Rutile R050031 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Rutile R050031

Name: Rutile
RRUFF ID: R050031
Ideal Chemistry: TiO₂
Locality: Chester City, Pennsylvannia, USA
Source: University of Arizona Mineral Museum 3776 [view label]
Owner: RRUFF
Description: Reddish brown single crystal fragment
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ Rutile (23) ]

Quick search: [ All Rutile samples (7) ]

CHEMISTRY

RRUFF ID:	R050031.2
Sample Description:	Microprobe fragment
Measured Chemistry:	TiO₂

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Sample is oriented, mounted onto a pin and polished

Pin ID:

M00132

Orientation:

Laser parallel to -a* (-1 0 0). Fiducial mark perpendicular to laser is parallel to -c [0 0 -1].

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

Raman Mode Analysis

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R050031

Wavelength:

Sample Description:

Unorientated Raman on the primary sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R050031.1

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R050031.1

Sample Description:

Powder

Cell Refinement Output:

a: 4.5945(1)Å b: 4.5945(1)Å c: 2.9594(1)Å
alpha: 90.° beta: 90.° gamma: 90.° Volume: 62.472(3)Å³ Crystal System: tetragonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Rutile
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Lampadius W A (1800) Noch ein Paar Bemertungen über den Uran- und Titangehalt einiger Fossilien. Der rothe schörl (Rutil, nach herrn Bergrath Werner), in Sammlung practisch-chemischer Abhandlungen und vermischter Bemerkungen, Volume 3 Walther Dresden [view file]
Ludwig C F (1803) Rutil, in Handbuch der Mineralogie nach A. G. Werner, Volume 1 Siegfried Lebrécht Crusius Leipzig 305-306 [view file]
Schoβberger, F. (1942) Über die umwandlungen des titandioxyds, Journal of Solid State Chemistry, 104, 358-374
Hutton C O (1950) Studies of heavy detrital minerals, Bulletin of the Geological Society of America, 61, 635-710 [view file]
Baur W H (1956) Über die verfeinerung der kristallstrukturbestimmung einiger vertreter des rutiltyps: TiO₂, SnO₂, GeO₂ und MgF₂, Acta Crystallographica, 9, 515-520 [link]
Bond W L (1965) Measurement of the refractive indices of several crystals, Journal of Applied Physics, 36, 1674-1677 [view file]
Papezik V S, De Witt M J (1973) Shorter communications: Coarse-grained rutile from northern Newfoundland, The Canadian Mineralogist, 12, 224-225 [view file]
Corlett M I, McIlreath I A (1974) An authigenic quartz-calcite-rutile assemblage in ordovician limestones, The Canadian Mineralogist, 12, 411-416 [view file]
Meagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO₂ polymorphs: refinement of the crystal structures of rutile and brookite at high temperature, The Canadian Mineralogist, 17, 77-85 [view file]
Černý P, Paul B J, Hawthorne F C, Chapman R (1981) A niobian rutile – disordered columbite intergrowth from the Huron Claim pegmatite, southeastern Manitoba, The Canadian Mineralogist, 19, 541-548 [view file]
Spear F S (1982) Phase equilibria of amphibolites from the post pond volcanics, Mt. cube quadrangle, Vermont, Journal of Petrology, 23, 383-426
Andrews A J, Masliwec A, Morris W A, Owsiacki L, York D (1986) The silver deposits at Cobalt and Gowganda, Ontario. II: An experiment in age determinations employing radiometric and paleomagnetic measurements, Canadian Journal of Earth Sciences, 23, 1507-1518
Kudoh Y, Takeda H (1986) Single crystal X-ray diffraction study on the bond compressibility of fayalite, Fe₂SiO₄ and rutile, TiO₂ under high pressure, Physica B, 139, 333-336
Tollo R P, Haggerty S E (1987) Nb–Cr-rutile in the Orapa kimberlite, Botswana, The Canadian Mineralogist, 25, 251-264 [view file]
Howard C J, Sabine T M, Dickson F (1991) Structural and thermal parameters for rutile and anatase, Acta Crystallographica, B47, 462-468
Sugiyama K, Takéuchi Y (1991) The crystal structure of rutile as a function of temperature up to 1600°C, Zeitschrift für Kristallographie, 194, 305-313 [view file]
Bursill (1996) Boron incorporation into rutile. phase equilibria and structure considerations, Journal of Solid State Chemistry, 127, 240-247
Rams J, Tejeda A, Cabrera J M (1997) Refractive indices of rutile as a function of temperature and wavelength, Journal of Applied Physics, 82, 994-997
Gesenhues U, Rentschler T (1999) Crystal growth and defect structure of Al³⁺-doped rutile, Journal of Solid State Chemistry, 143, 210-218
Bokhimi X, Morales A, Pedraza F (2002) Crystallography and crystallite morphology of rutile synthesized at low temperature, Journal of Solid State Chemistry, 169, 176-181
Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]
Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file]
Toledo-Antonio J A, Gutierrez-Baez R, Sebastian P J, Vazquez A (2003) Thermal stability and structural deformation of rutile SnO₂, Journal of Solid State Chemistry, 174, 241-248
Clarke D B, Carruzzo S (2007) Assimilation of country-rock ilmenite and rutile in the South Mountain batholith, Nova Scotia, Canada, The Canadian Mineralogist, 45, 31-42 [view file]
Glass B P, Fries M (2008) Micro-Raman spectroscopic study of fine-grained, shock-metamorphosed rock fragments from the Australasian microtektite layer, Meteoritics and Planetary Science, 43, 1487-1496 [view file]
Gunter M E (2010) Defining asbestos: differences between the built and natural environments, Chimia, 64, 747-752
Armbruster T, Lazic B, Reznitsky L Z, Sklyarov E V (2013) Kyzylkumite, Ti₂V³⁺O₅(OH): new structure type, modularity and revised formula, Mineralogical Magazine, 77, 33-44 [view file]
Daneu N, Rečnik A, Mader W (2014) Atomic structure and formation mechanism of (101) rutile twins from Diamantina (Brazil), American Mineralogist, 99, 612-624
Robinson P, Langenhorst F, McEnroe S A, Fabian K, Ballaran T B (2014) Ferroan geikielite and coupled spinel-rutile exsolution from titanohematite: interface characterization and magnetic properties, American Mineralogist, 99, 1694-1712
MacDonald R, Bagiński B, Kartashov P M, Zozulya D, Dzierżanowski (2015) Interaction of rare-metal minerals with hydrothermal fluids: Evidence from quartz-epidote metasomatites of the Haldzan Buragtag Massif, Mongolian Altai, The Canadian Mineralogist, 53, 1015-1034
Di Cecco V E, Tait K T, Spooner E T C, Scherba C (2018) The vanadium-bearing oxide minerals of the Green Giant vanadium-graphite deposit, southwest Madagascar, The Canadian Mineralogist, 56, 247-257
Negrão L B A, Da Costa M L, Pöllmann H, Horn A (2018) An application of the Rietveld refinement method to the mineralogy of a bauxite-bearing regolith in the Lower Amazon, Mineralogical Magazine, 82, 413-431
Tschauner O (2019) High-pressure minerals, American Mineralogist, 104, 1701-1731

