Tyrolite R050231

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Name: Tyrolite
RRUFF ID: R050231
Ideal Chemistry: Ca2Cu9(AsO4)4(CO3)(OH)8·11H2O
Locality: Tyrol, Austria
Source: Marcus Origlieri
Owner: RRUFF
Description: Thin green scaly crystals
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.
Mineral Group: [ Tyrolite (3) ]
Quick search: [ All Tyrolite samples (3) ]
CHEMISTRY 
RRUFF ID: R050231.2
Sample Description: Microprobe fragment
Measured Chemistry: (Ca0.80Fe2+0.20)Σ=1(Cu4.86Zn0.11   0.03)Σ=5((As0.96S0.03P0.01)Σ=1O4)2(CO3)(OH)4·6H2O
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050231
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 50% of 150mW
POWDER DIFFRACTION 
RRUFF ID: R050231.9
Sample Description: Single crystal, powder profile is calculated
Cell Refinement Output: a: 10.40(3)Å    b: 54.9(3)Å    c: 5.52(2)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 3151(10)Å3    Crystal System: orthorhombic
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REFERENCES for Tyrolite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Werner A G (1817) Kupferschaum, in Letztes Mineral-System Craz, Gerlach and Gerold Freiberg 50-51   [view file]

Haidinger W (1845) Zweite Klasse: Geogenide. IV. Ordnung. Malachite. VII. Euchlormalachit. Tirolit., in Handbuch der Bestimmenden Mineralogie Bei Braumüller and Seidel Wien 506-511   [view file]

Church A H (1895) A chemical study of some native arsenates and phosphates, Mineralogical Magazine, 11, 1-12   [view file]

Berry L G (1948) Tyrolite, higginsite and cornwallite, American Mineralogist, 33, 193-193   [view file]

Guillemin C (1956) Contribution a la minéralogie des arséniates, phosphates et vanadates de cuivre, Bulletin de la Société Française de Minéralogie et de Cristallographie, 79, 7-95   [view file]

Fleischer M (1957) New mineral names, American Mineralogist, 42, 117-124   [view file]

Kloprogge J T, Frost R L (2000) Raman microscopy study of tyrolite: a multi-anion arsenate mineral, Applied Spectroscopy, 54, 517-521

Krivovichev S V, Chernyshov D Y, Döbelin N, Armbruster T, Kahlenberg V, Kaindl R, Ferraris G, Tessadri R, Kaltenhauser G (2006) Crystal chemistry and polytypism of tyrolite, American Mineralogist, 91, 1378-1384   [view file]