Perovskite R110178 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Perovskite R110178

Name: Perovskite
RRUFF ID: R110178
Ideal Chemistry: CaTiO₃
Locality: St Lawrence Columbium mine, Oka, Laurentides, Quebec, Canada
Source: Donald Doell [view label]
Owner: RRUFF
Description: Black lustrous cubes
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.

Mineral Group: [ Perovskite (44) ]

Quick search: [ All Perovskite samples (6) ]

CHEMISTRY

RRUFF ID:	R110178.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	(Ca_0.78Na_0.21Mg_0.03Ce_0.01La_0.01)_∑=1.05(Ti_0.42Nb_0.39Fe_0.12Ta_0.03Zr_0.01)_∑=0.98O₃
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented Raman on the primary sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R110178

Wavelength:

Sample Description:

Unoriented Raman on the primary sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R110178.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 5.476(3)Å b: 5.484(2)Å c: 7.748(3)Å
alpha: 90° beta: 90° gamma: 90° Volume: 232.67(8)Å³ Crystal System: orthorhombic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Perovskite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Rose G (1839) Beschreibung einiger neuen Mineralien des Urals, Annalen der Physik und Chemie, 48, 551-573 [view file]
Náray-Szabó I (1942) A perovskit (CaTiO₃) szerkezete, Matematikai és Természettudományi Értesitö, 61, 913-925
Náray-Szabó S (1943) Der strukturtyp des perowskits (CaTiO₃), Naturwissenschaften, 31, 202-203
Kay H F, Bailey P C (1957) Structures and properties of CaTiO₃, Acta Crystallographica, 10, 219-226
Nickel E H, McAdam R C (1963) Niobian perovskite from Oka, Quebec; a new classification for minerals of the perovskite group, The Canadian Mineralogist, 7, 683-697 [view file]
Fleischer M (1964) New mineral names, American Mineralogist, 49, 816-821 [view file]
Muir I J, Metson J B, Bancroft G M (1984) ⁵⁷Fe Mössbauer spectra of perovskite and titanite, The Canadian Mineralogist, 22, 689-694 [view file]
Devi P S, Rao M S (1992) Preparation, structure, and properties of strontium-doped lanthanum chromites: La1-xSrxCrO3, Journal of Solid State Chemistry, 98, 237-244
Mitchell R H, Steele I (1992) Potassian zirconium and titanium silicates and strontian cerian perovskite in lamproites from the Leucite Hills, Wyoming, The Canadian Mineralogist, 30, 1153-1159 [view file]
Genouel R, Michel C, Nguyen N, Studer F, Hervieu M, Raveau B (1995) On the cubic perovskites La_0.2Sr_0.8Cu_0.4M_0.6O_3-y (M=Co,Fe), Journal of Solid State Chemistry, 119, 260-270
Leinenweber K, Parise K (1995) High-pressure synthesis and crystal structure of CaFeTi₂O₆, a new perovskite structure type, Journal of Solid State Chemistry, 114, 277-281
Beran A, Libowitzky E, Armbruster T (1996) A single-crystal infrared spectroscopic and X-ray-diffraction study of untwinned San Benito perovskite containing OH groups, The Canadian Mineralogist, 34, 803-809 [view file]
Taguchi H, Sonoda M, Nagao M, Kido H (1996) Role of tetravalent ion in metal-insulator transition in (La_0.1Ca_0.9)(Mn_1-xTi_x)O₃, Journal of Solid State Chemistry, 126, 235-241
Chakhmouradian A R, Mitchell R H (1998) A structural study of the perovskite series CaTi_1-2xFe_xNb_xO₃, Journal of Solid State Chemistry, 138, 272-277
Mitchell R H, Chakhmouradian A R (1998) Instability of perovskite in a CO₂-rich environment: examples from carbonatite and kimberlite, The Canadian Mineralogist, 36, 939-952 [view file]
Zhao Y (1998) Crystal chemistry and phase transitions of perovskite in p-t-x space: data for (K_xNa_1-x)MgF₃ perovskites, Journal of Solid State Chemistry, 141, 121-132
Joswig W, Stachel T, Harris J W, Baur W H, Brey G P (1999) New Ca-silicate inclusions in diamonds - tracers from the lower mantle, Earth and Planetary Science Letters, 173, 1-6
Mitchell R H, Chakhmouradian A R (1999) Solid solubility in the system NaLREETi₂O₆ - ThTi₂O₆ (LREE, light rare-earth elements): experimental and analytical data, Physics and Chemistry of Minerals, 26, 396-405
Mitchell R H, Chakhmouradian A R (1999) Sr-bearing perovskite and loparite from lamproite and agpaitic nepheline syenite pegmatites, The Canadian Mineralogist, 37, 99-112 [view file]
Haines J, Rouquette J, Bornand V, Pintard M, Papet P, Gorelli F A (2003) Raman scattering studies at high pressure and low tempurature: technique and application to the piezoelectric material PbZr_0.52Ti_0.48O₃, Journal of Raman Spectroscopy, 34, 519-523
Kojitani H, Katsura T, Akaogi M (2007) Aluminum substitution mechanisms in perovskite-type MgSiO₃: an investigation by Rietveld analysis, Physics and Chemistry of Minerals, 34, 257-267
Knight K S (2009) Parameterization of the crystal structures of centerosymmetric zone-boundary-tilted perovskites: An analysis in terms of symmetry-adapted basis-vectors of the cubic aristotype phase, The Canadian Mineralogist, 47, 381-400 [view file]
Kleppe A K, Welch M D, Crichton W A, Jephcoat A P (2012) Phase transitions in hydroxide perovskites: a Raman spectroscopic study of stottite, FeGe(OH)₆, to 21 GPa, Mineralogical Magazine, 76, 949-962 [view file]
Nakatsuka A, Kuribayashi S, Nakayama N, Fukui H, Arima H, Yoneda A, Yoshiasa A (2015) Temperature dependence of crystal structure of CaGeO₃ high-pressure perovskite phase and experimental determination of its Debye temperatures studied by low- and high-temperature single-crystal X-ray diffraction, American Mineralogist, 100, 1190-1202
Crichton W A, Bernal F L, Guignard J, Hanfland M, Margadonna S (2016) Observation of Sb₂S₃-type post-post-perovskite in NaFeF₃. Implications for ABX₃ and A₂X₃ systems at ultrahigh pressure, Mineralogical Magazine, 80, 659-674
Feng D, Shivaramaiah R, Navrotsky A (2016) Rare-earth perovskites along the CaTiO₃-Na_0.5La_0.5TiO₃ join: Phase transitions, formation enthalpies, and implications for loparite minerals, American Mineralogist, 101, 2051-2056
Mitchell R H, Welch M D, Chakhmouradian A R (2017) Nomenclature of the perovskite supergroup: A hierarchical system of classification based on crystal structure and composition, Mineralogical Magazine, 81, 411-461 [view file]
Duffy T S (2018) Single-crystal elastic properties of minerals and related materials with cubic symmetry, American Mineralogist, 103, 977-988
Tschauner O (2019) High-pressure minerals, American Mineralogist, 104, 1701-1731

