N R040102 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Natrolite R040102

Name: Natrolite
RRUFF ID: R040102
Ideal Chemistry: Na₂(Si₃Al₂)O₁₀·2H₂O
Locality: Ross' Quarry, Northland, New Zealand
Source: University of Arizona Mineral Museum 12862 [view label]
Owner: RRUFF
Description: Mass of colorless acicular crystals
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ Natrolite (13) ]

Quick search: [ All Natrolite samples (6) ]

CHEMISTRY

RRUFF ID:	R040102.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	(Na_0.92Ca_0.02)₂(Si_3.03Al_1.99)O₁₀·2H₂O

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Sample is oriented, mounted onto a pin and polished

Pin ID:

S00341

Orientation:

Laser parallel to -c* (0 0 -1). Fiducial mark perpendicular to laser is parallel to a [1 0 0].

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R040102

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R040102.1

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R040102.1

Sample Description:

Powder

Cell Refinement Output:

a: 18.3084(8)Å b: 18.6218(7)Å c: 6.5900(2)Å
alpha: 90.° beta: 90.° gamma: 90.° Volume: 2246.7(1)Å³ Crystal System: orthorhombic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Natrolite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Klaproth M H (1803) Chemische Untersuchung des Natroliths, Naturforschender Freunde zu Berlin, Neue Schriften, 4, 243-248 [view file]
Pauling L (1930) The structure of some sodium and calcium aluminosilicates, Proceedings of the National Academy of Sciences, 16, 453-459 [view file]
Murdoch J (1942) Crystallographic notes: cristobalite, stephanite, natrolite, American Mineralogist, 27, 500-506 [view file]
Fleischer M (1954) New mineral names, American Mineralogist, 39, 402-408 [view file]
Fleischer M (1957) New mineral names, American Mineralogist, 42, 919-921 [view file]
Meier W M (1960) The crystal structure of natrolite, Zeitschrift für Kristallographie, 113, 430-444 [view file]
Gabuda S P, Lundin A G, Mikhailov G M, Aleksandrov K S (1963) The position of hydrogen atoms in natrolite, Soviet Physics - Crystallography, 8, 305-307 [view file]
Alberti A, Vezzalini G (1983) How the structure of natrolite is modified through the heating-induced dehydration, Neues Jahrbuch für Mineralogie, Monatshefte, 1983, 135-144
Pechar F, Rykl D (1983) Study of the vibrational spectra of natural natrolite, The Canadian Mineralogist, 21, 689-695 [view file]
Baur W H, Kassner D, Kim C, Sieber N H W (1990) Flexibility and distortion of the framework of natrolite: crystal structures of ion-exchanged natrolites, European Journal of Mineralogy, 2, 761-769
Krogh Andersen E, Krogh Andersen IG, Ploug-Sorensen G (1990) Disorder in natrolites: structure determinations of three disordered natrolites and one lithium-exchanged disordered natrolite, European Journal of Mineralogy, 2, 799-807
Gunter M E, Knowles C R, Schalck D K (1993) Composite natrolite–mesolite crystals from the Columbia River Basalt Group, Clarkston, Washington, The Canadian Mineralogist, 31, 467-470 [view file]
Alberti A, Cruciani G, Dauru I (1995) Order-disorder in natrolite-group minerals, European Journal of Mineralogy, 7, 501-508
Goryainov S V, Belitsky I A (1995) Raman spectroscopy of water tracer diffusion of zeolite single crystals, Physics and Chemistry of Minerals, 22, 443-452 [link]
Joswig W, Baur W H (1995) The extreme collapse of a framework of NAT topology: the crystal structure of a metanatrolite (dehydrated natrolite) at 548K, Neues Jahrbuch für Mineralogie, Monatshefte, 1995, 26-38
Baur W H, Joswig W (1996) The phases of natrolite occurring during dehydration and rehydration studied by single crystal X-ray diffraction methods between room temperature and 923 K, Neues Jahrbuch für Mineralogie, Monatshefte, 1996, 171-187
Stuckenschmidt E, Joswig W, Baur W H (1996) Flexibility and distortion of the collapsible framework of NAT topology: the crystal structure of H₃O-natrolite, European Journal of Mineralogy, 8, 85-92
Coombs D S, Alberti A, Armbruster T, Artioli G, Colella C, Galli E, Grice J D, Liebau F, Mandarino J A, Minato H, Nickel E H, Passaglia E, Peacor D R, Quartieri S, Rinaldi R, Ross M, Sheppard R A, Tillmanns E, Vezzalini G, (1997) Recommended nomenclature for zeolite minerals: report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names, The Canadian Mineralogist, 35, 1571-1606 [view file]
Hamilton V E, McSween H Y, Hapke B (2005) Mineralogy of Martian atmospheric dust inferred from thermal infrared spectra of aerosols, Journal of Geophysical Research, 110, E12006 [link]
Seryotkin Y V, Bakakin V V, Fursenko B A, Belitsky I A, Joswig W, Radaelli P G (2005) Structural evolution of natrolite during over-hydration: a high-pressure neutron diffraction study, European Journal of Mineralogy, 17, 305-313
Wang H, Bish D L (2008) A PH₂O-dependent structural phase transition in the zeolite natrolite, American Mineralogist, 93, 1191-1194 [view file]
Liu D, Liu Z, Lee Y, Seoung D, Lee Y (2012) Spectroscopic characterization of alkali-metal exchanged natrolites, American Mineralogist, 97, 419-424 [view file]
Hwang H, Seoung D, Gatta G D, Blom D A, Vogt T, Lee Y (2015) Topotactic and reconstructive changes at high pressures and temperatures from Cs-natrolite to Cs-hexacelsian, American Mineralogist, 100, 1562-1567
Lee Y, Ahn D, Vogt T, Lee Y (2017) Dehydration studies of natrolites: Role of monovalent extra-framework cations and degree of hydration, American Mineralogist, 102, 1462-1469

