N R070236 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Hedenbergite R070236

Name: Hedenbergite
RRUFF ID: R070236
Ideal Chemistry: CaFe²⁺Si₂O₆
Locality: Dal'Negorsk, Primorskiy Kray; far eastern, Russia
Source: Michael Scott S104166 [view label]
Owner: RRUFF
Description: Gemmy drab to olive green orthorhombic prisms lining vug
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.

Mineral Group: [ pyroxene (81) ]

Quick search: [ All Hedenbergite samples (4) ]

CHEMISTRY

RRUFF ID:	R070236.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	Ca_1.00(Fe²⁺_0.67Mg_0.17Mn²⁺_0.16)_Σ=1Si_2.00O₆
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R070236

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R070236.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 9.8344(6)Å b: 9.023(5)Å c: 5.237(2)Å
alpha: 90° beta: 104.70(3)° gamma: 90° Volume: 449.51(2)Å³ Crystal System: monoclinic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Hedenbergite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Berzelius J J (1819) Hedenbergite, in Nouveau Système de Minéralogie Méquignon-Marvis Paris 269-270 [view file]
Dana E S (1904) Monoclinic Section. Pyroxene, in The System of Mineralogy of James Dwight Data 1837-1868, Sixth Edition John Wiley & Sons New York 352-371 [view file]
Kuno H, Hess H H (1953) Unit cell dimensions of clinoenstatite and pigeonite in relation to other common clinopyroxenes, American Journal of Science, 251, 741-752
Nolan J (1969) Physical properties of synthetic and natural pyroxenes in the system diopside-hedenbergite-acmite, Mineralogical Magazine, 37, 216-229 [view file]
Rutstein M S, Yund R A (1969) Unit-cell parameters of synthetic diopside-hedenbergite solid solutions, American Mineralogist, 54, 238-245 [view file]
Cameron M, Sueno S, Prewitt C T, Papike J J (1973) High-temperature crystal chemistry of acmite, diopside, hedenbergite, jadeite, spodumene, and ureyite, American Mineralogist, 58, 594-618 [view file]
Turnock A C, Lindsley D H, Grover J E (1973) Synthesis and unit cell parameters of Ca-Mg-Fe pyroxenes, American Mineralogist, 58, 50-59 [view file]
Ohashi Y, Burnham C W, Finger L W (1975) The effect of Ca-Fe on the clinopyroxene crystal structure, American Mineralogist, 60, 423-434 [view file]
Cameron M, Papike J J (1981) Structural and chemical variations in pyroxenes, American Mineralogist, 66, 1-50 [view file]
Morimoto N (1988) Nomenclature of pyroxenes, Mineralogical Magazine, 52, 535-550 [view file]
Raudsepp M, Hawthorne F C, Turnock A C (1990) Evaluation of the Rietveld method for the characterization of fine-grained products of mineral synthesis: the diopside-hedenbergite join, The Canadian Mineralogist, 28, 93-109 [view file]
Inoue A, Utada M (1991) Pumpellyite and related minerals from hydrothermally altered rocks at the Kamikita area, northern Honshu Japan, The Canadian Mineralogist, 29, 255-270 [view file]
Nakano T (1991) An antipathetic relation between the hedenbergite and johannsenite components in skarn clinopyroxene from the Kagata tungsten deposit, central Japan, The Canadian Mineralogist, 29, 427-434 [view file]
Huang E, Chen C H, Huang T, Lin E H, Xu J (2000) Raman spectroscopic characteristics of Mg-Fe-Ca pyroxenes, American Mineralogist, 85, 473-479 [view file]
Redhammer G J, Amthauer G, Lottermoser W, Treutmann W (2000) Synthesis and structural properties of clinopyroxenes of the hedenbergite CaFeSi₂O₆ - aegirine NaFeSi₂O₆ solid-solution series, European Journal of Mineralogy, 12, 105-120
Wang A, Jolliff B L, Haskin L A, Kuebler K E, Viskupic K M (2001) Characterization and comparison of structural and compositional features of planetary quadrilateral pyroxenes by Raman spectroscopy, American Mineralogist, 86, 790-806 [view file]
Heuer M, Huber A L, Bromiley G D, Fehr K T, Bente K (2002) Characterization of synthetic hedenbergite (CaFeSi₂O₆)–petedunnite (CaZnSi₂O₆) solid solution series by X-ray single crystal diffraction, Physics and Chemistry of Minerals, 32, 552-563
Redhammer G J, Amthauer G, Roth G, Tippelt G, Lottermoser W (2006) Single crystal X-ray diffraction and temperature dependent ⁵⁷Fe Mössbauer spectroscopy on the hedenbergite - aegirine (Ca,Na)(Fe²⁺,Fe³⁺)Si₂O₆ solid solution, American Mineralogist, 91, 1271-1292 [view file]
Nestola F, Tribaudino M, Boffa Ballaran T, Liebske C, Bruno M (2007) The crystal structure of pyroxenes along the jadeite-hedenbergite and jadeite-aegirine joins, American Mineralogist, 92, 1492-1501 [view file]
Buzatu A, Buzgar N (2010) The Raman study of single-chain silicates, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 56, 107-125 [view file]
Abdu Y A, Hawthorne F C (2013) Local structure in C2/c clinopyroxenes on the hedenbergite (CaFeSi₂O₆)-ferrosilite (Fe₂Si₂O₆) join: A new interpretation for the Mössbauer spectra of Ca-rich C2/c clinopyroxenes and implications for pyroxene exsolution, American Mineralogist, 98, 1227-1234
Mantovani L, Tribaudino M, Mezzadri F, Calestani G, Bromiley G (2013) The structure of (Ca,Co)CoSi₂O₆ pyroxenes and the Ca-M²⁺ substitution in (Ca,M²⁺)M²⁺Si₂O₆ pyroxenes (M²⁺ = Co, Fe, Mg), American Mineralogist, 98, 1241-1252
Kolitsch U, Rieck B, Brandstätter F, Schreiber F, Fabritz K H, Blaß G, Gröbner J (2014) Neufunde aus dem altem Bergbau und den Schlacken von Lavrion (II), Mineralien Welt, 25, 82-95
Mantovani L, Tribaudino M, Bertoni G, Salvianti G, Bromiley G (2014) Solid solutions and phase transitions in (Ca,M²⁺)M²⁺Si₂O₆ pyroxenes (M²⁺ = Co, Fe, Mg), American Mineralogist, 99, 704-711
Tribaudino M, Mantovani L (2014) Thermal expansion in C2/c pyroxenes: a review and new high-temperature structural data for a pyroxene of composition (Na_0.53Ca_0.47)(Al_0.53Fe_0.47)Si₂O₆ (Jd₅₃Hd₄₇), Mineralogical Magazine, 78, 311-324
Nespolo M, Aroyo M I (2016) The modular structure of pyroxenes, European Journal of Mineralogy, 28, 189-203
Nagashima M, Nishio-Hamane D (2018) Transmission electron microscopy study of the epitaxial association of hedenbergite whiskers with babingtonite, Mineralogical Magazine, 82, 23-33

