlungen der Königlich - Baierischen Akademie der Wissenschaften, 2, 128-140 [view file]
Ludwig C F (1804) A. G. Werners Mineral - System, Erste Klasse Erdige Fossilien, VI. Kalk - Geschlecht, in Handbuch der Mineralogie nach A. G. Werner Volume 2 Siegfried Lebrecht Crusius Leipzig 209-212 [view file]
Klaproth M H (1807) Chemische Untersuchung des Anhydrits, in Beiträge zur Chemischen Kenntnis der Mineralkörper Bei Decker Und Compagnie Und Bei Heinrich August Rottman Posen, Berlin 224-235 [view file]
Gallitelli P (1933) Ricerche sul solfato di calcio semidrato e sull'anidrite solubile, Periodico di Mineralogia, 4, 132-176 [view file]
Flörke O W (1952) Kristallographische und röntgenometrische untersuchungen im system CaSO₄ - CaSO₄·2H₂O, Neues Jahrbuch für Mineralogie, Abhandlungen, 4, 180-240 [view file]
Höhne E (1962) A more accurate determination of the crystal structure of anhydrite, CaSO₄, Soviet Physics - Crystallography, 7, 559-569 [view file]
Cheng G, Zussman J (1963) The crystal structure of anhydrite (CaSO₄), Acta Crystallographica, 16, 767-769
Kuzel V H J, Hauner M (1967) Chemische und kristallographische eigenschaften von calciumsulfat-halbhydrat und anhydrit III, Zement-Kalk-Gips, 40, 628-832 [view file]
Hawthorne F C, Ferguson R B (1975) Anhydrous sulphates. II. Refinement of the crystal structure of anhydrite, The Canadian Mineralogist, 13, 289-292 [view file]
Morikawa H, Tomita T, Minato I, Iwai S (1975) Anhydrite: a refinement, Acta Crystallographica, B31, 2164-2165
Louisnathan S J, Bloss F D, Korda E J (1978) Measurement of refractive indices and their dispersion, American Mineralogist, 63, 394-400 [view file]
Kirfel A, Will G (1980) Charge density in anhydrite, CaSO₄, from x-ray and neutron diffraction measurements, Acta Crystallographica, B36, 2881-2890 [view file]
Abriel V W (1983) Calcium sulfat subhydrat, CaSO₄·0,8H₂O, Acta Crystallographica, C39, 956-958 [view file]
Lager G A, Armbruster T, Rotella F J, Jorgensen J D, Hinks D G (1984) A crystallographic study of the low-temperature dehydration products of gypsum, CaSO₄·2H₂O: hemihydrate CaSO₄·0.50H₂O, and γ-CaSO₄, American Mineralogist, 69, 910-918 [view file]
Ramboz C, Oudin E, Thisse Y (1988) Geyser-type discharge in the Atlantis II Deep, Red Sea: evidence of boiling from fluid inclusions in epigenetic anhydrite, The Canadian Mineralogist, 26, 765-786 [view file]
Hartman P (1989) On the unit cell dimensions and bond lengths of anhydrite, European Journal of Mineralogy, 1, 721-722
Bezou C, Nonat A, Mutin J C, Christensen A N, Lehmann M S (1995) Investigation of the crystal structure of γ-CaSO₄, CaSO₄·0.5H₂O, and CaSO₄·0.6H₂O by powder diffraction methods, Journal of Solid State Chemistry, 117, 165-176
Sarma L P, Prasad P S R, Ravikumar N (1998) Raman spectroscopic study of phase transitions in natural gypsum, Journal of Raman Spectroscopy, 29, 851-856
Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]
Lane M D (2007) Mid-infrared emission spectroscopy of sulfate and sulfate-bearing minerals, American Mineralogist, 92, 1-18 [view file]
Christensen A N, Olesen M, Cerenius Y, Jensen T R (2008) Formation and transformation of five different phases in the CaSO₄-H₂O system: Crystal structure of the subhydrate β-CaSO₄·0.5H₂O and soluble anhydrite CaSO₄, Chemistry of Materials, 20, 2124-2132
Buzgar N, Buzatu A, Sanislav I V (2009) The Raman study on certain sulfates, Annalele Stiintifice ale Universitatii, 55, 5-23 [view file]
Seufert S, Hesse C, Goetz-Neunhoeffer F, Neubauer J (2009) Discrimination of bassanite and anhydrite III dehydrated from gypsum at different temperatures, Zeitschrift für Kristallographie, 30, 447-452 [view file]
Robertson K, Bish D (2013) Constraints on the distribution of CaSO₄·nH₂O phases on Mars and implications for their contribution to the hydrological cycle, Icarus, 223, 407-417
Bishop J L, Lane M D, Dyar M D, King S J, Brown A J, Swayze G A (2014) Spectral properties of Ca-sulfates: gypsum, bassanite, and anhydrite, American Mineralogist, 99, 2105-2115
Lopez-Reyes G, Sobron P, Lefebvre C, Rull F (2014) Multivariate analysis of Raman spectra for the identification of sulfates: Implications for ExoMars, American Mineralogist, 99, 1570-1579
Huang R, Keppler H (2015) Anhydrite stability and the effect of Ca on the behavior of sulfur in felsic magmas, American Mineralogist, 100, 257-266
Nowak M (2015) Anhydrite: an important sulfur binder limiting the climatic impact of subaerial volcanic eruptions, American Mineralogist, 100, 341-342
Xu H, Guo X, Bai J (2017) Thermal behavior of polyhalite: a high-temperature synchrotron XRD study, Physics and Chemistry of Minerals, 44, 125-135
Vaniman D T, Martinez G M, Rampe E B, Bristow T F, Blake D F, Yen A S, Ming D W, Rapin W, Meslin P Y, Morookian J M, Downs R T, Chipera S J, Morris R V, Morrison S M, Treiman A H, Achilles C N, Robertson K, Grotzinger J P, Hazen R M, Wiens R C, Sumner D Y (2018) Gypsum, bassanite, and anhydrite at Gale crater, Mars, American Mineralogist, 103, 1011-1020 [view file]
Biagioni C, Mauro D, Pasero M (2020) Sulfates from the pyrite ore deposits of the Apuan Alps (Tuscany, Italy): A review, Minerals, 10, 1092 [view file]