REFERENCES for Rutile

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Lampadius W A (1800) Noch ein Paar Bemertungen über den Uran- und Titangehalt einiger Fossilien. Der rothe schörl (Rutil, nach herrn Bergrath Werner), in Sammlung practisch-chemischer Abhandlungen und vermischter Bemerkungen, Volume 3 Walther Dresden [view file]

Ludwig C F (1803) Rutil, in Handbuch der Mineralogie nach A. G. Werner, Volume 1 Siegfried Lebrécht Crusius Leipzig 305-306 [view file]

Schoβberger, F. (1942) Über die umwandlungen des titandioxyds, Journal of Solid State Chemistry, 104, 358-374

Hutton C O (1950) Studies of heavy detrital minerals, Bulletin of the Geological Society of America, 61, 635-710 [view file]

Baur W H (1956) Über die verfeinerung der kristallstrukturbestimmung einiger vertreter des rutiltyps: TiO₂, SnO₂, GeO₂ und MgF₂, Acta Crystallographica, 9, 515-520 [link]

Bond W L (1965) Measurement of the refractive indices of several crystals, Journal of Applied Physics, 36, 1674-1677 [view file]

Papezik V S, De Witt M J (1973) Shorter communications: Coarse-grained rutile from northern Newfoundland, The Canadian Mineralogist, 12, 224-225 [view file]

Corlett M I, McIlreath I A (1974) An authigenic quartz-calcite-rutile assemblage in ordovician limestones, The Canadian Mineralogist, 12, 411-416 [view file]

Meagher E P, Lager G A (1979) Polyhedral thermal expansion in the TiO₂ polymorphs: refinement of the crystal structures of rutile and brookite at high temperature, The Canadian Mineralogist, 17, 77-85 [view file]