REFERENCES for Hedenbergite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Berzelius J J (1819) Hedenbergite, in Nouveau Système de Minéralogie Méquignon-Marvis Paris 269-270 [view file]

Dana E S (1904) Monoclinic Section. Pyroxene, in The System of Mineralogy of James Dwight Data 1837-1868, Sixth Edition John Wiley & Sons New York 352-371 [view file]

Kuno H, Hess H H (1953) Unit cell dimensions of clinoenstatite and pigeonite in relation to other common clinopyroxenes, American Journal of Science, 251, 741-752

Nolan J (1969) Physical properties of synthetic and natural pyroxenes in the system diopside-hedenbergite-acmite, Mineralogical Magazine, 37, 216-229 [view file]

Rutstein M S, Yund R A (1969) Unit-cell parameters of synthetic diopside-hedenbergite solid solutions, American Mineralogist, 54, 238-245 [view file]

Cameron M, Sueno S, Prewitt C T, Papike J J (1973) High-temperature crystal chemistry of acmite, diopside, hedenbergite, jadeite, spodumene, and ureyite, American Mineralogist, 58, 594-618 [view file]

Turnock A C, Lindsley D H, Grover J E (1973) Synthesis and unit cell parameters of Ca-Mg-Fe pyroxenes, American Mineralogist, 58, 50-59 [view file]

Ohashi Y, Burnham C W, Finger L W (1975) The effect of Ca-Fe on the clinopyroxene crystal structure, American Mineralogist, 60, 423-434 [view file]

Cameron M, Papike J J (1981) Structural and chemical variations in pyroxenes, American Mineralogist, 66, 1-50 [view file]

Morimoto N (1988) Nomenclature of pyroxenes, Mineralogical Magazine, 52, 535-550 [view file]

