Important Update News
The RRUFF Project is being updated to improve its interface and content. The beta version of the update is accessible to the public at RRUFF.net. New data is only being added to the beta site. Please note that it is in development, and some components are not functional. Existing RRUFF.info links will resolve to the new site after RRUFF.net is officially released.
We are grateful to NASA for the funding of this effort.
![]() |
![]() |
Name: Hureaulite RRUFF ID: R070452 Ideal Chemistry: Mn2+5(PO3OH)2(PO4)2·4H2O Locality: Tip Top mine, Fourmile, Custer District, Custer County, South Dakota, USA Source: Michael Scott S102347 [view label] Owner: RRUFF Description: Massive coarse pink granular Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis |
Mineral Group: [ Hureaulite (4) ] | ||
Quick search: [ All Hureaulite samples (2) ] |
CHEMISTRY | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|
![]() |
|
RAMAN SPECTRUM | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
|
BROAD SCAN WITH SPECTRAL ARTIFACTS | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
|
POWDER DIFFRACTION | ||||||||
---|---|---|---|---|---|---|---|---|
RRUFF ID: | R070452.1 | |||||||
Sample Description: | Powder | |||||||
Cell Refinement Output: |
a: 17.610(1)Å b: 9.1093(9)Å c: 9.4906(9)Å alpha: 90° beta: 96.600(8)° gamma: 90° Volume: 1512.4(2)Å3 Crystal System: monoclinic |
|||||||
|
|
REFERENCES for Hureaulite | |
---|---|
American Mineralogist Crystal Structure Database Record: [view record] |
|
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file] |
|
Vauquelin L N (1825) Analyse de l´huraulite, minéral trouvé dans la commune d´Hureaux, Annales de Chimie et de Physique, 3, 302-307 [view file] |
|
Alluaud F (1826) Notices sur l'hétérosite, l'hureaulite (fer et manganèse phosphatés), et sur quelques autres minéraux du département de la Haute-Vienne, Anneles des Sciences Naturelles, 8, 334-354 [view file] |
|
Brush G J, Dana E S, Wells H L (1890) On the mineral locality at Branchville, Connecticut: Fifth paper, American Journal of Science, 39, 201-216 [view file] |
|
Yagi K, Fleischer M (1955) New mineral names, American Mineralogist, 40, 367-370 [view file] |
|
Fisher D J (1964) Lithian hureaulite from the Black Hills, American Mineralogist, 49, 398-406 [view file] |
|
Moore P B, Araki T (1973) Hureaulite, Mn52+ (H2O)4[PO3(OH)]2[PO4]2: Its atomic arrangement, American Mineralogist, 58, 302-307 [view file] |
|
Shigley J E, Brown G E (1985) Occurance and alteration of phosphate minerals at the Stewart Pegmatite, Pala District, San Diego County, California, American Mineralogist, 70, 395-408 [view file] |
|
Corbin D R, Whitney J F, Fultz W C, Stucky G D, Eddy M M, Cheetham A K (1986) Synthesis of open-framework transition-metal phosphates using organometallic precursors in acidic media. Preparation and structural characterization of Fe5P4O20H10 and NaFe3P3O12, Inorganic Chemistry, 25, 2279-2280 |
|
Frost R L, Erickson K L (2005) Near-infrared spectroscopic study of selected hydrated hydroxylated phosphates, Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, 61, 45-50 [link] |
|
Dyar M D, Jawin E R, Breves E, Marchand G, Nelms M, Lane M D, Mertzman S A, Bish D L and Bishop J L (2014) Mössbauer parameters of iron in phosphate minerals: Implications for interpretation of martian data, American Mineralogist, 99, 914-942 [view file] |
|
Gatta G D, Redhammer G J, Vignola P, Meven M, McIntyre G J (2016) Single-crystal neutron diffraction and Mössbauer spectroscopic study of hureaulite, (Mn,Fe)5(PO4)2(HPO4)2(H2O)4, European Journal of Mineralogy, 28, 93-103 |
|
Đorđević T, Gerger S, Karanović L (2017) Hydrothermal and ionothermal synthesis of mineral-related arsenates in the system CdO–MO–As2O5 (M2+ = Mg, Co, Ni, Cu, Zn) and their crystal structures, European Journal of Mineralogy, 29, 73-89 |
|
|