Realgar R060107 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Realgar R060107

Name: Realgar
RRUFF ID: R060107
Ideal Chemistry: AsS
Locality: Shimen, Hunan Province, China
Source: University of Arizona Mineral Museum 13816 [view label]
Owner: RRUFF
Description: Red prismatic crystals
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Quick search: [ All Realgar samples (3) ]

CHEMISTRY

RRUFF ID:	R060107.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	As_0.99S_1.01
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R060107

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 1% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File
	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R060107.1

Sample Description:

Powder

Cell Refinement Output:

a: 9.323(1)Å b: 13.574(1)Å c: 6.587(1)Å
alpha: 90° beta: 106.47(1)° gamma: 90° Volume: 799.4(2)Å³ Crystal System: monoclinic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Realgar
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Wallerius J G (1747) in Mineralogia, eller Mineralriket Stockholm [view file]
Ito T, Morimoto N, Sadanaga R (1952) The crystal structure of realgar, Acta Crystallographica, 5, 775-782
Clark A H (1970) Alpha-arsenic sulfide, from Mina Alacrán, Pampa Larga, Chile, American Mineralogist, 55, 1338-1344 [view file]
Mullen D J E, Nowacki W (1972) Refinement of the crystal structures of realgar, AsS and orpiment, As₂S₃, Zeitschrift für Kristallographie, 136, 48-65 [view file]
Douglass D L, Shing C, Wang G (1992) The light-induced alteration of realgar to pararealgar, American Mineralogist, 77, 1266-1274 [view file]
Frost R L, Martens W N, Kloprogge J T (2002) Raman spectroscopic study of cinnabar (HgS), realgar (As₄S₄), and orpiment (As₂S₃) at 298 and 77K, Neues Jahrbuch für Mineralogie, Monatshefte, 2002, 469-480
Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file]
Kyono A, Kimata M, Hatta T (2005) Light-induced degradation dynamics in realgar: in situ structural investigation using single-crystal X-ray diffraction study and X-ray photoelectron spectroscopy, American Mineralogist, 90, 1563-1570 [view file]
Ballirano P, Maras A (2006) In-situ X-ray transmission powder diffraction study of the kinetics of the light induced alteration of realgar (α-As4S4), European Journal of Mineralogy, 18, 589-599
Bonazzi P, Bindi L, Pratesi G, Menchetti S (2006) Light-induced changes in molecular arsenic sulfides: State of the art and new evidence by single-crystal X-ray diffraction, American Mineralogist, 91, 1323-1330 [view file]
Naumov P, Makreski P, Jovanovski G (2007) Direct atomic scale observations of linkage isomerization of As₄S₄ clusters during the photoinduced transition of realgar to pararealgar, Inorganic Chemistry, 46, 10624-10631
Bonazzi P, Bindi L (2008) A crystallographic review of arsenic sulfides: Effects of chemical variations and changes induced by exposure to light, Zeitschrift für Kristallographie, 223, 132-147
Kyono A (2009) Molecular conformation and anion configuration variations for As₄S₄ and As₄Se₄ in an anion-substituted solid solution, American Mineralogist, 94, 451-460 [view file]
Tuktabiev M A, Popova S V, Brazhkin V V, Lyapin A G, Katayama K (2009) Compressibility and polymorphism of α-As₄S₄ realgar under high pressure, Journal of Physics: Condensed Matter, 21, 385401
Ballirano P (2012) Thermal behavior of realgar As₄S₄, and of arsenolite As₂O₃ and non-stoichiometric As₈S_8+x crystals produced from As₄S₄ melt recrystallization, American Mineralogist, 97, 1320-1329 [view file]
Hejny C, Sagl R, Többens D M, Miletich R, Wildner M, Nasdala L, Ullrich A, Balic-Zunic T (2012) Crystal-structure properties and the molecular nature of hydrostatically compressed realgar, Physics and Chemistry of Minerals, 39, 399-412
Lepore G O, Boffa Ballaran T, Nestola F, Bindi L, Pasqual D, Bonazzi P (2012) Compressibility of β-As₄S₄: an in situ high-pressure single-crystal X-ray study, Mineralogical Magazine, 76, 963-973 [view file]
Zoppi M, Pratesi G (2012) The dual behavior of the β-As₄S₄ altered by light, American Mineralogist, 97, 890-896 [view file]
Pratesi G, Zoppi M (2015) An insight into the inverse transformation of realgar altered by light, American Mineralogist, 100, 1222-1229
Đorđević T, Kolitsch U, Serafimovski T, Tasev G, Tepe N, Stöger-Pollach M, Hofmann T, Boev B, (2019) Mineralogy and weathering of realgar-rich tailings at a former As-Sb-Cr mine at Lojane, North Macedonia, The Canadian Mineralogist, 57, 403-423