REFERENCES for Perovskite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Rose G (1839) Beschreibung einiger neuen Mineralien des Urals, Annalen der Physik und Chemie, 48, 551-573 [view file]

Náray-Szabó I (1942) A perovskit (CaTiO₃) szerkezete, Matematikai és Természettudományi Értesitö, 61, 913-925

Náray-Szabó S (1943) Der strukturtyp des perowskits (CaTiO₃), Naturwissenschaften, 31, 202-203

Kay H F, Bailey P C (1957) Structures and properties of CaTiO₃, Acta Crystallographica, 10, 219-226

Nickel E H, McAdam R C (1963) Niobian perovskite from Oka, Quebec; a new classification for minerals of the perovskite group, The Canadian Mineralogist, 7, 683-697 [view file]

Fleischer M (1964) New mineral names, American Mineralogist, 49, 816-821 [view file]

Muir I J, Metson J B, Bancroft G M (1984) ⁵⁷Fe Mössbauer spectra of perovskite and titanite, The Canadian Mineralogist, 22, 689-694 [view file]

Devi P S, Rao M S (1992) Preparation, structure, and properties of strontium-doped lanthanum chromites: La1-xSrxCrO3, Journal of Solid State Chemistry, 98, 237-244

Mitchell R H, Steele I (1992) Potassian zirconium and titanium silicates and strontian cerian perovskite in lamproites from the Leucite Hills, Wyoming, The Canadian Mineralogist, 30, 1153-1159 [view file]

Genouel R, Michel C, Nguyen N, Studer F, Hervieu M, Raveau B (1995) On the cubic perovskites La_0.2Sr_0.8Cu_0.4M_0.6O_3-y (M=Co,Fe), Journal of Solid State Chemistry, 119, 260-270