Černý P, Paul B J, Hawthorne F C, Chapman R (1981) A niobian rutile – disordered columbite intergrowth from the Huron Claim pegmatite, southeastern Manitoba, The Canadian Mineralogist, 19, 541-548 [view file]

Spear F S (1982) Phase equilibria of amphibolites from the post pond volcanics, Mt. cube quadrangle, Vermont, Journal of Petrology, 23, 383-426

Andrews A J, Masliwec A, Morris W A, Owsiacki L, York D (1986) The silver deposits at Cobalt and Gowganda, Ontario. II: An experiment in age determinations employing radiometric and paleomagnetic measurements, Canadian Journal of Earth Sciences, 23, 1507-1518

Kudoh Y, Takeda H (1986) Single crystal X-ray diffraction study on the bond compressibility of fayalite, Fe₂SiO₄ and rutile, TiO₂ under high pressure, Physica B, 139, 333-336

Tollo R P, Haggerty S E (1987) Nb–Cr-rutile in the Orapa kimberlite, Botswana, The Canadian Mineralogist, 25, 251-264 [view file]

Howard C J, Sabine T M, Dickson F (1991) Structural and thermal parameters for rutile and anatase, Acta Crystallographica, B47, 462-468

Sugiyama K, Takéuchi Y (1991) The crystal structure of rutile as a function of temperature up to 1600°C, Zeitschrift für Kristallographie, 194, 305-313 [view file]

Bursill (1996) Boron incorporation into rutile. phase equilibria and structure considerations, Journal of Solid State Chemistry, 127, 240-247

Rams J, Tejeda A, Cabrera J M (1997) Refractive indices of rutile as a function of temperature and wavelength, Journal of Applied Physics, 82, 994-997

Gesenhues U, Rentschler T (1999) Crystal growth and defect structure of Al³⁺-doped rutile, Journal of Solid State Chemistry, 143, 210-218

Bokhimi X, Morales A, Pedraza F (2002) Crystallography and crystallite morphology of rutile synthesized at low temperature, Journal of Solid State Chemistry, 169, 176-181

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]

Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file]

Toledo-Antonio J A, Gutierrez-Baez R, Sebastian P J, Vazquez A (2003) Thermal stability and structural deformation of rutile SnO₂, Journal of Solid State Chemistry, 174, 241-248

Clarke D B, Carruzzo S (2007) Assimilation of country-rock ilmenite and rutile in the South Mountain batholith, Nova Scotia, Canada, The Canadian Mineralogist, 45, 31-42 [view file]

Glass B P, Fries M (2008) Micro-Raman spectroscopic study of fine-grained, shock-metamorphosed rock fragments from the Australasian microtektite layer, Meteoritics and Planetary Science, 43, 1487-1496 [view file]

Gunter M E (2010) Defining asbestos: differences between the built and natural environments, Chimia, 64, 747-752

Armbruster T, Lazic B, Reznitsky L Z, Sklyarov E V (2013) Kyzylkumite, Ti₂V³⁺O₅(OH): new structure type, modularity and revised formula, Mineralogical Magazine, 77, 33-44 [view file]

Daneu N, Rečnik A, Mader W (2014) Atomic structure and formation mechanism of (101) rutile twins from Diamantina (Brazil), American Mineralogist, 99, 612-624

Robinson P, Langenhorst F, McEnroe S A, Fabian K, Ballaran T B (2014) Ferroan geikielite and coupled spinel-rutile exsolution from titanohematite: interface characterization and magnetic properties, American Mineralogist, 99, 1694-1712

MacDonald R, Bagiński B, Kartashov P M, Zozulya D, Dzierżanowski (2015) Interaction of rare-metal minerals with hydrothermal fluids: Evidence from quartz-epidote metasomatites of the Haldzan Buragtag Massif, Mongolian Altai, The Canadian Mineralogist, 53, 1015-1034

Di Cecco V E, Tait K T, Spooner E T C, Scherba C (2018) The vanadium-bearing oxide minerals of the Green Giant vanadium-graphite deposit, southwest Madagascar, The Canadian Mineralogist, 56, 247-257

Negrão L B A, Da Costa M L, Pöllmann H, Horn A (2018) An application of the Rietveld refinement method to the mineralogy of a bauxite-bearing regolith in the Lower Amazon, Mineralogical Magazine, 82, 413-431

Tschauner O (2019) High-pressure minerals, American Mineralogist, 104, 1701-1731