REFERENCES for Natrolite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Klaproth M H (1803) Chemische Untersuchung des Natroliths, Naturforschender Freunde zu Berlin, Neue Schriften, 4, 243-248 [view file]

Pauling L (1930) The structure of some sodium and calcium aluminosilicates, Proceedings of the National Academy of Sciences, 16, 453-459 [view file]

Murdoch J (1942) Crystallographic notes: cristobalite, stephanite, natrolite, American Mineralogist, 27, 500-506 [view file]

Fleischer M (1954) New mineral names, American Mineralogist, 39, 402-408 [view file]

Fleischer M (1957) New mineral names, American Mineralogist, 42, 919-921 [view file]

Meier W M (1960) The crystal structure of natrolite, Zeitschrift für Kristallographie, 113, 430-444 [view file]

Gabuda S P, Lundin A G, Mikhailov G M, Aleksandrov K S (1963) The position of hydrogen atoms in natrolite, Soviet Physics - Crystallography, 8, 305-307 [view file]

Alberti A, Vezzalini G (1983) How the structure of natrolite is modified through the heating-induced dehydration, Neues Jahrbuch für Mineralogie, Monatshefte, 1983, 135-144

Pechar F, Rykl D (1983) Study of the vibrational spectra of natural natrolite, The Canadian Mineralogist, 21, 689-695 [view file]

Baur W H, Kassner D, Kim C, Sieber N H W (1990) Flexibility and distortion of the framework of natrolite: crystal structures of ion-exchanged natrolites, European Journal of Mineralogy, 2, 761-769

Krogh Andersen E, Krogh Andersen IG, Ploug-Sorensen G (1990) Disorder in natrolites: structure determinations of three disordered natrolites and one lithium-exchanged disordered natrolite, European Journal of Mineralogy, 2, 799-807

Gunter M E, Knowles C R, Schalck D K (1993) Composite natrolite–mesolite crystals from the Columbia River Basalt Group, Clarkston, Washington, The Canadian Mineralogist, 31, 467-470 [view file]

Alberti A, Cruciani G, Dauru I (1995) Order-disorder in natrolite-group minerals, European Journal of Mineralogy, 7, 501-508

Goryainov S V, Belitsky I A (1995) Raman spectroscopy of water tracer diffusion of zeolite single crystals, Physics and Chemistry of Minerals, 22, 443-452 [link]

Joswig W, Baur W H (1995) The extreme collapse of a framework of NAT topology: the crystal structure of a metanatrolite (dehydrated natrolite) at 548K, Neues Jahrbuch für Mineralogie, Monatshefte, 1995, 26-38

Baur W H, Joswig W (1996) The phases of natrolite occurring during dehydration and rehydration studied by single crystal X-ray diffraction methods between room temperature and 923 K, Neues Jahrbuch für Mineralogie, Monatshefte, 1996, 171-187

Stuckenschmidt E, Joswig W, Baur W H (1996) Flexibility and distortion of the collapsible framework of NAT topology: the crystal structure of H₃O-natrolite, European Journal of Mineralogy, 8, 85-92

Coombs D S, Alberti A, Armbruster T, Artioli G, Colella C, Galli E, Grice J D, Liebau F, Mandarino J A, Minato H, Nickel E H, Passaglia E, Peacor D R, Quartieri S, Rinaldi R, Ross M, Sheppard R A, Tillmanns E, Vezzalini G, (1997) Recommended nomenclature for zeolite minerals: report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names, The Canadian Mineralogist, 35, 1571-1606 [view file]

Hamilton V E, McSween H Y, Hapke B (2005) Mineralogy of Martian atmospheric dust inferred from thermal infrared spectra of aerosols, Journal of Geophysical Research, 110, E12006 [link]

Seryotkin Y V, Bakakin V V, Fursenko B A, Belitsky I A, Joswig W, Radaelli P G (2005) Structural evolution of natrolite during over-hydration: a high-pressure neutron diffraction study, European Journal of Mineralogy, 17, 305-313

Wang H, Bish D L (2008) A PH₂O-dependent structural phase transition in the zeolite natrolite, American Mineralogist, 93, 1191-1194 [view file]

Liu D, Liu Z, Lee Y, Seoung D, Lee Y (2012) Spectroscopic characterization of alkali-metal exchanged natrolites, American Mineralogist, 97, 419-424 [view file]

Hwang H, Seoung D, Gatta G D, Blom D A, Vogt T, Lee Y (2015) Topotactic and reconstructive changes at high pressures and temperatures from Cs-natrolite to Cs-hexacelsian, American Mineralogist, 100, 1562-1567

Lee Y, Ahn D, Vogt T, Lee Y (2017) Dehydration studies of natrolites: Role of monovalent extra-framework cations and degree of hydration, American Mineralogist, 102, 1462-1469