A R060402 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Hydroniumjarosite R060402

Name: Hydroniumjarosite
RRUFF ID: R060402
Ideal Chemistry: (H₃O)Fe³⁺₃(SO₄)₂(OH)₆
Locality: Cyprus, Greece
Source: American Museum of Natural History 21997 [view label]
Owner: RRUFF
Description: Tan colored consolidated powder
Status: The identification of this mineral has been made only by X-ray diffraction.

Mineral Groups: [ alunite (46) ] [ Alunite (20) ]

CHEMISTRY

RRUFF ID:	R060402.2
Sample Description:	Microprobe Fragment

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R060402

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R060402.1

Sample Description:

Powder

Cell Refinement Output:

a: 7.3153(9)Å b: 7.3153(9)Å c: 16.626(2)Å
alpha: 90° beta: 90° gamma: 120° Volume: 770.5(0)Å³ Crystal System: hexagonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Hydroniumjarosite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Arzruni A, Thaddeeff K (1899) Neue Minerale aus Chile, ein neues Vorkommen von Utahit und ein neues Wismuthcarbonat von Schneeberg, Zeitschrift für Kristallographie, 31, 229-247 [view file]
Kubisz J (1960) Hydronium jarosite - (H₃O)Fe₃(SO₄)₂(OH)₆, Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Geologiques et Geographiques, 8, 95-99 [view file]
Fleischer M (1961) New mineral names, American Mineralogist, 46, 241-244 [view file]
Brophy G P, Sheridan M F (1965) Sulfate studies IV: the jarosite—natrojarosite—hydronium jarosite solid solution series, American Mineralogist, 50, 1595-1607 [view file]
Jambor J L (1999) Nomenclature of the alunite supergroup, The Canadian Mineralogist, 37, 1323-1341 [view file]
Mazlan J, Stevens R, Boerio-Goates J, Woodfield B F, Navrotsky A, Burns P C, Crawford M K, Amos T G (2004) Thermodynamic properties, low-temperature heat-capacity anomalies, and single-crystal X-ray refinement of hydronium jarosite, (H₃O)Fe₃(SO₄)₂(OH)₆, Physics and Chemistry of Minerals, 31, 518-531
Frost R L, Wills R A, Weier M L, Martens W, Mills S (2006) A Raman spectroscopic study of selected natural jarosites, Spectrochimica Acta, A63, 1-8
Basciano L C, Peterson R C (2007) Jarosite—hydronium jarosite solid-solution series with full iron site occupancy: Mineralogy and crystal chemistry, American Mineralogist, 92, 1464-1473 [view file]
Basciano L C, Peterson R C (2007) The crystal structure of ammoniojarosite, (NH₄)Fe₃(SO₄)₂(OH)₆ and the crystal chemistry of the ammoniojarosite-hydronium jarosite solid-solution series, Mineralogical Magazine, 71, 427-441 [view file]
Basciano L C, Peterson R C (2008) Crystal chemistry of the natrojarosite-jarosite and natrojarosite-hydronium jarosite solid-solution: A synthetic study with full Fe site occupancy, American Mineralogist, 93, 853-862 [view file]
Burke E A J (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks, The Mineralogical Record, 39, 131-135 [view file]
Murphy P J, Smith A M L, Hudson-Edwards K A, Dubbin W E, Wright K (2009) Raman and IR spectroscopic studies of alunite-supergroup compounds containing Al, Cr³⁺, Fe³⁺ and V³⁺ at the B site, The Canadian Mineralogist, 47, 663-681 [view file]
Bayliss P, Kolitsch U, Nickel E H, Pring A (2010) Alunite supergroup: recommended nomenclature, Mineralogical Magazine, 74, 919-927 [view file]
Gale J D, Wright K, Hudson-Edwards K A (2010) A first-principles determination of the orientation of H₃O⁺ in hydronium alunite, American Mineralogist, 95, 1109-1112 [view file]
Plášil J, Škoda R, Fejfarová K, Čejka J, Kasatkin A V, Dušek M, Talla D, Lapčák L, Machovič V, Dini M (2014) Hydroniumjarosite, (H₃O)⁺Fe₃(SO₄)₂(OH)₆, from Cerros Pintados, Chile: Single-crystal X-ray diffraction and vibrational spectroscopic study, Mineralogical Magazine, 78, 535-547 [view file]
Spratt H J, Avdeev M, Pfrunder M C, McMurtrie J, Rintoul L, Martens W N (2014) Location of hydrogen atoms in hydronium jarosite, Physics and Chemistry of Minerals, 41, 505-517
Sklute E C, Glotch T D, Piatek J L, Woerner W R, Martone A A, Kraner M L (2015) Optical constants of synthetic potassium, sodium, and hydronium jarosite, American Mineralogist, 100, 1110-1122

