Sogdianite R050648


Name: Sogdianite
RRUFF ID: R050648
Ideal Chemistry: KZr2Li3Si12O30
Locality: Dara-i-Pioz, Tadjikistan
Source: Dmitri Belakyovski
Owner: RRUFF
Description: Purple tabular fragment, used in the Geiger & Grodzicki (2012) study
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Milarite (18) ]
CHEMISTRY 
RRUFF ID: R050648.2
Sample Description: Microprobe Fragment
Measured Chemistry: (◻1.13Na0.87)Σ=2K1.00Li3.00(Zr0.76Fe3+0.73Ti0.37Al0.14)Σ=2Si12.00O30 ; Li not measured but estimated by difference and charge balance.
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented Sample. Raman spectra are overwhelmed with fluorescence under laser 780 nm.
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050648
Wavelength:
Sample Description: Unoriented Sample. Raman spectra are overwhelmed with fluorescence under laser 780 nm.
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050648.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
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POWDER DIFFRACTION 
RRUFF ID: R050648.1
Sample Description: Powder
Cell Refinement Output: a: 10.0439(4)Å    b: 10.0439(4)Å    c: 14.2089(4)Å
alpha: 90.°    beta: 90.°    gamma: 120.°   Volume: 1241.3(1)Å3    Crystal System: hexagonal
  File Type Information Close
Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Sogdianite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Dusmatov V D, Efimov A F, Kataeva Z T, Khoroshilova L A, Yanulov K P (1968) Sogdianite - a new mineral, Doklady Akademii Nauk SSSR, 182, 1176-1177   [view file]

Fleischer M (1969) New mineral names, American Mineralogist, 54, 1218-1223   [view file]

International Mineralogical Association (1971) International Mineralogical Association: Commission on new minerals and mineral names, Mineralogical Magazine, 38, 102-105   [view file]

Fleischer M (1972) New mineral names, American Mineralogist, 57, 1909-1914   [view file]

Cooper M A, Hawthorne F C, Grew E S (1999) The crystal chemistry of sogdianite, a milarite-group mineral, American Mineralogist, 84, 764-768   [view file]

Sokolova E V, Hawthorne F C, Pautov L A (2000) The crystal chemistry of Li-bearing minerals with the milarite-type structure: the crystal structure of end-member sogdianite, The Canadian Mineralogist, 38, 853-859   [view file]

Geiger C A, Grodzicki M (2012) A 57Fe Mössbauer spectroscopic study of sogdianite: an example of a symmetric electric field gradient around Fe3+, Physics and Chemistry of Minerals, 39, 73-78

Gagné O C, Hawthorne F C (2016) Chemographic exploration of the milarite-type structure, The Canadian Mineralogist, 54, 1229-1247