REFERENCES for Anhydrite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Poda A N (1794) Bom Lilalith, in Mineralogische Aufsätze Mathias Andreas Schmidt Wein 226-236 [view file]

Haüy R J (1801) Chaux sulfatée anhydre, c'est-à-dire, privée d'eau, 4, in Traité de Minéralogie 348-353 [view file]

Klaproth M H (1803) Chemische Untersuchung des Muriacit, Neues Allgemeines Journal der Chemie, 1, 355-362 [view file]

Flurl M (1804) Einige Bemerkungen über den wasserfreyen Gyps (Anhydrit) und den Muriacit oder Würfelspath, Physikalische Abhandlungen der Königlich - Baierischen Akademie der Wissenschaften, 2, 128-140 [view file]

Ludwig C F (1804) A. G. Werners Mineral - System, Erste Klasse Erdige Fossilien, VI. Kalk - Geschlecht, in Handbuch der Mineralogie nach A. G. Werner Volume 2 Siegfried Lebrecht Crusius Leipzig 209-212 [view file]

Klaproth M H (1807) Chemische Untersuchung des Anhydrits, in Beiträge zur Chemischen Kenntnis der Mineralkörper Bei Decker Und Compagnie Und Bei Heinrich August Rottman Posen, Berlin 224-235 [view file]

Gallitelli P (1933) Ricerche sul solfato di calcio semidrato e sull'anidrite solubile, Periodico di Mineralogia, 4, 132-176 [view file]

Flörke O W (1952) Kristallographische und röntgenometrische untersuchungen im system CaSO₄ - CaSO₄·2H₂O, Neues Jahrbuch für Mineralogie, Abhandlungen, 4, 180-240 [view file]

Höhne E (1962) A more accurate determination of the crystal structure of anhydrite, CaSO₄, Soviet Physics - Crystallography, 7, 559-569 [view file]

Cheng G, Zussman J (1963) The crystal structure of anhydrite (CaSO₄), Acta Crystallographica, 16, 767-769

Kuzel V H J, Hauner M (1967) Chemische und kristallographische eigenschaften von calciumsulfat-halbhydrat und anhydrit III, Zement-Kalk-Gips, 40, 628-832 [view file]

Hawthorne F C, Ferguson R B (1975) Anhydrous sulphates. II. Refinement of the crystal structure of anhydrite, The Canadian Mineralogist, 13, 289-292 [view file]

Morikawa H, Tomita T, Minato I, Iwai S (1975) Anhydrite: a refinement, Acta Crystallographica, B31, 2164-2165