Leinenweber K, Parise K (1995) High-pressure synthesis and crystal structure of CaFeTi₂O₆, a new perovskite structure type, Journal of Solid State Chemistry, 114, 277-281

Beran A, Libowitzky E, Armbruster T (1996) A single-crystal infrared spectroscopic and X-ray-diffraction study of untwinned San Benito perovskite containing OH groups, The Canadian Mineralogist, 34, 803-809 [view file]

Taguchi H, Sonoda M, Nagao M, Kido H (1996) Role of tetravalent ion in metal-insulator transition in (La_0.1Ca_0.9)(Mn_1-xTi_x)O₃, Journal of Solid State Chemistry, 126, 235-241

Chakhmouradian A R, Mitchell R H (1998) A structural study of the perovskite series CaTi_1-2xFe_xNb_xO₃, Journal of Solid State Chemistry, 138, 272-277

Mitchell R H, Chakhmouradian A R (1998) Instability of perovskite in a CO₂-rich environment: examples from carbonatite and kimberlite, The Canadian Mineralogist, 36, 939-952 [view file]

Zhao Y (1998) Crystal chemistry and phase transitions of perovskite in p-t-x space: data for (K_xNa_1-x)MgF₃ perovskites, Journal of Solid State Chemistry, 141, 121-132

Joswig W, Stachel T, Harris J W, Baur W H, Brey G P (1999) New Ca-silicate inclusions in diamonds - tracers from the lower mantle, Earth and Planetary Science Letters, 173, 1-6

Mitchell R H, Chakhmouradian A R (1999) Solid solubility in the system NaLREETi₂O₆ - ThTi₂O₆ (LREE, light rare-earth elements): experimental and analytical data, Physics and Chemistry of Minerals, 26, 396-405

Mitchell R H, Chakhmouradian A R (1999) Sr-bearing perovskite and loparite from lamproite and agpaitic nepheline syenite pegmatites, The Canadian Mineralogist, 37, 99-112 [view file]

Haines J, Rouquette J, Bornand V, Pintard M, Papet P, Gorelli F A (2003) Raman scattering studies at high pressure and low tempurature: technique and application to the piezoelectric material PbZr_0.52Ti_0.48O₃, Journal of Raman Spectroscopy, 34, 519-523

Kojitani H, Katsura T, Akaogi M (2007) Aluminum substitution mechanisms in perovskite-type MgSiO₃: an investigation by Rietveld analysis, Physics and Chemistry of Minerals, 34, 257-267

Knight K S (2009) Parameterization of the crystal structures of centerosymmetric zone-boundary-tilted perovskites: An analysis in terms of symmetry-adapted basis-vectors of the cubic aristotype phase, The Canadian Mineralogist, 47, 381-400 [view file]

Kleppe A K, Welch M D, Crichton W A, Jephcoat A P (2012) Phase transitions in hydroxide perovskites: a Raman spectroscopic study of stottite, FeGe(OH)₆, to 21 GPa, Mineralogical Magazine, 76, 949-962 [view file]

Nakatsuka A, Kuribayashi S, Nakayama N, Fukui H, Arima H, Yoneda A, Yoshiasa A (2015) Temperature dependence of crystal structure of CaGeO₃ high-pressure perovskite phase and experimental determination of its Debye temperatures studied by low- and high-temperature single-crystal X-ray diffraction, American Mineralogist, 100, 1190-1202

Crichton W A, Bernal F L, Guignard J, Hanfland M, Margadonna S (2016) Observation of Sb₂S₃-type post-post-perovskite in NaFeF₃. Implications for ABX₃ and A₂X₃ systems at ultrahigh pressure, Mineralogical Magazine, 80, 659-674

Feng D, Shivaramaiah R, Navrotsky A (2016) Rare-earth perovskites along the CaTiO₃-Na_0.5La_0.5TiO₃ join: Phase transitions, formation enthalpies, and implications for loparite minerals, American Mineralogist, 101, 2051-2056

Mitchell R H, Welch M D, Chakhmouradian A R (2017) Nomenclature of the perovskite supergroup: A hierarchical system of classification based on crystal structure and composition, Mineralogical Magazine, 81, 411-461 [view file]

Duffy T S (2018) Single-crystal elastic properties of minerals and related materials with cubic symmetry, American Mineralogist, 103, 977-988

Tschauner O (2019) High-pressure minerals, American Mineralogist, 104, 1701-1731