Raudsepp M, Hawthorne F C, Turnock A C (1990) Evaluation of the Rietveld method for the characterization of fine-grained products of mineral synthesis: the diopside-hedenbergite join, The Canadian Mineralogist, 28, 93-109 [view file]

Inoue A, Utada M (1991) Pumpellyite and related minerals from hydrothermally altered rocks at the Kamikita area, northern Honshu Japan, The Canadian Mineralogist, 29, 255-270 [view file]

Nakano T (1991) An antipathetic relation between the hedenbergite and johannsenite components in skarn clinopyroxene from the Kagata tungsten deposit, central Japan, The Canadian Mineralogist, 29, 427-434 [view file]

Huang E, Chen C H, Huang T, Lin E H, Xu J (2000) Raman spectroscopic characteristics of Mg-Fe-Ca pyroxenes, American Mineralogist, 85, 473-479 [view file]

Redhammer G J, Amthauer G, Lottermoser W, Treutmann W (2000) Synthesis and structural properties of clinopyroxenes of the hedenbergite CaFeSi₂O₆ - aegirine NaFeSi₂O₆ solid-solution series, European Journal of Mineralogy, 12, 105-120

Wang A, Jolliff B L, Haskin L A, Kuebler K E, Viskupic K M (2001) Characterization and comparison of structural and compositional features of planetary quadrilateral pyroxenes by Raman spectroscopy, American Mineralogist, 86, 790-806 [view file]

Heuer M, Huber A L, Bromiley G D, Fehr K T, Bente K (2002) Characterization of synthetic hedenbergite (CaFeSi₂O₆)–petedunnite (CaZnSi₂O₆) solid solution series by X-ray single crystal diffraction, Physics and Chemistry of Minerals, 32, 552-563

Redhammer G J, Amthauer G, Roth G, Tippelt G, Lottermoser W (2006) Single crystal X-ray diffraction and temperature dependent ⁵⁷Fe Mössbauer spectroscopy on the hedenbergite - aegirine (Ca,Na)(Fe²⁺,Fe³⁺)Si₂O₆ solid solution, American Mineralogist, 91, 1271-1292 [view file]

Nestola F, Tribaudino M, Boffa Ballaran T, Liebske C, Bruno M (2007) The crystal structure of pyroxenes along the jadeite-hedenbergite and jadeite-aegirine joins, American Mineralogist, 92, 1492-1501 [view file]

Buzatu A, Buzgar N (2010) The Raman study of single-chain silicates, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 56, 107-125 [view file]

Abdu Y A, Hawthorne F C (2013) Local structure in C2/c clinopyroxenes on the hedenbergite (CaFeSi₂O₆)-ferrosilite (Fe₂Si₂O₆) join: A new interpretation for the Mössbauer spectra of Ca-rich C2/c clinopyroxenes and implications for pyroxene exsolution, American Mineralogist, 98, 1227-1234

Mantovani L, Tribaudino M, Mezzadri F, Calestani G, Bromiley G (2013) The structure of (Ca,Co)CoSi₂O₆ pyroxenes and the Ca-M²⁺ substitution in (Ca,M²⁺)M²⁺Si₂O₆ pyroxenes (M²⁺ = Co, Fe, Mg), American Mineralogist, 98, 1241-1252

Kolitsch U, Rieck B, Brandstätter F, Schreiber F, Fabritz K H, Blaß G, Gröbner J (2014) Neufunde aus dem altem Bergbau und den Schlacken von Lavrion (II), Mineralien Welt, 25, 82-95

Mantovani L, Tribaudino M, Bertoni G, Salvianti G, Bromiley G (2014) Solid solutions and phase transitions in (Ca,M²⁺)M²⁺Si₂O₆ pyroxenes (M²⁺ = Co, Fe, Mg), American Mineralogist, 99, 704-711

Tribaudino M, Mantovani L (2014) Thermal expansion in C2/c pyroxenes: a review and new high-temperature structural data for a pyroxene of composition (Na_0.53Ca_0.47)(Al_0.53Fe_0.47)Si₂O₆ (Jd₅₃Hd₄₇), Mineralogical Magazine, 78, 311-324

Nespolo M, Aroyo M I (2016) The modular structure of pyroxenes, European Journal of Mineralogy, 28, 189-203

Nagashima M, Nishio-Hamane D (2018) Transmission electron microscopy study of the epitaxial association of hedenbergite whiskers with babingtonite, Mineralogical Magazine, 82, 23-33