REFERENCES for Realgar

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Wallerius J G (1747) in Mineralogia, eller Mineralriket Stockholm [view file]

Ito T, Morimoto N, Sadanaga R (1952) The crystal structure of realgar, Acta Crystallographica, 5, 775-782

Clark A H (1970) Alpha-arsenic sulfide, from Mina Alacrán, Pampa Larga, Chile, American Mineralogist, 55, 1338-1344 [view file]

Mullen D J E, Nowacki W (1972) Refinement of the crystal structures of realgar, AsS and orpiment, As₂S₃, Zeitschrift für Kristallographie, 136, 48-65 [view file]

Douglass D L, Shing C, Wang G (1992) The light-induced alteration of realgar to pararealgar, American Mineralogist, 77, 1266-1274 [view file]

Frost R L, Martens W N, Kloprogge J T (2002) Raman spectroscopic study of cinnabar (HgS), realgar (As₄S₄), and orpiment (As₂S₃) at 298 and 77K, Neues Jahrbuch für Mineralogie, Monatshefte, 2002, 469-480

Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file]

Kyono A, Kimata M, Hatta T (2005) Light-induced degradation dynamics in realgar: in situ structural investigation using single-crystal X-ray diffraction study and X-ray photoelectron spectroscopy, American Mineralogist, 90, 1563-1570 [view file]

Ballirano P, Maras A (2006) In-situ X-ray transmission powder diffraction study of the kinetics of the light induced alteration of realgar (α-As4S4), European Journal of Mineralogy, 18, 589-599

Bonazzi P, Bindi L, Pratesi G, Menchetti S (2006) Light-induced changes in molecular arsenic sulfides: State of the art and new evidence by single-crystal X-ray diffraction, American Mineralogist, 91, 1323-1330 [view file]

Naumov P, Makreski P, Jovanovski G (2007) Direct atomic scale observations of linkage isomerization of As₄S₄ clusters during the photoinduced transition of realgar to pararealgar, Inorganic Chemistry, 46, 10624-10631

Bonazzi P, Bindi L (2008) A crystallographic review of arsenic sulfides: Effects of chemical variations and changes induced by exposure to light, Zeitschrift für Kristallographie, 223, 132-147

Kyono A (2009) Molecular conformation and anion configuration variations for As₄S₄ and As₄Se₄ in an anion-substituted solid solution, American Mineralogist, 94, 451-460 [view file]

Tuktabiev M A, Popova S V, Brazhkin V V, Lyapin A G, Katayama K (2009) Compressibility and polymorphism of α-As₄S₄ realgar under high pressure, Journal of Physics: Condensed Matter, 21, 385401

Ballirano P (2012) Thermal behavior of realgar As₄S₄, and of arsenolite As₂O₃ and non-stoichiometric As₈S_8+x crystals produced from As₄S₄ melt recrystallization, American Mineralogist, 97, 1320-1329 [view file]

Hejny C, Sagl R, Többens D M, Miletich R, Wildner M, Nasdala L, Ullrich A, Balic-Zunic T (2012) Crystal-structure properties and the molecular nature of hydrostatically compressed realgar, Physics and Chemistry of Minerals, 39, 399-412

Lepore G O, Boffa Ballaran T, Nestola F, Bindi L, Pasqual D, Bonazzi P (2012) Compressibility of β-As₄S₄: an in situ high-pressure single-crystal X-ray study, Mineralogical Magazine, 76, 963-973 [view file]

Zoppi M, Pratesi G (2012) The dual behavior of the β-As₄S₄ altered by light, American Mineralogist, 97, 890-896 [view file]

Pratesi G, Zoppi M (2015) An insight into the inverse transformation of realgar altered by light, American Mineralogist, 100, 1222-1229

Đorđević T, Kolitsch U, Serafimovski T, Tasev G, Tepe N, Stöger-Pollach M, Hofmann T, Boev B, (2019) Mineralogy and weathering of realgar-rich tailings at a former As-Sb-Cr mine at Lojane, North Macedonia, The Canadian Mineralogist, 57, 403-423