REFERENCES for Hydroniumjarosite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Arzruni A, Thaddeeff K (1899) Neue Minerale aus Chile, ein neues Vorkommen von Utahit und ein neues Wismuthcarbonat von Schneeberg, Zeitschrift für Kristallographie, 31, 229-247 [view file]

Kubisz J (1960) Hydronium jarosite - (H₃O)Fe₃(SO₄)₂(OH)₆, Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Geologiques et Geographiques, 8, 95-99 [view file]

Fleischer M (1961) New mineral names, American Mineralogist, 46, 241-244 [view file]

Brophy G P, Sheridan M F (1965) Sulfate studies IV: the jarosite—natrojarosite—hydronium jarosite solid solution series, American Mineralogist, 50, 1595-1607 [view file]

Jambor J L (1999) Nomenclature of the alunite supergroup, The Canadian Mineralogist, 37, 1323-1341 [view file]

Mazlan J, Stevens R, Boerio-Goates J, Woodfield B F, Navrotsky A, Burns P C, Crawford M K, Amos T G (2004) Thermodynamic properties, low-temperature heat-capacity anomalies, and single-crystal X-ray refinement of hydronium jarosite, (H₃O)Fe₃(SO₄)₂(OH)₆, Physics and Chemistry of Minerals, 31, 518-531

Frost R L, Wills R A, Weier M L, Martens W, Mills S (2006) A Raman spectroscopic study of selected natural jarosites, Spectrochimica Acta, A63, 1-8

Basciano L C, Peterson R C (2007) Jarosite—hydronium jarosite solid-solution series with full iron site occupancy: Mineralogy and crystal chemistry, American Mineralogist, 92, 1464-1473 [view file]

Basciano L C, Peterson R C (2007) The crystal structure of ammoniojarosite, (NH₄)Fe₃(SO₄)₂(OH)₆ and the crystal chemistry of the ammoniojarosite-hydronium jarosite solid-solution series, Mineralogical Magazine, 71, 427-441 [view file]

Basciano L C, Peterson R C (2008) Crystal chemistry of the natrojarosite-jarosite and natrojarosite-hydronium jarosite solid-solution: A synthetic study with full Fe site occupancy, American Mineralogist, 93, 853-862 [view file]

Burke E A J (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks, The Mineralogical Record, 39, 131-135 [view file]

Murphy P J, Smith A M L, Hudson-Edwards K A, Dubbin W E, Wright K (2009) Raman and IR spectroscopic studies of alunite-supergroup compounds containing Al, Cr³⁺, Fe³⁺ and V³⁺ at the B site, The Canadian Mineralogist, 47, 663-681 [view file]

Bayliss P, Kolitsch U, Nickel E H, Pring A (2010) Alunite supergroup: recommended nomenclature, Mineralogical Magazine, 74, 919-927 [view file]

Gale J D, Wright K, Hudson-Edwards K A (2010) A first-principles determination of the orientation of H₃O⁺ in hydronium alunite, American Mineralogist, 95, 1109-1112 [view file]

Plášil J, Škoda R, Fejfarová K, Čejka J, Kasatkin A V, Dušek M, Talla D, Lapčák L, Machovič V, Dini M (2014) Hydroniumjarosite, (H₃O)⁺Fe₃(SO₄)₂(OH)₆, from Cerros Pintados, Chile: Single-crystal X-ray diffraction and vibrational spectroscopic study, Mineralogical Magazine, 78, 535-547 [view file]

Spratt H J, Avdeev M, Pfrunder M C, McMurtrie J, Rintoul L, Martens W N (2014) Location of hydrogen atoms in hydronium jarosite, Physics and Chemistry of Minerals, 41, 505-517

Sklute E C, Glotch T D, Piatek J L, Woerner W R, Martone A A, Kraner M L (2015) Optical constants of synthetic potassium, sodium, and hydronium jarosite, American Mineralogist, 100, 1110-1122