Louisnathan S J, Bloss F D, Korda E J (1978) Measurement of refractive indices and their dispersion, American Mineralogist, 63, 394-400 [view file]

Kirfel A, Will G (1980) Charge density in anhydrite, CaSO₄, from x-ray and neutron diffraction measurements, Acta Crystallographica, B36, 2881-2890 [view file]

Abriel V W (1983) Calcium sulfat subhydrat, CaSO₄·0,8H₂O, Acta Crystallographica, C39, 956-958 [view file]

Lager G A, Armbruster T, Rotella F J, Jorgensen J D, Hinks D G (1984) A crystallographic study of the low-temperature dehydration products of gypsum, CaSO₄·2H₂O: hemihydrate CaSO₄·0.50H₂O, and γ-CaSO₄, American Mineralogist, 69, 910-918 [view file]

Ramboz C, Oudin E, Thisse Y (1988) Geyser-type discharge in the Atlantis II Deep, Red Sea: evidence of boiling from fluid inclusions in epigenetic anhydrite, The Canadian Mineralogist, 26, 765-786 [view file]

Hartman P (1989) On the unit cell dimensions and bond lengths of anhydrite, European Journal of Mineralogy, 1, 721-722

Bezou C, Nonat A, Mutin J C, Christensen A N, Lehmann M S (1995) Investigation of the crystal structure of γ-CaSO₄, CaSO₄·0.5H₂O, and CaSO₄·0.6H₂O by powder diffraction methods, Journal of Solid State Chemistry, 117, 165-176

Sarma L P, Prasad P S R, Ravikumar N (1998) Raman spectroscopic study of phase transitions in natural gypsum, Journal of Raman Spectroscopy, 29, 851-856

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]

Lane M D (2007) Mid-infrared emission spectroscopy of sulfate and sulfate-bearing minerals, American Mineralogist, 92, 1-18 [view file]

Christensen A N, Olesen M, Cerenius Y, Jensen T R (2008) Formation and transformation of five different phases in the CaSO₄-H₂O system: Crystal structure of the subhydrate β-CaSO₄·0.5H₂O and soluble anhydrite CaSO₄, Chemistry of Materials, 20, 2124-2132

Buzgar N, Buzatu A, Sanislav I V (2009) The Raman study on certain sulfates, Annalele Stiintifice ale Universitatii, 55, 5-23 [view file]

Seufert S, Hesse C, Goetz-Neunhoeffer F, Neubauer J (2009) Discrimination of bassanite and anhydrite III dehydrated from gypsum at different temperatures, Zeitschrift für Kristallographie, 30, 447-452 [view file]

Robertson K, Bish D (2013) Constraints on the distribution of CaSO₄·nH₂O phases on Mars and implications for their contribution to the hydrological cycle, Icarus, 223, 407-417

Bishop J L, Lane M D, Dyar M D, King S J, Brown A J, Swayze G A (2014) Spectral properties of Ca-sulfates: gypsum, bassanite, and anhydrite, American Mineralogist, 99, 2105-2115

Lopez-Reyes G, Sobron P, Lefebvre C, Rull F (2014) Multivariate analysis of Raman spectra for the identification of sulfates: Implications for ExoMars, American Mineralogist, 99, 1570-1579

Huang R, Keppler H (2015) Anhydrite stability and the effect of Ca on the behavior of sulfur in felsic magmas, American Mineralogist, 100, 257-266

Nowak M (2015) Anhydrite: an important sulfur binder limiting the climatic impact of subaerial volcanic eruptions, American Mineralogist, 100, 341-342

Xu H, Guo X, Bai J (2017) Thermal behavior of polyhalite: a high-temperature synchrotron XRD study, Physics and Chemistry of Minerals, 44, 125-135

Vaniman D T, Martinez G M, Rampe E B, Bristow T F, Blake D F, Yen A S, Ming D W, Rapin W, Meslin P Y, Morookian J M, Downs R T, Chipera S J, Morris R V, Morrison S M, Treiman A H, Achilles C N, Robertson K, Grotzinger J P, Hazen R M, Wiens R C, Sumner D Y (2018) Gypsum, bassanite, and anhydrite at Gale crater, Mars, American Mineralogist, 103, 1011-1020 [view file]

Biagioni C, Mauro D, Pasero M (2020) Sulfates from the pyrite ore deposits of the Apuan Alps (Tuscany, Italy): A review, Minerals, 10, 1092 [view file]